Macromolecular Rapid Communications, volume 42, issue 1, pages 2000450
Multicomponent Stress-Sensing Composites Fabricated by 3D-Printing Methodologies.
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Chair of Macromolecular Chemistry Division of Technical and Macromolecular Chemistry Institute of Chemistry Faculty of Natural Sciences II (Chemistry, Physics and Mathematics) Martin Luther University Halle‐Wittenberg von‐Danckelmann‐Platz 4 Halle D‐06120 Germany
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Publication type: Journal Article
Publication date: 2020-10-13
Journal:
Macromolecular Rapid Communications
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4.6
ISSN: 10221336, 15213927
Materials Chemistry
Organic Chemistry
Polymers and Plastics
Abstract
The preparation and characterization of mechanoresponsive, 3D-printed composites are reported using a dual-printing setup for both, liquid dispensing and fused-deposition-modeling. The here reported stress-sensing materials are based on high- and low molecular weight mechanophores, including poly(ε-caprolactone)-, polyurethane-, and alkyl(C11)-based latent copper(I)bis(N-heterocyclic carbenes), which can be activated by compression to trigger a fluorogenic, copper(I)-catalyzed azide/alkyne "click"-reaction of an azide-functionalized fluorescent dye inside a bulk polymeric material. Focus is placed on the printability and postprinting activity of the latent mechanophores and the fluorogenic "click"-components. The multicomponent specimen containing both, azide and alkyne, are manufactured via a 3D-printer to place the components separately inside the specimen into void spaces generated during the FDM-process, which subsequently are filled with liquids using a separate liquid dispenser, located within the same 3D-printing system. The low-molecular weight mechanophores bearing the alkyl-C11 chains display the best printability, yielding a mechanochemical response after the 3D-printing process.
Citations by journals
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2
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Polymers
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2 publications, 12.5%
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1 publication, 6.25%
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1 publication, 6.25%
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1 publication, 6.25%
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International Journal of Pharmaceutics
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International Journal of Pharmaceutics
1 publication, 6.25%
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Angewandte Chemie
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Angewandte Chemie
1 publication, 6.25%
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Chemie in Unserer Zeit
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1 publication, 6.25%
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Advanced Materials Technologies
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1 publication, 6.25%
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1 publication, 6.25%
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Materials Advances
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1 publication, 6.25%
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Chemical Communications
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1 publication, 6.25%
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Angewandte Chemie - International Edition
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Angewandte Chemie - International Edition
1 publication, 6.25%
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Polymer
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1 publication, 6.25%
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2
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Citations by publishers
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6
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Wiley
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Wiley
6 publications, 37.5%
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
4 publications, 25%
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Elsevier
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Elsevier
2 publications, 12.5%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
2 publications, 12.5%
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Frontiers Media S.A.
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Frontiers Media S.A.
1 publication, 6.25%
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American Chemical Society (ACS)
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American Chemical Society (ACS)
1 publication, 6.25%
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Rupp H., Binder W. H. Multicomponent Stress-Sensing Composites Fabricated by 3D-Printing Methodologies. // Macromolecular Rapid Communications. 2020. Vol. 42. No. 1. p. 2000450.
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Rupp H., Binder W. H. Multicomponent Stress-Sensing Composites Fabricated by 3D-Printing Methodologies. // Macromolecular Rapid Communications. 2020. Vol. 42. No. 1. p. 2000450.
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TY - JOUR
DO - 10.1002/marc.202000450
UR - https://doi.org/10.1002%2Fmarc.202000450
TI - Multicomponent Stress-Sensing Composites Fabricated by 3D-Printing Methodologies.
T2 - Macromolecular Rapid Communications
AU - Binder, Wolfgang H.
AU - Rupp, Harald
PY - 2020
DA - 2020/10/13 00:00:00
PB - Wiley
SP - 2000450
IS - 1
VL - 42
SN - 1022-1336
SN - 1521-3927
ER -
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@article{2020_Rupp,
author = {Wolfgang H. Binder and Harald Rupp},
title = {Multicomponent Stress-Sensing Composites Fabricated by 3D-Printing Methodologies.},
journal = {Macromolecular Rapid Communications},
year = {2020},
volume = {42},
publisher = {Wiley},
month = {oct},
url = {https://doi.org/10.1002%2Fmarc.202000450},
number = {1},
pages = {2000450},
doi = {10.1002/marc.202000450}
}
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MLA
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Rupp, Harald, and Wolfgang H. Binder. “Multicomponent Stress-Sensing Composites Fabricated by 3D-Printing Methodologies..” Macromolecular Rapid Communications, vol. 42, no. 1, Oct. 2020, p. 2000450. https://doi.org/10.1002%2Fmarc.202000450.