Journal of Applied Polymer Science, volume 134, issue 18
Dual-curing thermosetting monomer containing both propargyl ether and phthalonitrile groups
Bulgakov Boris
1
,
Sulimov A V
2
,
Babkin Alexander
3
,
Kepman A.V.
1, 3
,
Malakho A.P
1
,
Avdeev V.V.
1
3
Institute of New Carbon Materials and Technologies, Leninskie gory st, 1-11; Moscow 119991 Russia
|
Publication type: Journal Article
Publication date: 2017-01-06
Journal:
Journal of Applied Polymer Science
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor: 3
ISSN: 00218995, 10974628
Materials Chemistry
Surfaces, Coatings and Films
General Chemistry
Polymers and Plastics
Abstract
Novel self-curing monomer containing two thermosetting groups, namely propargyl ether and phthalonitrile (PN) in a molecular structure, is synthesized and investigated. The study of catalyzed and uncatalyzed curing is performed and high heat release during curing is observed. This disadvantage can be adjusted by catalysis of propargyl ether polymerization with Ni (II), Co (II), and Cu (II) salts. The cured monomer possesses high thermal properties featured to phthalonitrile matrices (Heat deflection temperature, HDT = 428 °C, T5% = 499 °C) and moderate mechanical properties (E = 4.9 ± 0.65 GPa, GIC = 106 ± 26 J/m2), it can be applied as a high temperature matrix for carbon fiber reinforced plastics (CFRP). Low melt viscosity (223 mPa s at 120 °C) of the monomer provides a possibility to consider its application for composite material formation by vacuum infusion or resin transfer molding (RTM) techniques, which are exceptionally rarely applied for matrices with HDT > 300 °C but allow to obtain composites of complex shape with minimal joining parts. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 133, 44786.
Citations by journals
1
2
3
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Polymer
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Polymer
3 publications, 12.5%
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European Polymer Journal
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European Polymer Journal
3 publications, 12.5%
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Reactive and Functional Polymers
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Reactive and Functional Polymers
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IOP Conference Series: Materials Science and Engineering
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IOP Conference Series: Materials Science and Engineering
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Polymers
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Polymers
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Journal of Applied Polymer Science
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Journal of Applied Polymer Science
2 publications, 8.33%
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Mendeleev Communications
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Mendeleev Communications
1 publication, 4.17%
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Eurasian Chemico-Technological Journal
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Eurasian Chemico-Technological Journal, 1, 4.17%
Eurasian Chemico-Technological Journal
1 publication, 4.17%
|
Polymer Science - Series C
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Polymer Science - Series C
1 publication, 4.17%
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ACS Applied Polymer Materials
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ACS Applied Polymer Materials
1 publication, 4.17%
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High Performance Polymers
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High Performance Polymers
1 publication, 4.17%
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Catalysts
|
Catalysts
1 publication, 4.17%
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Chinese Journal of Polymer Science (English Edition)
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Chinese Journal of Polymer Science (English Edition)
1 publication, 4.17%
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Polymers for Advanced Technologies
|
Polymers for Advanced Technologies
1 publication, 4.17%
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Polymer Science - Series B
|
Polymer Science - Series B
1 publication, 4.17%
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1
2
3
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Citations by publishers
1
2
3
4
5
6
7
8
9
|
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Elsevier
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Elsevier
9 publications, 37.5%
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
3 publications, 12.5%
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Wiley
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Wiley
3 publications, 12.5%
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IOP Publishing
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IOP Publishing
2 publications, 8.33%
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Pleiades Publishing
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Pleiades Publishing
2 publications, 8.33%
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Institute of New Chemical Technologies and Materials of Al-Farabi Kazakh State National University
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Institute of New Chemical Technologies and Materials of Al-Farabi Kazakh State National University, 1, 4.17%
Institute of New Chemical Technologies and Materials of Al-Farabi Kazakh State National University
1 publication, 4.17%
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American Chemical Society (ACS)
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American Chemical Society (ACS)
1 publication, 4.17%
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SAGE
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SAGE
1 publication, 4.17%
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Springer Nature
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Springer Nature
1 publication, 4.17%
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1
2
3
4
5
6
7
8
9
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Bulgakov B. et al. Dual-curing thermosetting monomer containing both propargyl ether and phthalonitrile groups // Journal of Applied Polymer Science. 2017. Vol. 134. No. 18.
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Bulgakov B., Sulimov A. V., Babkin A., Kepman A., Malakho A., Avdeev V. Dual-curing thermosetting monomer containing both propargyl ether and phthalonitrile groups // Journal of Applied Polymer Science. 2017. Vol. 134. No. 18.
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TY - JOUR
DO - 10.1002/app.44786
UR - https://doi.org/10.1002%2Fapp.44786
TI - Dual-curing thermosetting monomer containing both propargyl ether and phthalonitrile groups
T2 - Journal of Applied Polymer Science
AU - Sulimov, A V
AU - Kepman, A.V.
AU - Bulgakov, Boris
AU - Babkin, Alexander
AU - Malakho, A.P
AU - Avdeev, V.V.
PY - 2017
DA - 2017/01/06 00:00:00
PB - Wiley
IS - 18
VL - 134
SN - 0021-8995
SN - 1097-4628
ER -
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@article{2017_Bulgakov
author = {A V Sulimov and A.V. Kepman and Boris Bulgakov and Alexander Babkin and A.P Malakho and V.V. Avdeev},
title = {Dual-curing thermosetting monomer containing both propargyl ether and phthalonitrile groups},
journal = {Journal of Applied Polymer Science},
year = {2017},
volume = {134},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002%2Fapp.44786},
number = {18},
doi = {10.1002/app.44786}
}