Baker's yeast mediated synthesis of (5SR, 9S)-5,9-dimethyl-heptadecane and (5SR, 9S)-5,9-dimethyl pentadecane; the main sex-pheromone components of Leucoptera scitella and Perileucoptera coffeella enriched in 9S-isomers
1
Central Research Institute of Chemistry, 1525 Budapest, P.O. Box 17, Hungary
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Тип публикации: Journal Article
Дата публикации: 1991-06-01
scimago Q3
wos Q3
БС2
SJR: 0.334
CiteScore: 3.2
Impact factor: 1.5
ISSN: 00404039, 18733581
Organic Chemistry
Drug Discovery
Biochemistry
Краткое описание
A mixture of (5S, 9S)-5,9-dimethyl heptadecane (1a), the main sex-pheromone component of Leucoptera scitella, and its (5R, 9S)-isomer (2a) was synthetized conveniently from (R)-citronellal (4, obtained from racemic citronellal by enantiomer selective baker's yeast reduction) in four steps. (5SR, 9S)-5,9-Dimethyl-pentadecane (mixture of 1b and 2b), a possible sex-attractant of Perileucoptera coffeella was prepared analogously.
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Poppe L. et al. Baker's yeast mediated synthesis of (5SR, 9S)-5,9-dimethyl-heptadecane and (5SR, 9S)-5,9-dimethyl pentadecane; the main sex-pheromone components of Leucoptera scitella and Perileucoptera coffeella enriched in 9S-isomers // Tetrahedron Letters. 1991. Vol. 32. No. 23. pp. 2643-2646.
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Poppe L., Novak L., Devenyi J., Szántay C. Baker's yeast mediated synthesis of (5SR, 9S)-5,9-dimethyl-heptadecane and (5SR, 9S)-5,9-dimethyl pentadecane; the main sex-pheromone components of Leucoptera scitella and Perileucoptera coffeella enriched in 9S-isomers // Tetrahedron Letters. 1991. Vol. 32. No. 23. pp. 2643-2646.
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TY - JOUR
DO - 10.1016/s0040-4039(00)78807-1
UR - https://doi.org/10.1016/s0040-4039(00)78807-1
TI - Baker's yeast mediated synthesis of (5SR, 9S)-5,9-dimethyl-heptadecane and (5SR, 9S)-5,9-dimethyl pentadecane; the main sex-pheromone components of Leucoptera scitella and Perileucoptera coffeella enriched in 9S-isomers
T2 - Tetrahedron Letters
AU - Poppe, László
AU - Novak, L.
AU - Devenyi, J.
AU - Szántay, Cs
PY - 1991
DA - 1991/06/01
PB - Elsevier
SP - 2643-2646
IS - 23
VL - 32
SN - 0040-4039
SN - 1873-3581
ER -
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@article{1991_Poppe,
author = {László Poppe and L. Novak and J. Devenyi and Cs Szántay},
title = {Baker's yeast mediated synthesis of (5SR, 9S)-5,9-dimethyl-heptadecane and (5SR, 9S)-5,9-dimethyl pentadecane; the main sex-pheromone components of Leucoptera scitella and Perileucoptera coffeella enriched in 9S-isomers},
journal = {Tetrahedron Letters},
year = {1991},
volume = {32},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/s0040-4039(00)78807-1},
number = {23},
pages = {2643--2646},
doi = {10.1016/s0040-4039(00)78807-1}
}
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Poppe, László, et al. “Baker's yeast mediated synthesis of (5SR, 9S)-5,9-dimethyl-heptadecane and (5SR, 9S)-5,9-dimethyl pentadecane; the main sex-pheromone components of Leucoptera scitella and Perileucoptera coffeella enriched in 9S-isomers.” Tetrahedron Letters, vol. 32, no. 23, Jun. 1991, pp. 2643-2646. https://doi.org/10.1016/s0040-4039(00)78807-1.