volume 70, issue 3, pages 367-373

Laser performance of pyrromethene 567 dye in solid matrices of methyl methacrylate with different comonomers

Costela A. 1
García-Moreno I. 1
Barroso J 2
Sastre R. 2
1
 
Instituto de Química-Física “Rocasolano”, CSIC, Serrano 119, 28006 Madrid, Spain (Fax: +34-91/564-2431, E-mail: acostela@iqfr.csic.es), , ES
2
 
Instituto de Ciencia y Tecnología de Polímeros, CSIC, Juan de la Cierva 3, 28006 Madrid, Spain (Fax: +34-91/564-4853, E-mail: ictrs45@fresno.csic.es), , ES
Publication typeJournal Article
Publication date2000-03-01
General Physics and Astronomy
Physics and Astronomy (miscellaneous)
General Engineering
Abstract
Laser performance of pyrromethene 567 (PM567) dye dissolved in pure poly(methyl methacrylate) homopolymer and its copolymers with 2-hydroxyethyl methacrylate, 2-hydroxyethyl acrylate, 1-vinyl-2-pyrrolidone, 2-phenoxyethyl acrylate, and 2,2,2-trifluoromethyl methacrylate has been investigated. The chosen monomers were selected to mimic solvents used in a previous study on the photophysical and lasing properties of PM567 in liquid solution in order to establish correlations between the lasing properties of PM567 in liquid and solid solutions. The vol/vol proportion of the different comonomers in each copolymer formulation was systematically varied, and the effect of each composition on the lasing properties of PM567 was evaluated. The laser samples were transversely pumped at 534 nm with 5.5-mJ pulses from a frequency-doubled Q-switched Nd:KGW laser. Lasing efficiencies of up to 30% and good photostabilities, with a drop of the initial laser output of 20% after 10000 pump pulses in some of the solid samples, were demonstrated.

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