volume 69 issue 5 pages 1354-1366

Spin-trapping of oxygen free radicals in chemical and biological systems: new traps, radicals and possibilities.

Goran Bacic 1
Ivan Spasojevic 2
Bojana Secerov 3
Miloš Mojović 1
1
 
Faculty for Physical Chemistry, Studentski trg 12-16, Belgrade 11000, Serbia
2
 
Institute for Multidisciplinary Research, Kneza Višeslava 1, Belgrade 11000, Serbia
3
 
Vinča Institute of Nuclear Sciences, P.O. Box 522, Belgrade 11001, Serbia
Publication typeJournal Article
Publication date2008-05-01
scimago Q2
wos Q1
SJR0.664
CiteScore8.5
Impact factor4.6
ISSN13861425, 18733557
Spectroscopy
Analytical Chemistry
Atomic and Molecular Physics, and Optics
Instrumentation
Abstract
The choice of the spin-trap that is to be applied in any EPR study represents the crossroad between a comprehensive investigation and an "ordinary" quantification of production of radicals. So, the scope of our study was to compare the performance of different spin-traps for qualitative analysis of radical-generating systems, and their ability to recognize previously unnoticed radicals. In addition, we present a brief account of the difficulties involved in the detection of oxygen-centered radicals in chemical and biological systems accompanied by the rationale for using the EPR spin-trapping technique in quantitative studies of such reactive species. Certain technical aspects of EPR experiments related to efficient trapping of free radicals in biochemical systems are also discussed. As an example we present here results obtained using EPR spectroscopy and the spin-trap DEPMPO, which show that the Fenton reaction, as well as various biological systems generate a previously unappreciated hydrogen (*H) atom.
Found 
Found 

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Bacic G. et al. Spin-trapping of oxygen free radicals in chemical and biological systems: new traps, radicals and possibilities. // Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy. 2008. Vol. 69. No. 5. pp. 1354-1366.
GOST all authors (up to 50) Copy
Bacic G., Spasojevic I., Secerov B., Mojović M. Spin-trapping of oxygen free radicals in chemical and biological systems: new traps, radicals and possibilities. // Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy. 2008. Vol. 69. No. 5. pp. 1354-1366.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.saa.2007.09.047
UR - https://doi.org/10.1016/j.saa.2007.09.047
TI - Spin-trapping of oxygen free radicals in chemical and biological systems: new traps, radicals and possibilities.
T2 - Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
AU - Bacic, Goran
AU - Spasojevic, Ivan
AU - Secerov, Bojana
AU - Mojović, Miloš
PY - 2008
DA - 2008/05/01
PB - Elsevier
SP - 1354-1366
IS - 5
VL - 69
PMID - 18255335
SN - 1386-1425
SN - 1873-3557
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2008_Bacic,
author = {Goran Bacic and Ivan Spasojevic and Bojana Secerov and Miloš Mojović},
title = {Spin-trapping of oxygen free radicals in chemical and biological systems: new traps, radicals and possibilities.},
journal = {Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy},
year = {2008},
volume = {69},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016/j.saa.2007.09.047},
number = {5},
pages = {1354--1366},
doi = {10.1016/j.saa.2007.09.047}
}
MLA
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MLA Copy
Bacic, Goran, et al. “Spin-trapping of oxygen free radicals in chemical and biological systems: new traps, radicals and possibilities..” Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, vol. 69, no. 5, May. 2008, pp. 1354-1366. https://doi.org/10.1016/j.saa.2007.09.047.