Applied Organometallic Chemistry, volume 35, issue 4
Schiff base complexes with different metals incorporating derivatives of 3,6‐di‐ tert ‐butylcarbazole
Publication type: Journal Article
Publication date: 2021-01-05
Journal:
Applied Organometallic Chemistry
Quartile SCImago
Q2
Quartile WOS
Q1
Impact factor: 3.9
ISSN: 02682605, 10990739
DOI:
10.1002/aoc.6145
General Chemistry
Inorganic Chemistry
Abstract
Four new mononuclear complexes formed by the asymmetric azomethine ligand have been synthesized and characterized. Fe (III), Ga (III), Cu (II), and Co (II) ions were used as a central metal ion. The chelating ligand contains derivatives of 3,6‐di‐tert‐butylcarbazole as a chromophor. The data of far FT‐IR spectroscopy and mass spectrometry confirmed the formation of HCN bond and the coordination of metal ion through deprotonated oxygen and azomethine nitrogen. The X‐ray powder analysis of polycrystalline complexes showed that the crystal cells of all complexes are triclinic, with unit cells containing four molecules each. The counter‐ions are regularly embedded into the crystalline lattice. The conformation of the molecules of all complexes is elongated and symmetric. The thermal gravimetric analysis showed a high stability of all complexes above 200°C. The UV–Vis and fluorescence spectral data of the synthesized compounds were obtained in acetone, benzene, dichloromethane, chloroform, DMA, DMF, DMSO, and THF. The complexes show intensive π–π*, n–π*, and charge‐transfer (CT) bands in the range from 200 to 400 nm in all solvents, whereas the ligand shows intensive π–π*, n–π* bands only. A strong red shift (21–31 nm) of the emission band maximum of the complexes is observed upon transition from nonpolar to polar solvents.
Citations by journals
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Optical Materials
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Optical Materials
2 publications, 40%
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Symmetry
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Symmetry
1 publication, 20%
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RSC Advances
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RSC Advances
1 publication, 20%
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Applied Organometallic Chemistry
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Applied Organometallic Chemistry
1 publication, 20%
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Citations by publishers
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Elsevier
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Elsevier
2 publications, 40%
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 20%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
1 publication, 20%
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Wiley
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Wiley
1 publication, 20%
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1
2
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- Statistics recalculated weekly.
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Gruzdev M. S. et al. Schiff base complexes with different metals incorporating derivatives of 3,6‐di‐ tert ‐butylcarbazole // Applied Organometallic Chemistry. 2021. Vol. 35. No. 4.
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Gruzdev M. S., Chervonova U. V., Ksenofontov A. A., Krestyaninov M. A., Alexandrov A., Pashkova T. Schiff base complexes with different metals incorporating derivatives of 3,6‐di‐ tert ‐butylcarbazole // Applied Organometallic Chemistry. 2021. Vol. 35. No. 4.
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TY - JOUR
DO - 10.1002/aoc.6145
UR - https://doi.org/10.1002%2Faoc.6145
TI - Schiff base complexes with different metals incorporating derivatives of 3,6‐di‐ tert ‐butylcarbazole
T2 - Applied Organometallic Chemistry
AU - Gruzdev, Matvey S
AU - Chervonova, U V
AU - Ksenofontov, Alexander A
AU - Krestyaninov, Mikhail A.
AU - Alexandrov, A.I.
AU - Pashkova, T.V.
PY - 2021
DA - 2021/01/05 00:00:00
PB - Wiley
IS - 4
VL - 35
SN - 0268-2605
SN - 1099-0739
ER -
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@article{2021_Gruzdev,
author = {Matvey S Gruzdev and U V Chervonova and Alexander A Ksenofontov and Mikhail A. Krestyaninov and A.I. Alexandrov and T.V. Pashkova},
title = {Schiff base complexes with different metals incorporating derivatives of 3,6‐di‐ tert ‐butylcarbazole},
journal = {Applied Organometallic Chemistry},
year = {2021},
volume = {35},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002%2Faoc.6145},
number = {4},
doi = {10.1002/aoc.6145}
}