Dyes and Pigments, volume 195, pages 109656
Bis(dipyrromethene)s as a new class of highly efficient chromo-fluorogenic ligands
Publication type: Journal Article
Publication date: 2021-11-01
Journal:
Dyes and Pigments
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4.5
ISSN: 01437208, 18733743
General Chemical Engineering
Process Chemistry and Technology
Abstract
Compounds with an open chain tetrapyrrole structure are mainly formed in plant and animal organisms during the catabolism of heme or other natural macrocyclic tetrapyrroles. Great success has been achieved in the development of synthetic open-chain analogs of natural tetrapyrroles with a successful combination of practically useful properties. Various combinations of several types of modifications in terms of the method, the nature of the attachment of the spacer and peripheral substituents make it possible to obtain compounds with the necessary set of properties, required for specific practical purposes. Bis(dipyrromethene)s are characterized by conformational isomerism. Depending on the preferred conformation, the bis(dipyrromethene) ligands form complexes of different structure and composition upon complexation with cations of some elements. Bright coloristic and fluorescent signals of the complexation processes of such ligands with metal cations are of great practical interest. The review discusses the possibilities of using bis(dipyrromethene)s as colorimetric and fluorescent sensors of amines and zinc, cadmium, and mercury cations. The review highlights prospects of using bis(dipyrromethene) complexes in various fields of medicine, laser technology, supramolecular chemistry, etc. • Open-chain tetrapyrroles form a huge class of compounds with a variety of useful properties. • Bis(dipyrromethene)s with cations of some elements form complexes of various structures. • Open-chain tetrapyrroles and their complexes exhibit intense absorption and, in some cases, bright fluorescence. • Bis(dipyrromethene)s are effective fluorescent sensors of amines and Zn 2+ , Cd 2+ and Hg 2+ . • The bis(dipyrromethene) complexes are perspective markers, components of supramolecular structures, laser devices and PDT .
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Citations by publishers
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Elsevier
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Antina E. V. et al. Bis(dipyrromethene)s as a new class of highly efficient chromo-fluorogenic ligands // Dyes and Pigments. 2021. Vol. 195. p. 109656.
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Antina E. V., Bumagina N. A., Berezin M. B., Berezin M. Y. Bis(dipyrromethene)s as a new class of highly efficient chromo-fluorogenic ligands // Dyes and Pigments. 2021. Vol. 195. p. 109656.
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TY - JOUR
DO - 10.1016/j.dyepig.2021.109656
UR - https://doi.org/10.1016%2Fj.dyepig.2021.109656
TI - Bis(dipyrromethene)s as a new class of highly efficient chromo-fluorogenic ligands
T2 - Dyes and Pigments
AU - Antina, Elena V
AU - Bumagina, Natalia A
AU - Berezin, Mikhail B
AU - Berezin, Mikhail Y.
PY - 2021
DA - 2021/11/01 00:00:00
PB - Elsevier
SP - 109656
VL - 195
SN - 0143-7208
SN - 1873-3743
ER -
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@article{2021_Antina,
author = {Elena V Antina and Natalia A Bumagina and Mikhail B Berezin and Mikhail Y. Berezin},
title = {Bis(dipyrromethene)s as a new class of highly efficient chromo-fluorogenic ligands},
journal = {Dyes and Pigments},
year = {2021},
volume = {195},
publisher = {Elsevier},
month = {nov},
url = {https://doi.org/10.1016%2Fj.dyepig.2021.109656},
pages = {109656},
doi = {10.1016/j.dyepig.2021.109656}
}