Journal of Polymer Science, Part A: Polymer Chemistry, volume 34, issue 1, pages 57-62

Supramolecular hydrogen-bonded liquid-crystalline polymer complexes. Design of side-chain polymers and a host-guest system by noncovalent interaction

Kato Takashi 1
Hirota Norifumi 2
Fujishima Akira 2
Fréchet Jean M. J. 3
Publication typeJournal Article
Publication date1996-01-15
Quartile SCImago
Quartile WOS
Impact factor
ISSN0887624X, 10990518
Materials Chemistry
Organic Chemistry
Polymers and Plastics
Abstract
Supramolecular liquid–crystalline polymeric complexes based on a backbone that contains vinyl pyridine units and azobenzene or biphenyl derivatives that posses alkyl chains terminated by carboxylic acid have been obtained by the formation of intermolecular hydrogen bonds between the carboxylic acid and the pyridyl moieties. The polymeric complexes behave as side-chain liquid–crystalline polymers and exhibit smectic phases. A new type of H-bonded host-guest liquid–crystalline system is also reported. The liquid–crystalline host copolymers contain both mesogenic acrylate and 4-vinylpyridine units. The guest molecule is an azobenzene that has a carboxylic acid moiety at one of its extremities. The H-bonded polymeric host–guest complexes exhibit nematic phases. Sequential UV and visible light irradiation of the polymeric complex causes reversible photochemically induced phase transitions. The isothermal nematic–isotropic and isotropic–nematic transitions result from the trans-cis and cis-trans photoisomerization of the guest azobenzene in the host–guest system. © 1996 John Wiley & Sons, Inc.

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Kato T. et al. Supramolecular hydrogen-bonded liquid-crystalline polymer complexes. Design of side-chain polymers and a host-guest system by noncovalent interaction // Journal of Polymer Science, Part A: Polymer Chemistry. 1996. Vol. 34. No. 1. pp. 57-62.
GOST all authors (up to 50) Copy
Kato T., Hirota N., Fujishima A., Fréchet J. M. J. Supramolecular hydrogen-bonded liquid-crystalline polymer complexes. Design of side-chain polymers and a host-guest system by noncovalent interaction // Journal of Polymer Science, Part A: Polymer Chemistry. 1996. Vol. 34. No. 1. pp. 57-62.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/(SICI)1099-0518(19960115)34:1<57::AID-POLA5>3.0.CO;2-0
UR - https://doi.org/10.1002%2F%28SICI%291099-0518%2819960115%2934%3A1%3C57%3A%3AAID-POLA5%3E3.0.CO%3B2-0
TI - Supramolecular hydrogen-bonded liquid-crystalline polymer complexes. Design of side-chain polymers and a host-guest system by noncovalent interaction
T2 - Journal of Polymer Science, Part A: Polymer Chemistry
AU - Kato, Takashi
AU - Hirota, Norifumi
AU - Fujishima, Akira
AU - Fréchet, Jean M. J.
PY - 1996
DA - 1996/01/15 00:00:00
PB - Wiley
SP - 57-62
IS - 1
VL - 34
SN - 0887-624X
SN - 1099-0518
ER -
BibTex |
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BibTex Copy
@article{1996_Kato,
author = {Takashi Kato and Norifumi Hirota and Akira Fujishima and Jean M. J. Fréchet},
title = {Supramolecular hydrogen-bonded liquid-crystalline polymer complexes. Design of side-chain polymers and a host-guest system by noncovalent interaction},
journal = {Journal of Polymer Science, Part A: Polymer Chemistry},
year = {1996},
volume = {34},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002%2F%28SICI%291099-0518%2819960115%2934%3A1%3C57%3A%3AAID-POLA5%3E3.0.CO%3B2-0},
number = {1},
pages = {57--62},
doi = {10.1002/(SICI)1099-0518(19960115)34:1<57::AID-POLA5>3.0.CO;2-0}
}
MLA
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MLA Copy
Kato, Takashi, et al. “Supramolecular hydrogen-bonded liquid-crystalline polymer complexes. Design of side-chain polymers and a host-guest system by noncovalent interaction.” Journal of Polymer Science, Part A: Polymer Chemistry, vol. 34, no. 1, Jan. 1996, pp. 57-62. https://doi.org/10.1002%2F%28SICI%291099-0518%2819960115%2934%3A1%3C57%3A%3AAID-POLA5%3E3.0.CO%3B2-0.
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