Chemistry - A European Journal, volume 9, issue 19, pages 4661-4669
Synthesis, structure, and spectroscopy of phenylacetylenylene rods incorporating meso-substituted dipyrrin ligands.
1
Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA 92093‐0358, USA, Fax: (+1) 858‐822‐5598
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Publication type: Journal Article
Publication date: 2003-10-06
Journal:
Chemistry - A European Journal
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 4.3
ISSN: 09476539, 15213765
General Chemistry
Catalysis
Organic Chemistry
Abstract
The synthesis, structure, and spectroscopic characterization of a series of phenylacetylenylene rodlike molecules containing dipyrromethene (dipyrrin) ligands are described. The combination of the phenylacetylenylene groups with the porphyrinogenic dipyrrin moieties results in a rich absorption spectroscopy for these compounds, although the fluorescence of the phenylacetylenylene moiety is quenched by presence of the dipyrrin chelator. The Cu(2+) and Fe(3+) complexes of these ligands have been prepared and three of these compounds have been structurally characterized by using single-crystal X-ray diffraction. Unlike other octahedral metal-dipyrrin complexes described to date, one of the iron complexes demonstrates ideal threefold symmetry in the solid-state. The elongated structure and high symmetry of these complexes suggests the use of these meso-substituted phenylacetylenylene ligands as an interesting class of extended, branched molecules for the construction of supramolecular architectures.
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5
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25
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Halper S. R., Cohen S. M. Synthesis, structure, and spectroscopy of phenylacetylenylene rods incorporating meso-substituted dipyrrin ligands. // Chemistry - A European Journal. 2003. Vol. 9. No. 19. pp. 4661-4669.
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Halper S. R., Cohen S. M. Synthesis, structure, and spectroscopy of phenylacetylenylene rods incorporating meso-substituted dipyrrin ligands. // Chemistry - A European Journal. 2003. Vol. 9. No. 19. pp. 4661-4669.
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TY - JOUR
DO - 10.1002/chem.200305041
UR - https://doi.org/10.1002%2Fchem.200305041
TI - Synthesis, structure, and spectroscopy of phenylacetylenylene rods incorporating meso-substituted dipyrrin ligands.
T2 - Chemistry - A European Journal
AU - Halper, Sara R
AU - Cohen, Seth M
PY - 2003
DA - 2003/10/06 00:00:00
PB - Wiley
SP - 4661-4669
IS - 19
VL - 9
SN - 0947-6539
SN - 1521-3765
ER -
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@article{2003_Halper,
author = {Sara R Halper and Seth M Cohen},
title = {Synthesis, structure, and spectroscopy of phenylacetylenylene rods incorporating meso-substituted dipyrrin ligands.},
journal = {Chemistry - A European Journal},
year = {2003},
volume = {9},
publisher = {Wiley},
month = {oct},
url = {https://doi.org/10.1002%2Fchem.200305041},
number = {19},
pages = {4661--4669},
doi = {10.1002/chem.200305041}
}
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Halper, Sara R., and Seth M Cohen. “Synthesis, structure, and spectroscopy of phenylacetylenylene rods incorporating meso-substituted dipyrrin ligands..” Chemistry - A European Journal, vol. 9, no. 19, Oct. 2003, pp. 4661-4669. https://doi.org/10.1002%2Fchem.200305041.