Chemistry - A European Journal, volume 24, issue 49, pages 12779-12783
Overcoming the Inertness of Iridium(III) in a Facile Single‐Crystal to Single‐Crystal Reaction of Iodine Vapor with a Cyclometalated Chloride Monomer
Publication type: Journal Article
Publication date: 2018-08-01
Journal:
Chemistry - A European Journal
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 4.3
ISSN: 09476539, 15213765
General Chemistry
Catalysis
Organic Chemistry
Abstract
Iridium(III) is often considered to be one of the most inert octahedral metal ions. Herein we present a phenanthroimidazole‐based bis‐cyclometalated iridium(III) chloride undergoing a facile chloro ligand exchange with iodine, in a gas‐solid reaction under ambient conditions. Monitoring the progress of the reaction by X‐ray diffraction analysis reveals the crystal‐packing‐induced exceptional stereoselectivity of this topochemical transformation. The results provide excellent opportunities to modulate the geometry and kinetic properties of cyclometalated iridium(III) complexes that may be very promising in catalysis and design of anticancer agents.
Citations by journals
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5
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Dalton Transactions
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Dalton Transactions
5 publications, 41.67%
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European Journal of Inorganic Chemistry
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European Journal of Inorganic Chemistry
1 publication, 8.33%
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Molecules
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Molecules
1 publication, 8.33%
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Crystal Growth and Design
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1 publication, 8.33%
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Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
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Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
1 publication, 8.33%
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Angewandte Chemie - International Edition
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Angewandte Chemie - International Edition
1 publication, 8.33%
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Angewandte Chemie
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Angewandte Chemie
1 publication, 8.33%
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Materials Advances
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Materials Advances
1 publication, 8.33%
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5
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Citations by publishers
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6
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
6 publications, 50%
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Wiley
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Wiley
3 publications, 25%
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 8.33%
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American Chemical Society (ACS)
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American Chemical Society (ACS)
1 publication, 8.33%
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Pleiades Publishing
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Pleiades Publishing
1 publication, 8.33%
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1
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6
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Bezzubov S. I. et al. Overcoming the Inertness of Iridium(III) in a Facile Single‐Crystal to Single‐Crystal Reaction of Iodine Vapor with a Cyclometalated Chloride Monomer // Chemistry - A European Journal. 2018. Vol. 24. No. 49. pp. 12779-12783.
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Bezzubov S. I., Kalle P., Bilyalova A. A., Tatarin S. V., Dolzhenko V. D. Overcoming the Inertness of Iridium(III) in a Facile Single‐Crystal to Single‐Crystal Reaction of Iodine Vapor with a Cyclometalated Chloride Monomer // Chemistry - A European Journal. 2018. Vol. 24. No. 49. pp. 12779-12783.
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TY - JOUR
DO - 10.1002/chem.201801963
UR - https://doi.org/10.1002%2Fchem.201801963
TI - Overcoming the Inertness of Iridium(III) in a Facile Single‐Crystal to Single‐Crystal Reaction of Iodine Vapor with a Cyclometalated Chloride Monomer
T2 - Chemistry - A European Journal
AU - Bilyalova, Alfiya A.
AU - Dolzhenko, Vladimir D.
AU - Kalle, Paulina
AU - Bezzubov, Stanislav I.
AU - Tatarin, Sergei V.
PY - 2018
DA - 2018/08/01 00:00:00
PB - Wiley
SP - 12779-12783
IS - 49
VL - 24
SN - 0947-6539
SN - 1521-3765
ER -
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@article{2018_Bezzubov
author = {Alfiya A. Bilyalova and Vladimir D. Dolzhenko and Paulina Kalle and Stanislav I. Bezzubov and Sergei V. Tatarin},
title = {Overcoming the Inertness of Iridium(III) in a Facile Single‐Crystal to Single‐Crystal Reaction of Iodine Vapor with a Cyclometalated Chloride Monomer},
journal = {Chemistry - A European Journal},
year = {2018},
volume = {24},
publisher = {Wiley},
month = {aug},
url = {https://doi.org/10.1002%2Fchem.201801963},
number = {49},
pages = {12779--12783},
doi = {10.1002/chem.201801963}
}
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MLA
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Bezzubov, Stanislav I., et al. “Overcoming the Inertness of Iridium(III) in a Facile Single‐Crystal to Single‐Crystal Reaction of Iodine Vapor with a Cyclometalated Chloride Monomer.” Chemistry - A European Journal, vol. 24, no. 49, Aug. 2018, pp. 12779-12783. https://doi.org/10.1002%2Fchem.201801963.