ChemSusChem, volume 14, issue 17, pages 3494-3501
Reducing energy loss in organic solar cells by changing the central metal in metalloporphyrins.
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Department of inorganic, organic and biochemistry Universidad de Castilla – La Mancha Institute of Nanoscience, Nanotechnology and Molecular Materials (INAMOL) Campus de la Fábrica de Armas Toledo Spain
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2
Department of Physics Malviya National Institute of Technology, JLN Marg Jaipur (Raj.) 302017 India
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Publication type: Journal Article
Publication date: 2020-12-16
Journal:
ChemSusChem
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 8.4
ISSN: 18645631, 1864564X
General Chemical Engineering
General Materials Science
General Energy
Environmental Chemistry
Abstract
The effect of central donor core on the properties of A-π-D-π-A donors where D is a porphyrin macrocycle was investigated for the fabrication of the organic solar cells, along PC 71 BM as electron acceptor. A new molecule consisting of Ni-porphyrin central donor core ( VC9 ) showed deep HOMO energy level and OSCs based on optimized VC9 :PC 71 BM realized overall power conversion efficiency (PCE) of 10.66% (J SC = 15.48 mA/cm 2 , FF = 0.65) with high open circuit voltage of 1.06 V with very low energy loss of 0.49 eV whereas VC8 :PC 71 BM counterpart showed PCE of 9.69% with V OC of 0.89 V, J SC of 16.25 mA/cm 2 and FF of 0.67. Although the OSCs based on the Zn-Porphyrin analogous VC8 showed higher J SC in comparison to VC9 , originated from the broader absorption profile of VC8 , leading the more exciton generation, the higher value of PCE of VC9 is due to higher value of V OC and reduced energy loss.
Citations by journals
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2
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ACS applied materials & interfaces
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ACS applied materials & interfaces
2 publications, 33.33%
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International Journal of Molecular Sciences
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International Journal of Molecular Sciences
1 publication, 16.67%
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Solar RRL
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Solar RRL
1 publication, 16.67%
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ACS Applied Energy Materials
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ACS Applied Energy Materials
1 publication, 16.67%
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Journal of Materials Chemistry A
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Journal of Materials Chemistry A
1 publication, 16.67%
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2
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Citations by publishers
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3
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American Chemical Society (ACS)
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American Chemical Society (ACS)
3 publications, 50%
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 16.67%
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Wiley
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Wiley
1 publication, 16.67%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
1 publication, 16.67%
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Cuesta V. et al. Reducing energy loss in organic solar cells by changing the central metal in metalloporphyrins. // ChemSusChem. 2020. Vol. 14. No. 17. pp. 3494-3501.
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Cuesta V., Singhal R., de la Cruz P., Sharma G. D., Langa F. Reducing energy loss in organic solar cells by changing the central metal in metalloporphyrins. // ChemSusChem. 2020. Vol. 14. No. 17. pp. 3494-3501.
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TY - JOUR
DO - 10.1002/cssc.202002664
UR - https://doi.org/10.1002%2Fcssc.202002664
TI - Reducing energy loss in organic solar cells by changing the central metal in metalloporphyrins.
T2 - ChemSusChem
AU - Cuesta, Virginia
AU - Singhal, Rahul
AU - de la Cruz, Pilar
AU - Sharma, Ganesh Datt
AU - Langa, Fernando
PY - 2020
DA - 2020/12/16 00:00:00
PB - Wiley
SP - 3494-3501
IS - 17
VL - 14
SN - 1864-5631
SN - 1864-564X
ER -
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@article{2020_Cuesta,
author = {Virginia Cuesta and Rahul Singhal and Pilar de la Cruz and Ganesh Datt Sharma and Fernando Langa},
title = {Reducing energy loss in organic solar cells by changing the central metal in metalloporphyrins.},
journal = {ChemSusChem},
year = {2020},
volume = {14},
publisher = {Wiley},
month = {dec},
url = {https://doi.org/10.1002%2Fcssc.202002664},
number = {17},
pages = {3494--3501},
doi = {10.1002/cssc.202002664}
}
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Cuesta, Virginia, et al. “Reducing energy loss in organic solar cells by changing the central metal in metalloporphyrins..” ChemSusChem, vol. 14, no. 17, Dec. 2020, pp. 3494-3501. https://doi.org/10.1002%2Fcssc.202002664.