Catalysis Today, volume 268, pages 60-67
Bimetallic carbon nanocatalysts for methanol steam reforming in conventional and membrane reactors
Lytkina Aleksandra A
1
,
Orekhova Natalia V
1
,
Ermilova Margarita M
1
,
Belenov Sergey
2
,
Guterman V. E.
2
,
Efimov M. N.
1
,
Publication type: Journal Article
Publication date: 2016-06-01
General Chemistry
Catalysis
Abstract
In this paper we report the results obtained by a comparative study of catalytic activity of bimetallic (Ru–Rh, Ni–Cu) catalysts synthesized on a surface of different carbon supports: detonation nanodiamonds (DND), infrared pyrolyzed polyacrylonitrile, carbon black Vulcan-XC-72, in steam reforming of methanol (MSR) for hydrogen production. All obtained catalysts were characterized by N 2 physisorption, SEM, TEM, FTIR spectroscopy, X-ray diffraction. It was shown, that activity of catalysts and products distribution depends on metal type, support material and the specific surface area. Support effect was investigated for Ru–Rh system. DND showed the best properties as a catalyst support. Ru–Rh system is more active than Cu–Ni as it is shown on the example of DND supported catalysts. Comparative study between conventional (CR) and membrane (MR) reactors was carried out. MR represented a flow system with a plane Pd-containing membrane. The effect of different catalysts on the MR performances as well as a general comparison of the experimental results was considered. Obtained results demonstrate the ability of the membrane to increase the reaction conversion. The hydrogen stream produced from the MR is ultra pure: especially, it is CO-free and thus suitable to be directly fed to a polymer electrolyte membrane fuel cell.
Citations by journals
1
2
3
4
5
|
|
International Journal of Hydrogen Energy
|
International Journal of Hydrogen Energy
5 publications, 14.29%
|
Inorganic Materials
|
Inorganic Materials
3 publications, 8.57%
|
Processes
|
Processes
2 publications, 5.71%
|
Industrial & Engineering Chemistry Research
|
Industrial & Engineering Chemistry Research
2 publications, 5.71%
|
Comprehensive Nanoscience and Nanotechnology
|
Comprehensive Nanoscience and Nanotechnology
1 publication, 2.86%
|
Russian Chemical Reviews
|
Russian Chemical Reviews
1 publication, 2.86%
|
Catalysis Communications
|
Catalysis Communications
1 publication, 2.86%
|
Russian Journal of Physical Chemistry A
|
Russian Journal of Physical Chemistry A
1 publication, 2.86%
|
Pure and Applied Chemistry
|
Pure and Applied Chemistry
1 publication, 2.86%
|
Membranes and Membrane Technologies
|
Membranes and Membrane Technologies
1 publication, 2.86%
|
Petroleum Chemistry
|
Petroleum Chemistry
1 publication, 2.86%
|
Materials
|
Materials
1 publication, 2.86%
|
ChemEngineering
|
ChemEngineering
1 publication, 2.86%
|
Journal of Energy Chemistry
|
Journal of Energy Chemistry
1 publication, 2.86%
|
Journal of Industrial and Engineering Chemistry
|
Journal of Industrial and Engineering Chemistry, 1, 2.86%
Journal of Industrial and Engineering Chemistry
1 publication, 2.86%
|
Materials Research Bulletin
|
Materials Research Bulletin
1 publication, 2.86%
|
ChemistrySelect
|
ChemistrySelect
1 publication, 2.86%
|
Russian Journal of Inorganic Chemistry
|
Russian Journal of Inorganic Chemistry
1 publication, 2.86%
|
Kataliz v promyshlennosti
|
Kataliz v promyshlennosti, 1, 2.86%
Kataliz v promyshlennosti
1 publication, 2.86%
|
Renewable and Sustainable Energy Reviews
|
Renewable and Sustainable Energy Reviews
1 publication, 2.86%
|
Catalysis in Industry
|
Catalysis in Industry
1 publication, 2.86%
|
Russian Journal of Applied Chemistry
|
Russian Journal of Applied Chemistry
1 publication, 2.86%
|
1
2
3
4
5
|
Citations by publishers
2
4
6
8
10
|
|
Elsevier
|
Elsevier
10 publications, 28.57%
|
Pleiades Publishing
|
Pleiades Publishing
9 publications, 25.71%
|
Multidisciplinary Digital Publishing Institute (MDPI)
|
Multidisciplinary Digital Publishing Institute (MDPI)
4 publications, 11.43%
|
American Chemical Society (ACS)
|
American Chemical Society (ACS)
2 publications, 5.71%
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 2.86%
|
Walter de Gruyter
|
Walter de Gruyter
1 publication, 2.86%
|
Korean Society of Industrial Engineering Chemistry
|
Korean Society of Industrial Engineering Chemistry, 1, 2.86%
Korean Society of Industrial Engineering Chemistry
1 publication, 2.86%
|
Wiley
|
Wiley
1 publication, 2.86%
|
Kalvis
|
Kalvis, 1, 2.86%
Kalvis
1 publication, 2.86%
|
2
4
6
8
10
|
- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2016,2017,2018,2019,2020,2021,2022,2023,2024],"ids":[0,0,0,0,0,0,0,0,0],"codes":[0,0,0,0,0,0,0,0,0],"imageUrls":["","","","","","","","",""],"datasets":[{"label":"Citations number","data":[1,2,3,6,7,5,6,4,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["2.86","5.71","8.57","17.14","20","14.29","17.14","11.43","2.86"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["International Journal of Hydrogen Energy","Inorganic Materials","Processes","Industrial & Engineering Chemistry Research","Comprehensive Nanoscience and Nanotechnology","Russian Chemical Reviews","Catalysis Communications","Russian Journal of Physical Chemistry A","Pure and Applied Chemistry","Membranes and Membrane Technologies","Petroleum Chemistry","Materials","ChemEngineering","Journal of Energy Chemistry","Journal of Industrial and Engineering Chemistry","Materials Research Bulletin","ChemistrySelect","Russian Journal of Inorganic Chemistry","Kataliz v promyshlennosti","Renewable and Sustainable Energy Reviews","Catalysis in Industry","Russian Journal of Applied Chemistry"],"ids":[8699,7716,19796,12141,57016,23802,23806,6134,11456,26667,19946,25198,27565,20653,1786,9849,8021,426,25503,17453,4253,9557],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/3SpVxcYL33bOvPq4sHxJLH2NeKNeDloahSUpNiO4_medium.webp","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp"],"datasets":[{"label":"","data":[5,3,2,2,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[14.29,8.57,5.71,5.71,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Elsevier","Pleiades Publishing","Multidisciplinary Digital Publishing Institute (MDPI)","American Chemical Society (ACS)","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii","Walter de Gruyter","Korean Society of Industrial Engineering Chemistry","Wiley","Kalvis"],"ids":[17,101,202,40,9422,4,709,11,6927],"codes":[0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp","\/storage\/images\/resized\/3SpVxcYL33bOvPq4sHxJLH2NeKNeDloahSUpNiO4_medium.webp","","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp",""],"datasets":[{"label":"","data":[10,9,4,2,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[28.57,25.71,11.43,5.71,2.86,2.86,2.86,2.86,2.86],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Metrics
Cite this
GOST |
RIS |
BibTex
Cite this
GOST
Copy
Lytkina A. A. et al. Bimetallic carbon nanocatalysts for methanol steam reforming in conventional and membrane reactors // Catalysis Today. 2016. Vol. 268. pp. 60-67.
GOST all authors (up to 50)
Copy
Lytkina A. A., Orekhova N. V., Ermilova M. M., Belenov S., Guterman V. E., Efimov M. N., Yaroslavtsev A. B. Bimetallic carbon nanocatalysts for methanol steam reforming in conventional and membrane reactors // Catalysis Today. 2016. Vol. 268. pp. 60-67.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.cattod.2016.01.003
UR - https://doi.org/10.1016%2Fj.cattod.2016.01.003
TI - Bimetallic carbon nanocatalysts for methanol steam reforming in conventional and membrane reactors
T2 - Catalysis Today
AU - Lytkina, Aleksandra A
AU - Orekhova, Natalia V
AU - Ermilova, Margarita M
AU - Belenov, Sergey
AU - Guterman, V. E.
AU - Efimov, M. N.
AU - Yaroslavtsev, A. B.
PY - 2016
DA - 2016/06/01 00:00:00
PB - Elsevier
SP - 60-67
VL - 268
SN - 0920-5861
ER -
Cite this
BibTex
Copy
@article{2016_Lytkina
author = {Aleksandra A Lytkina and Natalia V Orekhova and Margarita M Ermilova and Sergey Belenov and V. E. Guterman and M. N. Efimov and A. B. Yaroslavtsev},
title = {Bimetallic carbon nanocatalysts for methanol steam reforming in conventional and membrane reactors},
journal = {Catalysis Today},
year = {2016},
volume = {268},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016%2Fj.cattod.2016.01.003},
pages = {60--67},
doi = {10.1016/j.cattod.2016.01.003}
}