Chemistry - A European Journal, volume 24, issue 49, pages 12779-12783

Overcoming the Inertness of Iridium(III) in a Facile Single‐Crystal to Single‐Crystal Reaction of Iodine Vapor with a Cyclometalated Chloride Monomer

Publication typeJournal Article
Publication date2018-08-01
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor4.3
ISSN09476539, 15213765
General Chemistry
Catalysis
Organic Chemistry
Abstract

Iridium(III) is often considered to be one of the most inert octahedral metal ions. Herein we present a phenanthroimidazole‐based bis‐cyclometalated iridium(III) chloride undergoing a facile chloro ligand exchange with iodine, in a gas‐solid reaction under ambient conditions. Monitoring the progress of the reaction by X‐ray diffraction analysis reveals the crystal‐packing‐induced exceptional stereoselectivity of this topochemical transformation. The results provide excellent opportunities to modulate the geometry and kinetic properties of cyclometalated iridium(III) complexes that may be very promising in catalysis and design of anticancer agents.

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GOST Copy
Bezzubov S. I. et al. Overcoming the Inertness of Iridium(III) in a Facile Single‐Crystal to Single‐Crystal Reaction of Iodine Vapor with a Cyclometalated Chloride Monomer // Chemistry - A European Journal. 2018. Vol. 24. No. 49. pp. 12779-12783.
GOST all authors (up to 50) Copy
Bezzubov S. I., Kalle P., Bilyalova A. A., Tatarin S. V., Dolzhenko V. D. Overcoming the Inertness of Iridium(III) in a Facile Single‐Crystal to Single‐Crystal Reaction of Iodine Vapor with a Cyclometalated Chloride Monomer // Chemistry - A European Journal. 2018. Vol. 24. No. 49. pp. 12779-12783.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/chem.201801963
UR - https://doi.org/10.1002%2Fchem.201801963
TI - Overcoming the Inertness of Iridium(III) in a Facile Single‐Crystal to Single‐Crystal Reaction of Iodine Vapor with a Cyclometalated Chloride Monomer
T2 - Chemistry - A European Journal
AU - Bilyalova, Alfiya A.
AU - Dolzhenko, Vladimir D.
AU - Kalle, Paulina
AU - Bezzubov, Stanislav I.
AU - Tatarin, Sergei V.
PY - 2018
DA - 2018/08/01 00:00:00
PB - Wiley
SP - 12779-12783
IS - 49
VL - 24
SN - 0947-6539
SN - 1521-3765
ER -
BibTex |
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BibTex Copy
@article{2018_Bezzubov
author = {Alfiya A. Bilyalova and Vladimir D. Dolzhenko and Paulina Kalle and Stanislav I. Bezzubov and Sergei V. Tatarin},
title = {Overcoming the Inertness of Iridium(III) in a Facile Single‐Crystal to Single‐Crystal Reaction of Iodine Vapor with a Cyclometalated Chloride Monomer},
journal = {Chemistry - A European Journal},
year = {2018},
volume = {24},
publisher = {Wiley},
month = {aug},
url = {https://doi.org/10.1002%2Fchem.201801963},
number = {49},
pages = {12779--12783},
doi = {10.1002/chem.201801963}
}
MLA
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MLA Copy
Bezzubov, Stanislav I., et al. “Overcoming the Inertness of Iridium(III) in a Facile Single‐Crystal to Single‐Crystal Reaction of Iodine Vapor with a Cyclometalated Chloride Monomer.” Chemistry - A European Journal, vol. 24, no. 49, Aug. 2018, pp. 12779-12783. https://doi.org/10.1002%2Fchem.201801963.
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