Journal of Applied Polymer Science, volume 134, issue 18

Dual-curing thermosetting monomer containing both propargyl ether and phthalonitrile groups

Publication typeJournal Article
Publication date2017-01-06
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor3
ISSN00218995, 10974628
Materials Chemistry
Surfaces, Coatings and Films
General Chemistry
Polymers and Plastics
Abstract
Novel self-curing monomer containing two thermosetting groups, namely propargyl ether and phthalonitrile (PN) in a molecular structure, is synthesized and investigated. The study of catalyzed and uncatalyzed curing is performed and high heat release during curing is observed. This disadvantage can be adjusted by catalysis of propargyl ether polymerization with Ni (II), Co (II), and Cu (II) salts. The cured monomer possesses high thermal properties featured to phthalonitrile matrices (Heat deflection temperature, HDT = 428 °C, T5% = 499 °C) and moderate mechanical properties (E = 4.9 ± 0.65 GPa, GIC = 106 ± 26 J/m2), it can be applied as a high temperature matrix for carbon fiber reinforced plastics (CFRP). Low melt viscosity (223 mPa s at 120 °C) of the monomer provides a possibility to consider its application for composite material formation by vacuum infusion or resin transfer molding (RTM) techniques, which are exceptionally rarely applied for matrices with HDT > 300 °C but allow to obtain composites of complex shape with minimal joining parts. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 133, 44786.

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Bulgakov B. et al. Dual-curing thermosetting monomer containing both propargyl ether and phthalonitrile groups // Journal of Applied Polymer Science. 2017. Vol. 134. No. 18.
GOST all authors (up to 50) Copy
Bulgakov B., Sulimov A. V., Babkin A., Kepman A., Malakho A., Avdeev V. Dual-curing thermosetting monomer containing both propargyl ether and phthalonitrile groups // Journal of Applied Polymer Science. 2017. Vol. 134. No. 18.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/app.44786
UR - https://doi.org/10.1002%2Fapp.44786
TI - Dual-curing thermosetting monomer containing both propargyl ether and phthalonitrile groups
T2 - Journal of Applied Polymer Science
AU - Sulimov, A V
AU - Kepman, A.V.
AU - Bulgakov, Boris
AU - Babkin, Alexander
AU - Malakho, A.P
AU - Avdeev, V.V.
PY - 2017
DA - 2017/01/06 00:00:00
PB - Wiley
IS - 18
VL - 134
SN - 0021-8995
SN - 1097-4628
ER -
BibTex
Cite this
BibTex Copy
@article{2017_Bulgakov
author = {A V Sulimov and A.V. Kepman and Boris Bulgakov and Alexander Babkin and A.P Malakho and V.V. Avdeev},
title = {Dual-curing thermosetting monomer containing both propargyl ether and phthalonitrile groups},
journal = {Journal of Applied Polymer Science},
year = {2017},
volume = {134},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002%2Fapp.44786},
number = {18},
doi = {10.1002/app.44786}
}
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