Electrochimica Acta, volume 334, pages 135512

Efficient gel-polymer electrolyte for sodium-ion batteries based on poly(acrylonitrile-co-methyl acrylate)

Lonchakova O V ¹

Karpushkin E A

Zakharkin M V

ANTIPOV E. V.

Semenikhin O.A. ¹

Sergeyev V. G.

Zakharkin Maxim V. ^{1, 2}

Karpushkin Evgeny A. ¹

Sergeyev Vladimir G. ¹

Antipov Evgeny V. ^{1, 2}

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Department of Chemistry, M.V. Lomonosov Moscow State University, 1-3 Leninskiye Gory, Moscow, 119991, Russia |

Skolkovo Institute of Science and Technology, 3 Nobel St., Moscow, 143025, Russia |

Publication type: Journal Article

Publication date: 2020-02-01

Elsevier

Journal: Electrochimica Acta

Quartile SCImago

Quartile WOS

Impact factor: 6.6

ISSN: 00134686

DOI: 10.1016/j.electacta.2019.135512

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General Chemical Engineering

Electrochemistry

Abstract

Abstract Efficient polyacrylonitrile-based gel-polymer electrolyte for sodium-ion batteries was prepared using commercially available copolymer poly(acrylonitrile-co-methyl acrylate), propylene carbonate as plasticizer, and NaClO4 or NaPF6 as electrolyte salts. Specific and molar conductivities were determined at different salt concentrations using the ac impedance technique with reversible rather than blocking electrodes. The cation transference numbers were measured using the potentiostatic polarization technique. The electrolytes showed high room-temperature ionic conductivities up to 1.8 × 10−3 S cm−1 and high cation transference numbers up to 0.89. The conductivity followed the Arrhenius behavior with the activation energy of 12–15 kJ mol−1. The polymer electrolyte was able to sustain over 700 charge-discharge cycles in full sodium-ion cells at room temperature and at −20 °C. The results indicate that polyacrylonitrile-based gel-polymer electrolytes are promising systems to replace liquid electrolytes in future sodium-ion batteries.

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Citations by journals

	1 2 3
Energy Storage Materials	Energy Storage Materials, 3, 11.54% Energy Storage Materials 3 publications, 11.54%
ACS Energy Letters	ACS Energy Letters, 2, 7.69% ACS Energy Letters 2 publications, 7.69%
Journal of Energy Storage	Journal of Energy Storage, 2, 7.69% Journal of Energy Storage 2 publications, 7.69%
Russian Chemical Reviews	Russian Chemical Reviews, 1, 3.85% Russian Chemical Reviews 1 publication, 3.85%
Inorganic Materials	Inorganic Materials, 1, 3.85% Inorganic Materials 1 publication, 3.85%
Journal of Materials Science: Materials in Electronics	Journal of Materials Science: Materials in Electronics, 1, 3.85% Journal of Materials Science: Materials in Electronics 1 publication, 3.85%
Heliyon	Heliyon, 1, 3.85% Heliyon 1 publication, 3.85%
Journal of Power Sources	Journal of Power Sources, 1, 3.85% Journal of Power Sources 1 publication, 3.85%
Electrochimica Acta	Electrochimica Acta, 1, 3.85% Electrochimica Acta 1 publication, 3.85%
Journal of Alloys and Compounds	Journal of Alloys and Compounds, 1, 3.85% Journal of Alloys and Compounds 1 publication, 3.85%
Polymer	Polymer, 1, 3.85% Polymer 1 publication, 3.85%
Small	Small, 1, 3.85% Small 1 publication, 3.85%
ACS Applied Polymer Materials	ACS Applied Polymer Materials, 1, 3.85% ACS Applied Polymer Materials 1 publication, 3.85%
ACS applied materials & interfaces	ACS applied materials & interfaces, 1, 3.85% ACS applied materials & interfaces 1 publication, 3.85%
ACS Sustainable Chemistry and Engineering	ACS Sustainable Chemistry and Engineering, 1, 3.85% ACS Sustainable Chemistry and Engineering 1 publication, 3.85%
Journal of Materials Chemistry A	Journal of Materials Chemistry A, 1, 3.85% Journal of Materials Chemistry A 1 publication, 3.85%
Journal of the Electrochemical Society	Journal of the Electrochemical Society, 1, 3.85% Journal of the Electrochemical Society 1 publication, 3.85%
Energy & Environmental Materials	Energy & Environmental Materials, 1, 3.85% Energy & Environmental Materials 1 publication, 3.85%
Electrochemical Energy Reviews	Electrochemical Energy Reviews, 1, 3.85% Electrochemical Energy Reviews 1 publication, 3.85%
Colloids and Surfaces A: Physicochemical and Engineering Aspects	Colloids and Surfaces A: Physicochemical and Engineering Aspects, 1, 3.85% Colloids and Surfaces A: Physicochemical and Engineering Aspects 1 publication, 3.85%
Batteries	Batteries, 1, 3.85% Batteries 1 publication, 3.85%
	1 2 3

Citations by publishers

	2 4 6 8 10 12
Elsevier	Elsevier, 11, 42.31% Elsevier 11 publications, 42.31%
American Chemical Society (ACS)	American Chemical Society (ACS), 5, 19.23% American Chemical Society (ACS) 5 publications, 19.23%
Springer Nature	Springer Nature, 2, 7.69% Springer Nature 2 publications, 7.69%
Wiley	Wiley, 2, 7.69% Wiley 2 publications, 7.69%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 3.85% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 3.85%
Pleiades Publishing	Pleiades Publishing, 1, 3.85% Pleiades Publishing 1 publication, 3.85%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 1, 3.85% Royal Society of Chemistry (RSC) 1 publication, 3.85%
The Electrochemical Society	The Electrochemical Society, 1, 3.85% The Electrochemical Society 1 publication, 3.85%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 1, 3.85% Multidisciplinary Digital Publishing Institute (MDPI) 1 publication, 3.85%
	2 4 6 8 10 12

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Lonchakova O. V. et al. Efficient gel-polymer electrolyte for sodium-ion batteries based on poly(acrylonitrile-co-methyl acrylate) // Electrochimica Acta. 2020. Vol. 334. p. 135512.

GOST all authors (up to 50) Copy

Lonchakova O. V., Semenikhin O., Zakharkin M. V., Karpushkin E. A., Sergeyev V. G., ANTIPOV E. V., Zakharkin M. V., Karpushkin E. A., Sergeyev V. G., Antipov E. V. Efficient gel-polymer electrolyte for sodium-ion batteries based on poly(acrylonitrile-co-methyl acrylate) // Electrochimica Acta. 2020. Vol. 334. p. 135512.

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RIS Copy

TY - JOUR

DO - 10.1016/j.electacta.2019.135512

UR - https://doi.org/10.1016%2Fj.electacta.2019.135512

TI - Efficient gel-polymer electrolyte for sodium-ion batteries based on poly(acrylonitrile-co-methyl acrylate)

T2 - Electrochimica Acta

AU - Lonchakova, O V

AU - Semenikhin, O.A.

AU - Zakharkin, M V

AU - Karpushkin, E A

AU - Sergeyev, V. G.

AU - ANTIPOV, E. V.

AU - Zakharkin, Maxim V.

AU - Karpushkin, Evgeny A.

AU - Sergeyev, Vladimir G.

AU - Antipov, Evgeny V.

PY - 2020

DA - 2020/02/01 00:00:00

PB - Elsevier

SP - 135512

VL - 334

SN - 0013-4686

ER -

BibTex

Cite this

BibTex Copy

@article{2020_Lonchakova,

author = {O V Lonchakova and O.A. Semenikhin and M V Zakharkin and E A Karpushkin and V. G. Sergeyev and E. V. ANTIPOV and Maxim V. Zakharkin and Evgeny A. Karpushkin and Vladimir G. Sergeyev and Evgeny V. Antipov},

title = {Efficient gel-polymer electrolyte for sodium-ion batteries based on poly(acrylonitrile-co-methyl acrylate)},

journal = {Electrochimica Acta},

year = {2020},

volume = {334},

publisher = {Elsevier},

month = {feb},

url = {https://doi.org/10.1016%2Fj.electacta.2019.135512},

pages = {135512},

doi = {10.1016/j.electacta.2019.135512}

}

Found error?

Publisher

Elsevier

Journal

Electrochimica Acta

Quartile SCImago

Quartile WOS

Impact factor

6.6

ISSN

00134686 (Print)

Labs

Laboratory of Materials for Electrochemical Processes

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