Colloids and Surfaces A: Physicochemical and Engineering Aspects, volume 618, pages 126449
Effect of ms-substitution on aggregation behavior and spectroscopic properties of BODIPY dyes in aqueous solution, Langmuir-Schaefer and poly(methyl methacrylate) thin films
Antina Lubov A
1
,
Antina Elena V
1
,
Usoltseva Nadezhda V
2
,
Kazak Alexander V
2
,
Ksenofontov A.L.
1
,
Publication type: Journal Article
Publication date: 2021-06-01
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 5.2
ISSN: 09277757, 18734359
Colloid and Surface Chemistry
Abstract
It is well known that boron-dipyrromethene (BODIPY) dyes have a remarkable combination of photophysical and photochemical properties, which are significant for practical use. Unfortunately, the application of BODIPYs in optical devices and biosensorics is severely limited due to the aggregation quenching effect (ACQ), the effects of the internal filter and/or the formation of excimers. One way to prevent fluorescence quenching is to synthesize new molecules BODIPY with a highly complicated structural organization or hybrid systems based on them. But in this paper, we demonstrate that the introduction of simple aliphatic or aryl substituents into the ms -position of the BODIPY molecule is an effective way to control the aggregation in various states: thin mono- and multilayer Langmuir-Schaefer (LS) films, polymer films and concentrated solutions, including aqueous ones. The results of experimental studies of the aggregation behavior of BODIPYs ( BDP1-BDP3 ) are in good agreement with the theoretical calculations data of di- and tetramers, as well as multilayer packing. This allows to adjust the spectral properties of luminophores to the most possible types of their real applications in practical areas. • A comparative analysis of the different ms -substituted BODIPYs aggregation behavior in different states was carried out. • The nature of the BODIPY substituent in the ms -position determines the type of dye aggregation in solutions and in the solid phase. • The BDP2 with an extended ester group at the ms -position is distinguished by a significantly lower tendency to aggregation.
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Citations by publishers
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Antina E. V. et al. Effect of ms-substitution on aggregation behavior and spectroscopic properties of BODIPY dyes in aqueous solution, Langmuir-Schaefer and poly(methyl methacrylate) thin films // Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2021. Vol. 618. p. 126449.
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Antina E. V., Ksenofontov A. A., Usoltseva N. V., Berezin M. B., Antina L. A., Kazak A. V., Ksenofontov A., Berezin M. Y. Effect of ms-substitution on aggregation behavior and spectroscopic properties of BODIPY dyes in aqueous solution, Langmuir-Schaefer and poly(methyl methacrylate) thin films // Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2021. Vol. 618. p. 126449.
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TY - JOUR
DO - 10.1016/j.colsurfa.2021.126449
UR - https://doi.org/10.1016%2Fj.colsurfa.2021.126449
TI - Effect of ms-substitution on aggregation behavior and spectroscopic properties of BODIPY dyes in aqueous solution, Langmuir-Schaefer and poly(methyl methacrylate) thin films
T2 - Colloids and Surfaces A: Physicochemical and Engineering Aspects
AU - Antina, Elena V
AU - Ksenofontov, Alexander A
AU - Usoltseva, Nadezhda V
AU - Berezin, Mikhail B
AU - Antina, Lubov A
AU - Kazak, Alexander V
AU - Ksenofontov, A.L.
AU - Berezin, Mikhail Y.
PY - 2021
DA - 2021/06/01 00:00:00
PB - Elsevier
SP - 126449
VL - 618
SN - 0927-7757
SN - 1873-4359
ER -
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@article{2021_Antina,
author = {Elena V Antina and Alexander A Ksenofontov and Nadezhda V Usoltseva and Mikhail B Berezin and Lubov A Antina and Alexander V Kazak and A.L. Ksenofontov and Mikhail Y. Berezin},
title = {Effect of ms-substitution on aggregation behavior and spectroscopic properties of BODIPY dyes in aqueous solution, Langmuir-Schaefer and poly(methyl methacrylate) thin films},
journal = {Colloids and Surfaces A: Physicochemical and Engineering Aspects},
year = {2021},
volume = {618},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016%2Fj.colsurfa.2021.126449},
pages = {126449},
doi = {10.1016/j.colsurfa.2021.126449}
}