Journal of Polymer Science, Part B: Polymer Physics, volume 43, issue 17, pages 2352-2360
Kinetically controlled phase transitions in liquid-crystalline polymers. III. Influence of the molecular weight and annealing temperature on two-dimensional K phase formation in a side-chain polyacrylate
2
Ernst‐Berl‐Institute of Technical Engineering and Macromolecular Science, Darmstadt University of Technology, Petersenstraße 22, D‐64287 Darmstadt, Germany
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Publication type: Journal Article
Publication date: 2005-07-14
Quartile SCImago
Q2
Quartile WOS
—
Impact factor: —
ISSN: 08876266, 10990488
Materials Chemistry
Physical and Theoretical Chemistry
Condensed Matter Physics
Polymers and Plastics
Abstract
Narrow fractions of a side-chain acrylate oligomer/polymer with phenyl benzoate side chains are separated in a broad range of the degree of polymerization (7 ≤ Pw ≤ 149). An examination of the phase behavior of the obtained fractions has shown that only the longer macromolecules can form the two-dimensional K (TDK) mesophase, whereas oligomers of a shorter main chain form the conventional nematic phase only. A critical Pw value has been observed to be necessary for the TDK mesophase formation. The temperatures and enthalpies of liquid-crystalline phase transitions have been studied as a function of the molar mass, and the phase-growth kinetics for the TDK phase have been studied with an Avrami treatment. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 2352–2360, 2005
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Citations by publishers
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1 publication, 3.57%
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American Physical Society (APS)
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American Physical Society (APS)
1 publication, 3.57%
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Springer Nature
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Springer Nature
1 publication, 3.57%
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Boiko N. I., Shibaev V., Kozlovsky M. Kinetically controlled phase transitions in liquid-crystalline polymers. III. Influence of the molecular weight and annealing temperature on two-dimensional K phase formation in a side-chain polyacrylate // Journal of Polymer Science, Part B: Polymer Physics. 2005. Vol. 43. No. 17. pp. 2352-2360.
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Boiko N. I., Shibaev V., Kozlovsky M. Kinetically controlled phase transitions in liquid-crystalline polymers. III. Influence of the molecular weight and annealing temperature on two-dimensional K phase formation in a side-chain polyacrylate // Journal of Polymer Science, Part B: Polymer Physics. 2005. Vol. 43. No. 17. pp. 2352-2360.
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TY - JOUR
DO - 10.1002/polb.20521
UR - https://doi.org/10.1002%2Fpolb.20521
TI - Kinetically controlled phase transitions in liquid-crystalline polymers. III. Influence of the molecular weight and annealing temperature on two-dimensional K phase formation in a side-chain polyacrylate
T2 - Journal of Polymer Science, Part B: Polymer Physics
AU - Boiko, N. I.
AU - Shibaev, Valery
AU - Kozlovsky, M.
PY - 2005
DA - 2005/07/14 00:00:00
PB - Wiley
SP - 2352-2360
IS - 17
VL - 43
SN - 0887-6266
SN - 1099-0488
ER -
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@article{2005_Boiko,
author = {N. I. Boiko and Valery Shibaev and M. Kozlovsky},
title = {Kinetically controlled phase transitions in liquid-crystalline polymers. III. Influence of the molecular weight and annealing temperature on two-dimensional K phase formation in a side-chain polyacrylate},
journal = {Journal of Polymer Science, Part B: Polymer Physics},
year = {2005},
volume = {43},
publisher = {Wiley},
month = {jul},
url = {https://doi.org/10.1002%2Fpolb.20521},
number = {17},
pages = {2352--2360},
doi = {10.1002/polb.20521}
}
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MLA
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Boiko, N. I., et al. “Kinetically controlled phase transitions in liquid-crystalline polymers. III. Influence of the molecular weight and annealing temperature on two-dimensional K phase formation in a side-chain polyacrylate.” Journal of Polymer Science, Part B: Polymer Physics, vol. 43, no. 17, Jul. 2005, pp. 2352-2360. https://doi.org/10.1002%2Fpolb.20521.