Carbon, volume 189, pages 37-45

Insights into fullerene polymerization under the high pressure: The role of endohedral Sc dimer

Churkin V D 1
Vnukova N.G 2
Zhukov V V 1
Churilov G.N 2
Publication typeJournal Article
Publication date2022-04-01
Journal: Carbon
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor10.9
ISSN00086223
General Chemistry
General Materials Science
Abstract
In this work, through the technology of producing endohedral metallofullerene in macroscopic quantities, the process of pressure polymerization of Sc 2 C 2 @C 82 and their mechanical properties have been investigated in detail using a set of experimental and theoretical methods. The crucial role of endohedral atoms is demonstrated by comparison with pristine fullerenes. It is shown that the embedding of Sc 2 C 2 complex inside a fullerene significantly facilitates the polymerization process which finally leads to the highly rigid material at high pressures.

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Erohin S. V. et al. Insights into fullerene polymerization under the high pressure: The role of endohedral Sc dimer // Carbon. 2022. Vol. 189. pp. 37-45.
GOST all authors (up to 50) Copy
Erohin S. V., Churkin V. D., Vnukova N., Visotin M., Zhukov V. V., Antipina L. Yu., Tomashevich Y. V., Mikhlin Y. L., Popov M., Churilov G., Sorokin P. B., Fedorov A. Insights into fullerene polymerization under the high pressure: The role of endohedral Sc dimer // Carbon. 2022. Vol. 189. pp. 37-45.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.carbon.2021.12.040
UR - https://doi.org/10.1016%2Fj.carbon.2021.12.040
TI - Insights into fullerene polymerization under the high pressure: The role of endohedral Sc dimer
T2 - Carbon
AU - Erohin, Sergey V
AU - Churkin, V D
AU - Vnukova, N.G
AU - Visotin, Maxim
AU - Fedorov, A.S
AU - Zhukov, V V
AU - Antipina, Liubov Yu
AU - Tomashevich, Ye V
AU - Mikhlin, Yuri L.
AU - Popov, Mikhail
AU - Churilov, G.N
AU - Sorokin, Pavel B.
PY - 2022
DA - 2022/04/01 00:00:00
PB - Elsevier
SP - 37-45
VL - 189
SN - 0008-6223
ER -
BibTex
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BibTex Copy
@article{2022_Erohin
author = {Sergey V Erohin and V D Churkin and N.G Vnukova and Maxim Visotin and A.S Fedorov and V V Zhukov and Liubov Yu Antipina and Ye V Tomashevich and Yuri L. Mikhlin and Mikhail Popov and G.N Churilov and Pavel B. Sorokin},
title = {Insights into fullerene polymerization under the high pressure: The role of endohedral Sc dimer},
journal = {Carbon},
year = {2022},
volume = {189},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016%2Fj.carbon.2021.12.040},
pages = {37--45},
doi = {10.1016/j.carbon.2021.12.040}
}
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