Chemical Physics Letters, volume 763, pages 138165
Effect of substituents of corrole derivatives on generation of singlet oxygen
1
Bi Biophotonics Co., Ltd., Gimpo-si, Kyunggi-do 10090, South Korea
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2
Department of Pharmacy, College of Pharmacy, Kyung Hee University, Seoul 02447, Republic of Korea
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3
Department of Chemistry, Seoul Women's University,Seoul 01797,South Korea
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Publication type: Journal Article
Publication date: 2021-01-01
Journal:
Chemical Physics Letters
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor: 2.8
ISSN: 00092614
Physical and Theoretical Chemistry
General Physics and Astronomy
Abstract
The correlation between the molecular structures of three corrole derivatives (PC: 5,10,15-triphenyl corrole, PFPC: 5,10,15-tris(pentafluorophenyl) corrole, MCPC: 5,10,15-tris(p-methoxycarbonylphenyl)corrole) and their efficiencies for singlet oxygen generation was studied. Introducing electron-withdrawing fluorine atoms into the PC moiety led to a significant enhancement in singlet oxygen generation and facilitated intersystem crossing (ISC) due to enhanced spin-orbit coupling. Cyclic voltammetry experiments revealed a desirable linear relationship between the quenching rate constants and the oxidation potentials of the three corrole derivatives, indicating that the substituent effect is a critical factor governing the oxidation potential of photosensitizers for singlet oxygen generation.
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Citations by publishers
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4 publications, 57.14%
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Wiley
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Wiley
1 publication, 14.29%
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- We do not take into account publications that without a DOI.
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- Statistics recalculated weekly.
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Shin J. H. et al. Effect of substituents of corrole derivatives on generation of singlet oxygen // Chemical Physics Letters. 2021. Vol. 763. p. 138165.
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Shin J. H., Kim S., Lee S., Lee Y. B., Han W., Wang K. Effect of substituents of corrole derivatives on generation of singlet oxygen // Chemical Physics Letters. 2021. Vol. 763. p. 138165.
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TY - JOUR
DO - 10.1016/j.cplett.2020.138165
UR - https://doi.org/10.1016%2Fj.cplett.2020.138165
TI - Effect of substituents of corrole derivatives on generation of singlet oxygen
T2 - Chemical Physics Letters
AU - Shin, Jun Ho
AU - Kim, Seung-Hwan
AU - Lee, Sunhee
AU - Lee, Yong Beom
AU - Han, Won-Sik
AU - Wang, Kang
PY - 2021
DA - 2021/01/01 00:00:00
PB - Elsevier
SP - 138165
VL - 763
SN - 0009-2614
ER -
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@article{2021_Shin,
author = {Jun Ho Shin and Seung-Hwan Kim and Sunhee Lee and Yong Beom Lee and Won-Sik Han and Kang Wang},
title = {Effect of substituents of corrole derivatives on generation of singlet oxygen},
journal = {Chemical Physics Letters},
year = {2021},
volume = {763},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016%2Fj.cplett.2020.138165},
pages = {138165},
doi = {10.1016/j.cplett.2020.138165}
}