Nanocomposite E(PbSnF4;SnF2)@SWCNT – Promising material for fluoride-ion batteries
Publication type: Journal Article
Publication date: 2022-09-01
scimago Q1
wos Q1
SJR: 1.034
CiteScore: 9.1
Impact factor: 5.6
ISSN: 02728842, 18733956
Materials Chemistry
Surfaces, Coatings and Films
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Process Chemistry and Technology
Abstract
The channels of single walled carbon nanotubes (SWCNT) were filled with eutectic composition consisting of PbSnF 4 and SnF 2 . The nanocomposite was investigated by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), scanning transmission electron microscopy (STEM), X-ray energy dispersive (EDX) spectroscopy and Raman spectroscopy. The SnF 2 and PbSnF 4 nanocrystals form independent regions with disordered atomic region between them inside the SWCNT with a diameter of 20.0(3) Å. In the PbSnF 4 region there are two separate fragments connected by a twinning plane. Structural models of the PbSnF 4 twin nanocrystal and SnF 2 nanocrystal inside the nanotube with chilarity (26,0) were constructed and computer modelling of TEM-image of E (PbSnF 4 ;SnF 2 )@SWCNT nanocomposite was performed. Solid-state FIB with Ce as anode, dispersed E (PbSnF 4 ;SnF 2 )@SWCNT + SnF 2 as a composite-cathode and 95.03%LaF 3 +4.97%BaF 2 electrolyte was investigated by the impedance spectroscopy and cyclic voltammetry. The current density reached ∼0.6 A/m 2 at 180 °C, the open circuit voltage of the pellet at room temperature was 1.9 V.
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Total citations:
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Citations from 2024:
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Zakalyukin R. M. et al. Nanocomposite E(PbSnF4;SnF2)@SWCNT – Promising material for fluoride-ion batteries // Ceramics International. 2022. Vol. 48. No. 18. pp. 26565-26574.
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Zakalyukin R. M., Levkevich E. A., Kumskov A. S. Nanocomposite E(PbSnF4;SnF2)@SWCNT – Promising material for fluoride-ion batteries // Ceramics International. 2022. Vol. 48. No. 18. pp. 26565-26574.
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RIS
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TY - JOUR
DO - 10.1016/j.ceramint.2022.05.352
UR - https://doi.org/10.1016/j.ceramint.2022.05.352
TI - Nanocomposite E(PbSnF4;SnF2)@SWCNT – Promising material for fluoride-ion batteries
T2 - Ceramics International
AU - Zakalyukin, Ruslan M
AU - Levkevich, E. A.
AU - Kumskov, A S
PY - 2022
DA - 2022/09/01
PB - Elsevier
SP - 26565-26574
IS - 18
VL - 48
SN - 0272-8842
SN - 1873-3956
ER -
Cite this
BibTex (up to 50 authors)
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@article{2022_Zakalyukin,
author = {Ruslan M Zakalyukin and E. A. Levkevich and A S Kumskov},
title = {Nanocomposite E(PbSnF4;SnF2)@SWCNT – Promising material for fluoride-ion batteries},
journal = {Ceramics International},
year = {2022},
volume = {48},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016/j.ceramint.2022.05.352},
number = {18},
pages = {26565--26574},
doi = {10.1016/j.ceramint.2022.05.352}
}
Cite this
MLA
Copy
Zakalyukin, Ruslan M., et al. “Nanocomposite E(PbSnF4;SnF2)@SWCNT – Promising material for fluoride-ion batteries.” Ceramics International, vol. 48, no. 18, Sep. 2022, pp. 26565-26574. https://doi.org/10.1016/j.ceramint.2022.05.352.
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