Activation of a nickel-chromium catalyst for low-temperature steam reforming of C2+-alkanes

• XRD study on activation of an industrial Ni-Cr-Al catalyst. • Reduction of NiO by H 2 , syngas, methanol and reaction mixture. • Nickel catalyst passivation and reactivation. • Steam reforming of C 2+ -hydrocarbons into CH 4 , CO 2 and H 2 . Activation of a nickel-chromium catalyst for low temperature steam reforming of C 2+ -alkanes to methane rich gas has been studied by TPR and XRD in situ techniques. The activation procedure has been studied with the following reducing agents: hydrogen, syngas, methanol and the reaction mixture of low-temperature steam reforming. Attempts were made to activate the catalyst at 300, 340 and 420 °C. Activated samples were tested in low-temperature steam reforming of a methane-propane mixture. A passivation process has been proposed and tested for compatibility with following activation in the LTSR reaction mixture.