Advanced Synthesis and Catalysis, volume 364, issue 13, pages 2248-2253

Catalyst‐Free Visible Light Mediated Synthesis of Unsymmetrical Tertiary Arylphosphines

Publication typeJournal Article
Publication date2022-05-24
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor5.4
ISSN16154150, 16154169
General Chemistry
Abstract
Arylation of tertiary aryl and alkyl phosphines bearing 2-cyanoethyl group with aryl(mesityl)iodonium triflates under blue light irradiation followed by retro-Michael reaction of the in situ generated quaternary phosphonium salts initiated by DBU represent a novel efficient and general method for the preparation of distinctly substituted tertiary arylphosphines. An operationally simple, one-pot protocol features mild, transition-metal-free conditions, high selectivity, broad functional group compatibility, as well as scalability and would be applied to substrates with different electronic and steric nature.

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Bugaenko D. I. Catalyst‐Free Visible Light Mediated Synthesis of Unsymmetrical Tertiary Arylphosphines // Advanced Synthesis and Catalysis. 2022. Vol. 364. No. 13. pp. 2248-2253.
GOST all authors (up to 50) Copy
Bugaenko D. I. Catalyst‐Free Visible Light Mediated Synthesis of Unsymmetrical Tertiary Arylphosphines // Advanced Synthesis and Catalysis. 2022. Vol. 364. No. 13. pp. 2248-2253.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/adsc.202200309
UR - https://doi.org/10.1002%2Fadsc.202200309
TI - Catalyst‐Free Visible Light Mediated Synthesis of Unsymmetrical Tertiary Arylphosphines
T2 - Advanced Synthesis and Catalysis
AU - Bugaenko, Dmitry I
PY - 2022
DA - 2022/05/24 00:00:00
PB - Wiley
SP - 2248-2253
IS - 13
VL - 364
SN - 1615-4150
SN - 1615-4169
ER -
BibTex |
Cite this
BibTex Copy
@article{2022_Bugaenko,
author = {Dmitry I Bugaenko},
title = {Catalyst‐Free Visible Light Mediated Synthesis of Unsymmetrical Tertiary Arylphosphines},
journal = {Advanced Synthesis and Catalysis},
year = {2022},
volume = {364},
publisher = {Wiley},
month = {may},
url = {https://doi.org/10.1002%2Fadsc.202200309},
number = {13},
pages = {2248--2253},
doi = {10.1002/adsc.202200309}
}
MLA
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MLA Copy
Bugaenko, Dmitry I.. “Catalyst‐Free Visible Light Mediated Synthesis of Unsymmetrical Tertiary Arylphosphines.” Advanced Synthesis and Catalysis, vol. 364, no. 13, May. 2022, pp. 2248-2253. https://doi.org/10.1002%2Fadsc.202200309.
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