Coordination Chemistry Reviews, издание 469, номер публикации: 214684

Basic structural modifications for improving the practical properties of BODIPY

Тип публикацииJournal Article
Дата публикации2022-10-01
ЖурналCoordination Chemistry Reviews
Квартиль SCImagoQ1
Квартиль WOSQ1
Impact factor20.6
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
• The BODIPY modification have a very significant effect on the photophysical properties. • Alkyl-BODIPYs absorb at 490–535 nm and fluoresce at 500–550 nm ( Ф F from 70 to 100%). • Fluorescence quantum yield of Br- and I-BODIPYs was decreased due to the “heavy atom” effect. • The attachment positions of the aryl substituents in the BODIPY determine their properties. • The NIR-BODIPYs (to 1000 nm) were obtained by meso -aza, benzo-fused and oligo-modification. The review considers the results of research by scientists from different countries in the field of synthesis and photophysical property study of known BODIPY. We focus on describing the main ways the BODIPY structure modifying by substituting the pyrrole rings, the meso -spacer, and the boron atom of the indacene core with different nature substituents and changing the spectral and other practically significant BODIPY properties associated with a particular type of their modification. In addition, we have considered the effects of alkylation, halogenation, nitration, amination, and arylation at the meso -spacer and/or pyrrole rings, boron atom; pyrrole rings annulation; meso -aza-substitution, covalent oligomerization through direct σ-bonds or spacers. Most of these approaches have a very significant and individual effect on the photophysical properties, hydrophobicity or hydrophilicity of dyes and consequently, on their practical application possibility. In the general case, BODIPY modification approaches considered above make it possible to vary the absorption and fluorescence bands position of BODIPY in the range from UV to NIR spectral regions (from 400 to 1000 nm). Depending on the features of BODIPY functionalization, as well as on the properties of the medium, the quantum yields of fluorescence, phosphorescence, and singlet oxygen generation of BODIPYs can be changed from 0 to 100%.
1. Bumagina N. A. и др. Basic structural modifications for improving the practical properties of BODIPY // Coordination Chemistry Reviews. 2022. Т. 469. С. 214684.


DO - 10.1016/j.ccr.2022.214684

UR -

TI - Basic structural modifications for improving the practical properties of BODIPY

T2 - Coordination Chemistry Reviews

AU - Bumagina, Natalia A.

AU - Antina, Elena V.

AU - Ksenofontov, Alexander A.

AU - Antina, Lubov A.

AU - Kalyagin, Alexander A.

AU - Berezin, Mikhail B.

PY - 2022

DA - 2022/10

PB - Elsevier BV

SP - 214684

VL - 469

SN - 0010-8545

ER -

BibTex |


doi = {10.1016/j.ccr.2022.214684},

url = {},

year = 2022,

month = {oct},

publisher = {Elsevier {BV}},

volume = {469},

pages = {214684},

author = {Natalia A. Bumagina and Elena V. Antina and Alexander A. Ksenofontov and Lubov A. Antina and Alexander A. Kalyagin and Mikhail B. Berezin},

title = {Basic structural modifications for improving the practical properties of {BODIPY}},

journal = {Coordination Chemistry Reviews}


Bumagina, Natalia A., et al. “Basic Structural Modifications for Improving the Practical Properties of BODIPY.” Coordination Chemistry Reviews, vol. 469, Oct. 2022, p. 214684. Crossref,