Advanced Optical Materials, volume 9, issue 9, pages 2100053
Photoalignment in Polysiloxane Liquid‐Crystalline Elastomers with Rearrangeable Networks
1
Research and Development Initiative Chuo University 1‐13‐27, Kasuga, Bunkyo‐ku Tokyo 112‐8551 Japan
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2
Technical Institute of Physics and Chemistry Chinese Academy of Sciences 29 Zhongguancun East Road Beijing 100190 China
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Publication type: Journal Article
Publication date: 2021-02-16
Journal:
Advanced Optical Materials
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 9
ISSN: 21951071
Electronic, Optical and Magnetic Materials
Atomic and Molecular Physics, and Optics
Abstract
Molecular alignment in liquid‐crystalline elastomers with polysiloxane backbone is controlled with the aid of photoalignment and exchangeable links to enhance performance as photoactuators. The photoalignment is triggered by trans‐cis‐trans isomerization of azobenzene moieties, which are introduced at crosslinking points, upon irradiation with linearly polarized UV (LPUV) light under heating. The induced alignment is memorized by rearrangement of network structures through exchange reactions of covalent bonds. When irradiated with LPUV light, freestanding films show bending along with the alignment change in surface regions. Macroscopic shapes are also rememorized by exchange reactions at crosslinks. Combination of photoalignment and network rearrangement allows continuous deformation of freestanding films upon exposure to LPUV light with varying polarization directions. This approach enhances the degree of freedom in alignment control, photoactuation, and reshaping of polysiloxane‐based liquid‐crystalline elastomers, which are feasible as soft actuators.
Citations by journals
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Liquid Crystals
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Liquid Crystals
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Journal of Sol-Gel Science and Technology
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Journal of Sol-Gel Science and Technology
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Angewandte Chemie
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Angewandte Chemie - International Edition
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Physical Chemistry Chemical Physics
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ACS Applied Polymer Materials
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ACS Applied Polymer Materials
1 publication, 4%
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Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films
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Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films
1 publication, 4%
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Polymers
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Polymers
1 publication, 4%
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Applied Physics A: Materials Science and Processing
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Applied Physics A: Materials Science and Processing
1 publication, 4%
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Current Opinion in Solid State and Materials Science
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Current Opinion in Solid State and Materials Science
1 publication, 4%
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Polymer
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Polymer
1 publication, 4%
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Journal of Materials Research and Technology
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Journal of Materials Research and Technology
1 publication, 4%
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FlatChem
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FlatChem
1 publication, 4%
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Chemistry - A European Journal
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Chemistry - A European Journal
1 publication, 4%
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Polymers for Advanced Technologies
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Polymers for Advanced Technologies
1 publication, 4%
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Macromolecules
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Macromolecules
1 publication, 4%
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Macromolecular Chemistry and Physics
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Macromolecular Chemistry and Physics
1 publication, 4%
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Advanced Functional Materials
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Advanced Functional Materials
1 publication, 4%
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ACS Omega
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ACS Omega
1 publication, 4%
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Journal of Hazardous Materials
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Journal of Hazardous Materials
1 publication, 4%
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Responsive Materials
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Responsive Materials
1 publication, 4%
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Citations by publishers
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9
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Wiley
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Wiley
9 publications, 36%
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Elsevier
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Elsevier
5 publications, 20%
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American Chemical Society (ACS)
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American Chemical Society (ACS)
3 publications, 12%
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Springer Nature
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Springer Nature
3 publications, 12%
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Taylor & Francis
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Taylor & Francis
2 publications, 8%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
1 publication, 4%
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American Institute of Physics (AIP)
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American Institute of Physics (AIP)
1 publication, 4%
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 4%
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Ube T. et al. Photoalignment in Polysiloxane Liquid‐Crystalline Elastomers with Rearrangeable Networks // Advanced Optical Materials. 2021. Vol. 9. No. 9. p. 2100053.
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Ube T., Tsunoda H., Kawasaki K., IKEDA T. Photoalignment in Polysiloxane Liquid‐Crystalline Elastomers with Rearrangeable Networks // Advanced Optical Materials. 2021. Vol. 9. No. 9. p. 2100053.
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TY - JOUR
DO - 10.1002/adom.202100053
UR - https://doi.org/10.1002%2Fadom.202100053
TI - Photoalignment in Polysiloxane Liquid‐Crystalline Elastomers with Rearrangeable Networks
T2 - Advanced Optical Materials
AU - Tsunoda, Haruna
AU - Kawasaki, Kyohei
AU - Ube, Toru
AU - IKEDA, T
PY - 2021
DA - 2021/02/16 00:00:00
PB - Wiley
SP - 2100053
IS - 9
VL - 9
SN - 2195-1071
ER -
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@article{2021_Ube,
author = {Haruna Tsunoda and Kyohei Kawasaki and Toru Ube and T IKEDA},
title = {Photoalignment in Polysiloxane Liquid‐Crystalline Elastomers with Rearrangeable Networks},
journal = {Advanced Optical Materials},
year = {2021},
volume = {9},
publisher = {Wiley},
month = {feb},
url = {https://doi.org/10.1002%2Fadom.202100053},
number = {9},
pages = {2100053},
doi = {10.1002/adom.202100053}
}
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Ube, Toru, et al. “Photoalignment in Polysiloxane Liquid‐Crystalline Elastomers with Rearrangeable Networks.” Advanced Optical Materials, vol. 9, no. 9, Feb. 2021, p. 2100053. https://doi.org/10.1002%2Fadom.202100053.