Dyes and Pigments, volume 113, pages 664-674

New luminophors based on the binuclear helicates of d-METALS with BIS(DIPYRRIN)S

Publication typeJournal Article
Publication date2015-02-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor4.5
ISSN01437208, 18733743
General Chemical Engineering
Process Chemistry and Technology
Abstract
The review highlights recent advances devoted to new luminophores based on d -metal complexes of bis(dipyrrin)s of [M 2 L 2 ]. The [M 2 L 2 ] helicates possess intense absorption in a visible spectrum region. The [Zn 2 L 2 ], [Cd 2 L 2 ] and [Hg 2 L 2 ] helicates are fluorophores with the most intense fluorescence in nonpolar solvents. The fluorescence of [M 2 L 2 ] bis(dipyrrinate)s decreases by two-fold in aromatic solvents and becomes close to zero in electron-donor media. The fluorescence is increased in a series of 2,2′-, 2,3′-, 3,3′-bis(dipyrrinate)s with similar complexing agent and in a series of [Hg 2 L 2 ], [Cd 2 L 2 ], [Zn 2 L 2 ] complexes with the same ligand. Upon freezing and cooling of [Zn 2 L 2 ] in ethanol from 300 to 77 K the fluorescence quantum yield of [Zn 2 L 2 ] is increased up to 100 times. The [Zn 2 L 2 ] complexes are able to generate the stimulated emission induced at the 550–560 nm region in nonpolar solvents upon excitation by second harmonic Nd:YAG laser.

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Antina E. V. et al. New luminophors based on the binuclear helicates of d-METALS with BIS(DIPYRRIN)S // Dyes and Pigments. 2015. Vol. 113. pp. 664-674.
GOST all authors (up to 50) Copy
Antina E. V., Kuznetsova R., Antina L. A., Guseva G. B., Dudina N. A., Vyugin A. I., Solomonov A. V. New luminophors based on the binuclear helicates of d-METALS with BIS(DIPYRRIN)S // Dyes and Pigments. 2015. Vol. 113. pp. 664-674.
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RIS Copy
TY - JOUR
DO - 10.1016/j.dyepig.2014.10.002
UR - https://doi.org/10.1016%2Fj.dyepig.2014.10.002
TI - New luminophors based on the binuclear helicates of d-METALS with BIS(DIPYRRIN)S
T2 - Dyes and Pigments
AU - Antina, Elena V
AU - Vyugin, Anatolij I
AU - Antina, Lubov A
AU - Dudina, Natalia A
AU - Kuznetsova, Rimma
AU - Guseva, Galina B
AU - Solomonov, Alexey V.
PY - 2015
DA - 2015/02/01 00:00:00
PB - Elsevier
SP - 664-674
VL - 113
SN - 0143-7208
SN - 1873-3743
ER -
BibTex
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BibTex Copy
@article{2015_Antina,
author = {Elena V Antina and Anatolij I Vyugin and Lubov A Antina and Natalia A Dudina and Rimma Kuznetsova and Galina B Guseva and Alexey V. Solomonov},
title = {New luminophors based on the binuclear helicates of d-METALS with BIS(DIPYRRIN)S},
journal = {Dyes and Pigments},
year = {2015},
volume = {113},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016%2Fj.dyepig.2014.10.002},
pages = {664--674},
doi = {10.1016/j.dyepig.2014.10.002}
}
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