volume 2005 issue 23 pages 5055-5066

Cyclopentathiadiazines, Cyclohepta- and Cyclopentadithiazoles: New Materials and a Rich Heterocyclic Chemistry of Cyclic Enaminonitriles

Publication typeJournal Article
Publication date2005-12-01
scimago Q2
wos Q2
SJR0.558
CiteScore4.3
Impact factor2.7
ISSN1434193X, 10990690
Organic Chemistry
Physical and Theoretical Chemistry
Abstract
3-Amino-1H-indene-2-carbonitrile and 2-amino-3H-indene-1-carbonitrile reacted with SCl2, iBu3N and NCS to give benzocyclopenta[1,2,6]thiadiazines, and whilst 2-aminocyclopent-1-enecarbonitrile gave, under the same conditions, a cyclopenta[1,2,6]thiadiazine, its reaction with mixtures of S2Cl2, SCl2 and iBu3N under different conditions gave, selectively, an isothiazolo[3,4-d]cyclopenta[1,2,3]dithiazole and new cyclopenta[1,2,3]dithiazole derivatives. Similarly, 2-aminocyclohept-1-enecarbonitrile reacted with SCl2, iBu3N and NCS to give a formally antiaromatic cyclohepta[1,2,3]dithiazole. Some of the compounds obtained showed characteristics useful as new materials, for example, as liquid crystals and near-infrared dyes. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
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GOST Copy
Gomez T. et al. Cyclopentathiadiazines, Cyclohepta- and Cyclopentadithiazoles: New Materials and a Rich Heterocyclic Chemistry of Cyclic Enaminonitriles // European Journal of Organic Chemistry. 2005. Vol. 2005. No. 23. pp. 5055-5066.
GOST all authors (up to 50) Copy
Gomez T., Macho S., Miguel D., Neo A. G., Rodríguez T., Torroba T. Cyclopentathiadiazines, Cyclohepta- and Cyclopentadithiazoles: New Materials and a Rich Heterocyclic Chemistry of Cyclic Enaminonitriles // European Journal of Organic Chemistry. 2005. Vol. 2005. No. 23. pp. 5055-5066.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/ejoc.200500551
UR - https://doi.org/10.1002/ejoc.200500551
TI - Cyclopentathiadiazines, Cyclohepta- and Cyclopentadithiazoles: New Materials and a Rich Heterocyclic Chemistry of Cyclic Enaminonitriles
T2 - European Journal of Organic Chemistry
AU - Gomez, Teresa
AU - Macho, Sonia
AU - Miguel, D.
AU - Neo, Ana G
AU - Rodríguez, Teresa
AU - Torroba, Tomás
PY - 2005
DA - 2005/12/01
PB - Wiley
SP - 5055-5066
IS - 23
VL - 2005
SN - 1434-193X
SN - 1099-0690
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2005_Gomez,
author = {Teresa Gomez and Sonia Macho and D. Miguel and Ana G Neo and Teresa Rodríguez and Tomás Torroba},
title = {Cyclopentathiadiazines, Cyclohepta- and Cyclopentadithiazoles: New Materials and a Rich Heterocyclic Chemistry of Cyclic Enaminonitriles},
journal = {European Journal of Organic Chemistry},
year = {2005},
volume = {2005},
publisher = {Wiley},
month = {dec},
url = {https://doi.org/10.1002/ejoc.200500551},
number = {23},
pages = {5055--5066},
doi = {10.1002/ejoc.200500551}
}
MLA
Cite this
MLA Copy
Gomez, Teresa, et al. “Cyclopentathiadiazines, Cyclohepta- and Cyclopentadithiazoles: New Materials and a Rich Heterocyclic Chemistry of Cyclic Enaminonitriles.” European Journal of Organic Chemistry, vol. 2005, no. 23, Dec. 2005, pp. 5055-5066. https://doi.org/10.1002/ejoc.200500551.