Thermochimica Acta

, том 284 , издание 1 , страницы 213-227

Preparation and thermal decomposition of various forms of strontium oxalate

E KNAEPEN ¹

J. Mullens ¹

J. Yperman ¹

L.C. Van Poucke ¹

Скрыть аффилиации авторов Показать аффилиации авторов: 1 аффилиация

Laboratory of Inorganic and Physical Chemistry, Limburgs Universitair Centrum, B-3590 Diepenbeek, Belgium |

Тип публикации: Journal Article

Дата публикации: 1996-07-01

Elsevier

Thermochimica Acta

scimago Q2

wos Q2

БС2

SJR: 0.640

CiteScore: 6.2

Impact factor: 3.5

ISSN: 00406031, 1872762X

DOI: 10.1016/0040-6031(96)02863-8

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Physical and Theoretical Chemistry

Condensed Matter Physics

Instrumentation

Краткое описание

Strontium oxalate exists in two different forms: the neutral strontium oxalate hydrate, SrC 2 O 4 · x H 2 O, and the acid salt of strontium oxalate, SrC 2 O 4 · y H 2 C 2 O 4 · x H 2 O. Depending on the concentration of oxalic acid and ammonium oxalate as precipitating agents, both forms can be obtained. At a sufficiently low pH, the stoichiometric compound SrC 2 O 4 ·1 2 H 2 C 2 O 4 · H 2 O is formed. The thermal decomposition of the different strontium oxalates is studied in different atmospheres using DSC, and TGA coupled with FTIR and MS. The TGA-EGA spectra indicate that the anhydrous acid oxalate decomposes with the release of H 2 O, CO, CO 2 and formic acid.

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KNAEPEN E. et al. Preparation and thermal decomposition of various forms of strontium oxalate // Thermochimica Acta. 1996. Vol. 284. No. 1. pp. 213-227.

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KNAEPEN E., Mullens J., Yperman J., Van Poucke L. Preparation and thermal decomposition of various forms of strontium oxalate // Thermochimica Acta. 1996. Vol. 284. No. 1. pp. 213-227.

RIS |

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TY - JOUR

DO - 10.1016/0040-6031(96)02863-8

UR - https://doi.org/10.1016/0040-6031(96)02863-8

TI - Preparation and thermal decomposition of various forms of strontium oxalate

T2 - Thermochimica Acta

AU - KNAEPEN, E

AU - Mullens, J.

AU - Yperman, J.

AU - Van Poucke, L.C.

PY - 1996

DA - 1996/07/01

PB - Elsevier

SP - 213-227

IS - 1

VL - 284

SN - 0040-6031

SN - 1872-762X

ER -

BibTex |

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@article{1996_KNAEPEN,

author = {E KNAEPEN and J. Mullens and J. Yperman and L.C. Van Poucke},

title = {Preparation and thermal decomposition of various forms of strontium oxalate},

journal = {Thermochimica Acta},

year = {1996},

volume = {284},

publisher = {Elsevier},

month = {jul},

url = {https://doi.org/10.1016/0040-6031(96)02863-8},

number = {1},

pages = {213--227},

doi = {10.1016/0040-6031(96)02863-8}

}

MLA

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MLA Скопировать

KNAEPEN, E., et al. “Preparation and thermal decomposition of various forms of strontium oxalate.” Thermochimica Acta, vol. 284, no. 1, Jul. 1996, pp. 213-227. https://doi.org/10.1016/0040-6031(96)02863-8.

Издатель

Elsevier

Журнал

Thermochimica Acta

scimago Q2

wos Q2

БС2

SJR

0.640

CiteScore

6.2

Impact factor

3.5

ISSN

00406031 (Print)

1872762X (Electronic)