Electrochimica Acta, volume 368, pages 137637

Electrochemical synthesis and characterization of poly [Ni(CH3Osalen)] with immobilized poly(styrenesulfonate) anion dopants

Apraksin R V ¹

Levin Oleg V. ²

Volkov Alexey I ²

Lukyanov Daniil A ²

Volosatova Y A ²

Kulikov I R ³

Eliseeva S. N.

Vlasov P S

Власов П. К. ²

Eliseeva S. N. ²

Hide authors affiliations Show authors affiliations: 3 affiliations

Ioffe Institute, 26 Politekhnicheskaya Str., St. Petersburg 194021, Russia |

Department of Electrochemistry, Institute of Chemistry, St. Petersburg State University, 7/9 Universitetskaya Nab., St. Petersburg 199034, Russia |

Berlin Joint EPR Lab Fachbereich Physik Freie Universität Berlin Berlin D‐14195 Germany |

Publication type: Journal Article

Publication date: 2021-02-01

Elsevier

Journal: Electrochimica Acta

Quartile SCImago

Quartile WOS

Impact factor: 6.6

ISSN: 00134686

DOI: 10.1016/j.electacta.2020.137637

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General Chemical Engineering

Electrochemistry

Abstract

Abstract Intrinsically conductive polymer poly(N,N′-bis(3-methoxysalicylidene)ethylenediamine nickel(II)) (poly[Ni(CH3Osalen)]:PSS) has been synthesized by electrochemical polymerization from the [Ni(CH3Osalen)] solution containing tetrabutylammonium poly(styrenesulfonate) (TBAPSS). Cyclic voltammetry and in situ EQCM data demonstrated that electrochemical properties of poly[Ni(CH3Osalen)]:PSS are highly dependent on the nature of electrolyte solutions. A wider range of electrochemical activity, higher values of conductance and binary diffusion coefficient in TBAPSS solution are observed than in LiClO4, but the capacity values of films are higher in LiClO4 solution. The introduction of PSS− polyanion during synthesis of polymer film induced cationic mode of charge transport for poly[Ni(CH3Osalen)]. This type of PSS− doped polymers can be used as ion-exchange membranes. The combined electrochemical impedance spectroscopy and in situ conductance measurements on interdigitated electrodes were analyzed using the model concepts of Matthias and Haas, and Einstein relation. This novel approach allowed separating the diffusion coefficient into its ionic and electronic constituents. The ionic diffusion was found to be the limiting factor. Strong association of lithium cation with both the PSS− polyanion and methoxy-groups may be the cause of lower values of diffusion coefficients in LiClO4 solutions. The proposed model is suitable for further studies of similar systems.

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Catalysts	Catalysts, 1, 12.5% Catalysts 1 publication, 12.5%
ACS Applied Energy Materials	ACS Applied Energy Materials, 1, 12.5% ACS Applied Energy Materials 1 publication, 12.5%
Electrochimica Acta	Electrochimica Acta, 1, 12.5% Electrochimica Acta 1 publication, 12.5%
Nanomaterials	Nanomaterials, 1, 12.5% Nanomaterials 1 publication, 12.5%
Molecules	Molecules, 1, 12.5% Molecules 1 publication, 12.5%
MolBank	MolBank, 1, 12.5% MolBank 1 publication, 12.5%
Polymers	Polymers, 1, 12.5% Polymers 1 publication, 12.5%
AIP Conference Proceedings	AIP Conference Proceedings, 1, 12.5% AIP Conference Proceedings 1 publication, 12.5%
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Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 5, 62.5% Multidisciplinary Digital Publishing Institute (MDPI) 5 publications, 62.5%
American Chemical Society (ACS)	American Chemical Society (ACS), 1, 12.5% American Chemical Society (ACS) 1 publication, 12.5%
Elsevier	Elsevier, 1, 12.5% Elsevier 1 publication, 12.5%
American Institute of Physics (AIP)	American Institute of Physics (AIP), 1, 12.5% American Institute of Physics (AIP) 1 publication, 12.5%
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Apraksin R. V. et al. Electrochemical synthesis and characterization of poly [Ni(CH3Osalen)] with immobilized poly(styrenesulfonate) anion dopants // Electrochimica Acta. 2021. Vol. 368. p. 137637.

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Apraksin R. V., Volosatova Y. A., Volkov A. I., Lukyanov D. A., Kulikov I. R., Levin O. V., Vlasov P. S., Eliseeva S. N., Власов П. К., Eliseeva S. N. Electrochemical synthesis and characterization of poly [Ni(CH3Osalen)] with immobilized poly(styrenesulfonate) anion dopants // Electrochimica Acta. 2021. Vol. 368. p. 137637.

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TY - JOUR

DO - 10.1016/j.electacta.2020.137637

UR - https://doi.org/10.1016%2Fj.electacta.2020.137637

TI - Electrochemical synthesis and characterization of poly [Ni(CH3Osalen)] with immobilized poly(styrenesulfonate) anion dopants

T2 - Electrochimica Acta

AU - Apraksin, R V

AU - Volosatova, Y A

AU - Volkov, Alexey I

AU - Lukyanov, Daniil A

AU - Kulikov, I R

AU - Levin, Oleg V.

AU - Vlasov, P S

AU - Eliseeva, S. N.

AU - Власов, П. К.

AU - Eliseeva, S. N.

PY - 2021

DA - 2021/02/01 00:00:00

PB - Elsevier

SP - 137637

VL - 368

SN - 0013-4686

ER -

BibTex

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BibTex Copy

@article{2021_Apraksin,

author = {R V Apraksin and Y A Volosatova and Alexey I Volkov and Daniil A Lukyanov and I R Kulikov and Oleg V. Levin and P S Vlasov and S. N. Eliseeva and П. К. Власов and S. N. Eliseeva},

title = {Electrochemical synthesis and characterization of poly [Ni(CH3Osalen)] with immobilized poly(styrenesulfonate) anion dopants},

journal = {Electrochimica Acta},

year = {2021},

volume = {368},

publisher = {Elsevier},

month = {feb},

url = {https://doi.org/10.1016%2Fj.electacta.2020.137637},

pages = {137637},

doi = {10.1016/j.electacta.2020.137637}

}

Found error?

Publisher

Elsevier

Journal

Electrochimica Acta

Quartile SCImago

Quartile WOS

Impact factor

6.6

ISSN

00134686 (Print)

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