Electrochimica Acta, volume 265, pages 140-150

Improving the electrochemical properties of MXene Ti3C2 multilayer for Li-ion batteries by vacuum calcination

Kong Fanyu ¹

He Xiaodong ¹

Liu Qianqian ¹

Qi Xinxin ¹

Zheng Yongting ¹

Wang Rongguo ¹

Bai Yuelei ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

National Key Laboratory of Science and Technology on Advanced Composites in Special Environments, and Center for Composite Materials and Structures, Harbin Institute of Technology, Harbin, 150080, PR China |

Publication type: Journal Article

Publication date: 2018-03-01

Elsevier

Journal: Electrochimica Acta

Quartile SCImago

Quartile WOS

Impact factor: 6.6

ISSN: 00134686

DOI: 10.1016/j.electacta.2018.01.196

Copy DOI

General Chemical Engineering

Electrochemistry

Abstract

The electrochemical properties of MXene Ti3C2 multilayer for Li-ion batteries were improved greatly by vacuum calcination, after systematically evaluating its thermal stability in different atmosphere in details. In air, the as-prepared Ti3C2 could not be oxidized up to 429.9 °C and the rutile-TiO2 would remain as the oxidation product at 1200 °C. The surface functional groups especially F groups can be eliminated by heat treatment. After vacuum calcination at 400 °C, the Ti3C2 show much higher capacities due to the removal of OH groups (126.4 mAh·g−1 at 1C), and exhibited excellent rate capability. Besides, the formation of TiO2 nanoparticles at 700 °C further increases the first coulombic efficiency (62%) and capacity retention after 100 cycles (97%). In contrast, the dense microstructures of resulting TiCx formed after calcination at 1000 °C results in the worst electrochemical properties. This paper presented a relatively simple and easily scalable post-treatment for improving the electrochemical properties of MXene, and demonstrated a great potential of Ti3C2 of using as anode material for Li-ion batteries.

By date By citations

Citations by journals

	1 2 3 4 5 6 7
Electrochimica Acta	Electrochimica Acta, 7, 7.37% Electrochimica Acta 7 publications, 7.37%
Ceramics International	Ceramics International, 4, 4.21% Ceramics International 4 publications, 4.21%
Chemical Engineering Journal	Chemical Engineering Journal, 4, 4.21% Chemical Engineering Journal 4 publications, 4.21%
Nanomaterials	Nanomaterials, 3, 3.16% Nanomaterials 3 publications, 3.16%
Journal of Energy Storage	Journal of Energy Storage, 3, 3.16% Journal of Energy Storage 3 publications, 3.16%
ACS Nano	ACS Nano, 3, 3.16% ACS Nano 3 publications, 3.16%
Journal of Materials Chemistry A	Journal of Materials Chemistry A, 3, 3.16% Journal of Materials Chemistry A 3 publications, 3.16%
Journal of Materials Science	Journal of Materials Science, 2, 2.11% Journal of Materials Science 2 publications, 2.11%
RSC Advances	RSC Advances, 2, 2.11% RSC Advances 2 publications, 2.11%
Chinese Chemical Letters	Chinese Chemical Letters, 2, 2.11% Chinese Chemical Letters 2 publications, 2.11%
FlatChem	FlatChem, 2, 2.11% FlatChem 2 publications, 2.11%
Journal of Alloys and Compounds	Journal of Alloys and Compounds, 2, 2.11% Journal of Alloys and Compounds 2 publications, 2.11%
Nanotechnology	Nanotechnology, 2, 2.11% Nanotechnology 2 publications, 2.11%
Small	Small, 2, 2.11% Small 2 publications, 2.11%
Nanoscale	Nanoscale, 2, 2.11% Nanoscale 2 publications, 2.11%
ACS Symposium Series	ACS Symposium Series, 2, 2.11% ACS Symposium Series 2 publications, 2.11%
Nano Letters	Nano Letters, 1, 1.05% Nano Letters 1 publication, 1.05%
Diagnostics	Diagnostics, 1, 1.05% Diagnostics 1 publication, 1.05%
Scientific Reports	Scientific Reports, 1, 1.05% Scientific Reports 1 publication, 1.05%
Electrochemical Energy Reviews	Electrochemical Energy Reviews, 1, 1.05% Electrochemical Energy Reviews 1 publication, 1.05%
Chemosphere	Chemosphere, 1, 1.05% Chemosphere 1 publication, 1.05%
Materials Reports Energy	Materials Reports Energy, 1, 1.05% Materials Reports Energy 1 publication, 1.05%
Analytica Chimica Acta	Analytica Chimica Acta, 1, 1.05% Analytica Chimica Acta 1 publication, 1.05%
Composites Part B: Engineering	Composites Part B: Engineering, 1, 1.05% Composites Part B: Engineering 1 publication, 1.05%
Journal of Energy Chemistry	Journal of Energy Chemistry, 1, 1.05% Journal of Energy Chemistry 1 publication, 1.05%
Energy Storage Materials	Energy Storage Materials, 1, 1.05% Energy Storage Materials 1 publication, 1.05%
Journal of Electroanalytical Chemistry	Journal of Electroanalytical Chemistry, 1, 1.05% Journal of Electroanalytical Chemistry 1 publication, 1.05%
Catalysis Today	Catalysis Today, 1, 1.05% Catalysis Today 1 publication, 1.05%
Coordination Chemistry Reviews	Coordination Chemistry Reviews, 1, 1.05% Coordination Chemistry Reviews 1 publication, 1.05%
	1 2 3 4 5 6 7

Citations by publishers

	10 20 30 40 50
Elsevier	Elsevier, 50, 52.63% Elsevier 50 publications, 52.63%
American Chemical Society (ACS)	American Chemical Society (ACS), 14, 14.74% American Chemical Society (ACS) 14 publications, 14.74%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 9, 9.47% Royal Society of Chemistry (RSC) 9 publications, 9.47%
Wiley	Wiley, 7, 7.37% Wiley 7 publications, 7.37%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 4, 4.21% Multidisciplinary Digital Publishing Institute (MDPI) 4 publications, 4.21%
Springer Nature	Springer Nature, 4, 4.21% Springer Nature 4 publications, 4.21%
IOP Publishing	IOP Publishing, 2, 2.11% IOP Publishing 2 publications, 2.11%
Trans Tech Publications	Trans Tech Publications, 1, 1.05% Trans Tech Publications 1 publication, 1.05%
American Institute of Physics (AIP)	American Institute of Physics (AIP), 1, 1.05% American Institute of Physics (AIP) 1 publication, 1.05%
	10 20 30 40 50

We do not take into account publications that without a DOI.
Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
Statistics recalculated weekly.

{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2018,2019,2020,2021,2022,2023,2024],"ids":[0,0,0,0,0,0,0],"codes":[0,0,0,0,0,0,0],"imageUrls":["","","","","","",""],"datasets":[{"label":"Citations number","data":[5,9,15,20,24,17,5],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["5.26","9.47","15.79","21.05","25.26","17.89","5.26"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Electrochimica Acta","Ceramics International","Chemical Engineering Journal","Nanomaterials","Journal of Energy Storage","ACS Nano","Journal of Materials Chemistry A","Journal of Materials Science","RSC Advances","Chinese Chemical Letters","FlatChem","Journal of Alloys and Compounds","Nanotechnology","Small","Nanoscale","ACS Symposium Series","Nano Letters","Diagnostics","Scientific Reports","Electrochemical Energy Reviews","Chemosphere","Materials Reports Energy","Analytica Chimica Acta","Composites Part B: Engineering","Journal of Energy Chemistry","Energy Storage Materials","Journal of Electroanalytical Chemistry","Catalysis Today","Coordination Chemistry Reviews"],"ids":[15613,15103,16275,10051,18623,8724,14919,11453,3100,20341,16384,4015,16187,9872,228,23301,10312,18499,13767,25884,22418,28048,19094,10468,20653,3858,22454,14481,13437],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/LsKy6OnmmmRGcAU6CZgWQvNiP1polbaSLNrN7zqj_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp"],"datasets":[{"label":"","data":[7,4,4,3,3,3,3,2,2,2,2,2,2,2,2,2,1,1,1,1,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[7.37,4.21,4.21,3.16,3.16,3.16,3.16,2.11,2.11,2.11,2.11,2.11,2.11,2.11,2.11,2.11,1.05,1.05,1.05,1.05,1.05,1.05,1.05,1.05,1.05,1.05,1.05,1.05,1.05],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Elsevier","American Chemical Society (ACS)","Royal Society of Chemistry (RSC)","Wiley","Multidisciplinary Digital Publishing Institute (MDPI)","Springer Nature","IOP Publishing","Trans Tech Publications","American Institute of Physics (AIP)"],"ids":[17,40,123,11,202,8,2075,104,250],"codes":[0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/LsKy6OnmmmRGcAU6CZgWQvNiP1polbaSLNrN7zqj_medium.webp","\/storage\/images\/resized\/lZMRu5MhhE0HtEBGlENti9uMMEivcrzFOV6rqpGN_medium.webp","\/storage\/images\/resized\/ARM4e6URKRsbRZvIF0vFis9DjxGloBjnBYJXbHmZ_medium.webp"],"datasets":[{"label":"","data":[50,14,9,7,4,4,2,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[52.63,14.74,9.47,7.37,4.21,4.21,2.11,1.05,1.05],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}

Metrics

Cite this

GOST |

Cite this

GOST Copy

Kong F. et al. Improving the electrochemical properties of MXene Ti3C2 multilayer for Li-ion batteries by vacuum calcination // Electrochimica Acta. 2018. Vol. 265. pp. 140-150.

GOST all authors (up to 50) Copy

Kong F., He X., Liu Q., Qi X., Zheng Y., Wang R., Bai Y. Improving the electrochemical properties of MXene Ti3C2 multilayer for Li-ion batteries by vacuum calcination // Electrochimica Acta. 2018. Vol. 265. pp. 140-150.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1016/j.electacta.2018.01.196

UR - https://doi.org/10.1016%2Fj.electacta.2018.01.196

TI - Improving the electrochemical properties of MXene Ti3C2 multilayer for Li-ion batteries by vacuum calcination

T2 - Electrochimica Acta

AU - Kong, Fanyu

AU - He, Xiaodong

AU - Liu, Qianqian

AU - Qi, Xinxin

AU - Zheng, Yongting

AU - Wang, Rongguo

AU - Bai, Yuelei

PY - 2018

DA - 2018/03/01 00:00:00

PB - Elsevier

SP - 140-150

VL - 265

SN - 0013-4686

ER -

BibTex

Cite this

BibTex Copy

@article{2018_Kong,

author = {Fanyu Kong and Xiaodong He and Qianqian Liu and Xinxin Qi and Yongting Zheng and Rongguo Wang and Yuelei Bai},

title = {Improving the electrochemical properties of MXene Ti3C2 multilayer for Li-ion batteries by vacuum calcination},

journal = {Electrochimica Acta},

year = {2018},

volume = {265},

publisher = {Elsevier},

month = {mar},

url = {https://doi.org/10.1016%2Fj.electacta.2018.01.196},

pages = {140--150},

doi = {10.1016/j.electacta.2018.01.196}

}

Found error?

Publisher

Elsevier

Journal

Electrochimica Acta

Quartile SCImago

Quartile WOS

Impact factor

6.6

ISSN

00134686 (Print)