Ni(II) and Cu(II) based catalysts for propargylated novolac resins curing: Activity study and curing process simulation
Boris Bulgakov
1
,
Alexander Babkin
1
,
Irina Makarenko
2
,
Nikolay Tikhonov
1
,
Denis Kalugin
2
,
Alexey Kepman
1
,
A.P Malakho
1
,
Viktor Avdeev
1
Publication type: Journal Article
Publication date: 2015-12-01
scimago Q1
wos Q1
SJR: 1.076
CiteScore: 10.2
Impact factor: 6.3
ISSN: 00143057, 18731945
Materials Chemistry
Organic Chemistry
General Physics and Astronomy
Polymers and Plastics
Abstract
Abstract Catalysts for propargylated novolac resins ( PN ) curing based on stable Ni and Cu salts were studied. Concentration dependences of catalytic activities for both catalyst types were investigated. For the first time copper salts were suggested as catalysts for PN curing and catalytic action mechanism was suggested based on model experiments. Catalytic kinetic study followed by computer modeling allowed to simulate the curing process avoiding overheating during manufacturing of bulky composite part. A sufficient decrease both in processing time and temperature was demonstrated even under smoother thermal conditions while using the Ni catalysis. It was also shown that catalyzed curing proceeded more uniformly in the volume of bulky parts.
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Total citations:
14
Citations from 2024:
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GOST
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Bulgakov B. et al. Ni(II) and Cu(II) based catalysts for propargylated novolac resins curing: Activity study and curing process simulation // European Polymer Journal. 2015. Vol. 73. pp. 247-258.
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Bulgakov B., Babkin A., Makarenko I., Tikhonov N., Kalugin D., Kepman A., Malakho A., Avdeev V. Ni(II) and Cu(II) based catalysts for propargylated novolac resins curing: Activity study and curing process simulation // European Polymer Journal. 2015. Vol. 73. pp. 247-258.
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RIS
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TY - JOUR
DO - 10.1016/j.eurpolymj.2015.10.018
UR - https://linkinghub.elsevier.com/retrieve/pii/S0014305715300240
TI - Ni(II) and Cu(II) based catalysts for propargylated novolac resins curing: Activity study and curing process simulation
T2 - European Polymer Journal
AU - Bulgakov, Boris
AU - Babkin, Alexander
AU - Makarenko, Irina
AU - Tikhonov, Nikolay
AU - Kalugin, Denis
AU - Kepman, Alexey
AU - Malakho, A.P
AU - Avdeev, Viktor
PY - 2015
DA - 2015/12/01
PB - Elsevier
SP - 247-258
VL - 73
SN - 0014-3057
SN - 1873-1945
ER -
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BibTex (up to 50 authors)
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@article{2015_Bulgakov,
author = {Boris Bulgakov and Alexander Babkin and Irina Makarenko and Nikolay Tikhonov and Denis Kalugin and Alexey Kepman and A.P Malakho and Viktor Avdeev},
title = {Ni(II) and Cu(II) based catalysts for propargylated novolac resins curing: Activity study and curing process simulation},
journal = {European Polymer Journal},
year = {2015},
volume = {73},
publisher = {Elsevier},
month = {dec},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0014305715300240},
pages = {247--258},
doi = {10.1016/j.eurpolymj.2015.10.018}
}