Inorganica Chimica Acta, volume 384, pages 18-22
Dimeric "paddle-wheel" cymantrenylcarboxylates of copper (II)
Pasynskii A. A.
1
,
Gordienko A V
1
,
Razuvaev D I
1
,
Skabitsky I. V.
1
,
Aleksandrov G.G.
1
,
Dobrohotova Zh W
1
,
Publication type: Journal Article
Publication date: 2012-04-01
Journal:
Inorganica Chimica Acta
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor: 2.8
ISSN: 00201693, 18733255
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract The interaction of cymantrenylcarboxylic acid (C5H4CO2H)Mn(CO)3 (CymCOOH) or its potassium salts with salts of Cu (II) in alcohol or water with subsequent treatment with ligands L gives binuclear complexes LCu(CymCOO)4CuL where L = THF (I), Et2O (II), CymCOOH (III) or PPh3 (IV). The structures of I–III were solved by X-ray analyses. The frame of all complexes is constructed as “paddle-wheel” with four carboxylate bridges. At thermal decomposition of I and II in Ar the loss of L ligands took place, then the decarboxylation of all CymCOO groups was observed followed by decarbonylation with elimination of nine CO groups only. Finally the loss of cyclopentadienyl ligands results the solid product which according to powder XRD data contains metallic copper and Mn1.5Cu1.5O4 phase probably due to the splitting of the retaining CO groups.
Citations by journals
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Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
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Molecules
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1 publication, 4.76%
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1 publication, 4.76%
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Citations by publishers
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9
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Pleiades Publishing
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9 publications, 42.86%
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Wiley
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2 publications, 9.52%
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Multidisciplinary Digital Publishing Institute (MDPI)
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2 publications, 9.52%
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Royal Society of Chemistry (RSC)
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1 publication, 4.76%
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Springer Nature
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Springer Nature
1 publication, 4.76%
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American Chemical Society (ACS)
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American Chemical Society (ACS)
1 publication, 4.76%
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- We do not take into account publications that without a DOI.
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- Statistics recalculated weekly.
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Pasynskii A. A. et al. Dimeric "paddle-wheel" cymantrenylcarboxylates of copper (II) // Inorganica Chimica Acta. 2012. Vol. 384. pp. 18-22.
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Pasynskii A. A., Shapovalov S. S., Gordienko A. V., Razuvaev D. I., Skabitsky I. V., Aleksandrov G., Dobrohotova Z. W., Bogomyakov A. S. Dimeric "paddle-wheel" cymantrenylcarboxylates of copper (II) // Inorganica Chimica Acta. 2012. Vol. 384. pp. 18-22.
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TY - JOUR
DO - 10.1016/J.ICA.2011.11.026
UR - https://doi.org/10.1016%2FJ.ICA.2011.11.026
TI - Dimeric "paddle-wheel" cymantrenylcarboxylates of copper (II)
T2 - Inorganica Chimica Acta
AU - Pasynskii, A. A.
AU - Shapovalov, Sergey S.
AU - Gordienko, A V
AU - Razuvaev, D I
AU - Skabitsky, I. V.
AU - Aleksandrov, G.G.
AU - Dobrohotova, Zh W
AU - Bogomyakov, Artem S
PY - 2012
DA - 2012/04/01 00:00:00
PB - Elsevier
SP - 18-22
VL - 384
SN - 0020-1693
SN - 1873-3255
ER -
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@article{2012_Pasynskii,
author = {A. A. Pasynskii and Sergey S. Shapovalov and A V Gordienko and D I Razuvaev and I. V. Skabitsky and G.G. Aleksandrov and Zh W Dobrohotova and Artem S Bogomyakov},
title = {Dimeric "paddle-wheel" cymantrenylcarboxylates of copper (II)},
journal = {Inorganica Chimica Acta},
year = {2012},
volume = {384},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016%2FJ.ICA.2011.11.026},
pages = {18--22},
doi = {10.1016/J.ICA.2011.11.026}
}