Carbon, volume 122, pages 737-745

Rehybridization of carbon on facets of detonation diamond nanocrystals and forming hydrosols of individual particles

4
 
Helmholtz–Zentrum Berlin fuer Materialien und Energie, Berlin 12489, Germany
5
 
II Physikalisches Institut, Universität zu Köln, Zülpicher Strasse 77, 50937 Köln,Germany
Publication typeJournal Article
Publication date2017-10-01
Journal: Carbon
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor10.9
ISSN00086223
General Chemistry
General Materials Science
Abstract
It was revealed that sp3-sp2 rehybridization of carbon atoms on the facets of nanocrystalline paricles of detonation diamond under thermal treatment results in weakening the hardness of its primary agglomerates. That discloses a secret of the unusual high strength of industrial diamond agglomerates and allows obtaining hydrosol of individual diamond nanoparticles ranging of 4–5 nm. Details of sp3-sp2 rehybridization have been studied by number of complementary methods including TEM, AFM, XPS, Raman scattering, X-ray diffraction and dynamic light scattering. A model for complete explanation of the processes during the annealing and obtaining stable hydrosols of 4–5 nm DND particles with different ζ-potentials is suggested. The model reveals the new ways for obtaining nanodiamond sols in other solvents.

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Dideikin A. T. et al. Rehybridization of carbon on facets of detonation diamond nanocrystals and forming hydrosols of individual particles // Carbon. 2017. Vol. 122. pp. 737-745.
GOST all authors (up to 50) Copy
Dideikin A. T., Aleksenskii A. E., Baidakova M. V., Brunkov P., Brzhezinskaya M., Davydov V., Levitskii V., Kidalov S., Kukushkina Yu. A., Kirilenko D., Shnitov V., Shvidchenko A. V., Senkovskiy B. V., Shestakov M. S., Vul' A. Rehybridization of carbon on facets of detonation diamond nanocrystals and forming hydrosols of individual particles // Carbon. 2017. Vol. 122. pp. 737-745.
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RIS Copy
TY - JOUR
DO - 10.1016/j.carbon.2017.07.013
UR - https://doi.org/10.1016%2Fj.carbon.2017.07.013
TI - Rehybridization of carbon on facets of detonation diamond nanocrystals and forming hydrosols of individual particles
T2 - Carbon
AU - Dideikin, Artur Torievich
AU - Aleksenskii, Alexander E.
AU - Levitskii, Vladimir
AU - Kukushkina, Yu A
AU - Shvidchenko, A. V.
AU - Senkovskiy, Boris V.
AU - Shestakov, M S
AU - Baidakova, M. V.
AU - Brunkov, P.N
AU - Brzhezinskaya, M.
AU - Davydov, Valery
AU - Kidalov, S.V.
AU - Kirilenko, D.A.
AU - Shnitov, V.V.
AU - Vul', A.Ya.
PY - 2017
DA - 2017/10/01 00:00:00
PB - Elsevier
SP - 737-745
VL - 122
SN - 0008-6223
ER -
BibTex
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BibTex Copy
@article{2017_Dideikin,
author = {Artur Torievich Dideikin and Alexander E. Aleksenskii and Vladimir Levitskii and Yu A Kukushkina and A. V. Shvidchenko and Boris V. Senkovskiy and M S Shestakov and M. V. Baidakova and P.N Brunkov and M. Brzhezinskaya and Valery Davydov and S.V. Kidalov and D.A. Kirilenko and V.V. Shnitov and A.Ya. Vul'},
title = {Rehybridization of carbon on facets of detonation diamond nanocrystals and forming hydrosols of individual particles},
journal = {Carbon},
year = {2017},
volume = {122},
publisher = {Elsevier},
month = {oct},
url = {https://doi.org/10.1016%2Fj.carbon.2017.07.013},
pages = {737--745},
doi = {10.1016/j.carbon.2017.07.013}
}
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