European Polymer Journal, volume 84, pages 205-217

Low-melting phthalonitrile thermosetting monomers with siloxane- and phosphate bridges

Publication typeJournal Article
Publication date2016-11-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor6
ISSN00143057
Materials Chemistry
Organic Chemistry
General Physics and Astronomy
Polymers and Plastics
Abstract
Abstract The series of low-melting siloxane- and phosphate-bridged phthalonitriles are studied. The monomers of this type possess glass transition temperatures more than 100 °C lower than for common phthalonitriles. Based on the collected experimental data molecular dynamics simulations aimed to predict glass-transition temperatures of the considered types of low-melting phthalonitriles are reported. The validity of computational model is confirmed by successful synthesis of the new monomers, e.g. phosphate- and phosphonate-bridged phthalonitriles are introduced for a first time. Cured Bis(3-(3,4-dicyanophenoxy)phenyl) phenyl phosphate demonstrates thermal performance featured to phthalonitriles (HDT ∼ 450 °C, T 5%  = 524 °C, Y c , (Ar) = 80%) along with increased thermo-oxidative stability. In aggregate with convenient processing the considered phthalonitriles can be used as high-temperature matrices for fiber-reinforced plastics production by vacuum infusion or RTM techniques.

Citations by journals

1
2
3
4
5
Reactive and Functional Polymers
Reactive and Functional Polymers, 5, 10.42%
Reactive and Functional Polymers
5 publications, 10.42%
Mendeleev Communications
Mendeleev Communications, 5, 10.42%
Mendeleev Communications
5 publications, 10.42%
European Polymer Journal
European Polymer Journal, 5, 10.42%
European Polymer Journal
5 publications, 10.42%
Polymer
Polymer, 4, 8.33%
Polymer
4 publications, 8.33%
Journal of Applied Polymer Science
Journal of Applied Polymer Science, 3, 6.25%
Journal of Applied Polymer Science
3 publications, 6.25%
Polymer Science - Series C
Polymer Science - Series C, 2, 4.17%
Polymer Science - Series C
2 publications, 4.17%
Materials Today Communications
Materials Today Communications, 2, 4.17%
Materials Today Communications
2 publications, 4.17%
High Performance Polymers
High Performance Polymers, 2, 4.17%
High Performance Polymers
2 publications, 4.17%
Thermochimica Acta
Thermochimica Acta, 2, 4.17%
Thermochimica Acta
2 publications, 4.17%
ChemistrySelect
ChemistrySelect, 2, 4.17%
ChemistrySelect
2 publications, 4.17%
Journal of Composite Materials
Journal of Composite Materials, 1, 2.08%
Journal of Composite Materials
1 publication, 2.08%
Russian Chemical Bulletin
Russian Chemical Bulletin, 1, 2.08%
Russian Chemical Bulletin
1 publication, 2.08%
IOP Conference Series: Materials Science and Engineering
IOP Conference Series: Materials Science and Engineering, 1, 2.08%
IOP Conference Series: Materials Science and Engineering
1 publication, 2.08%
Polymers
Polymers, 1, 2.08%
Polymers
1 publication, 2.08%
Data in Brief
Data in Brief, 1, 2.08%
Data in Brief
1 publication, 2.08%
Journal of Polymer Science, Part B: Polymer Physics
Journal of Polymer Science, Part B: Polymer Physics, 1, 2.08%
Journal of Polymer Science, Part B: Polymer Physics
1 publication, 2.08%
Fine Chemical Technologies
Fine Chemical Technologies, 1, 2.08%
Fine Chemical Technologies
1 publication, 2.08%
Journal of Chemical Physics
Journal of Chemical Physics, 1, 2.08%
Journal of Chemical Physics
1 publication, 2.08%
Iranian Polymer Journal (English Edition)
Iranian Polymer Journal (English Edition), 1, 2.08%
Iranian Polymer Journal (English Edition)
1 publication, 2.08%
Macromolecular Theory and Simulations
Macromolecular Theory and Simulations, 1, 2.08%
Macromolecular Theory and Simulations
1 publication, 2.08%
Industrial & Engineering Chemistry Research
Industrial & Engineering Chemistry Research, 1, 2.08%
Industrial & Engineering Chemistry Research
1 publication, 2.08%
New Journal of Chemistry
New Journal of Chemistry, 1, 2.08%
New Journal of Chemistry
1 publication, 2.08%
International Journal of Materials Research
International Journal of Materials Research, 1, 2.08%
International Journal of Materials Research
1 publication, 2.08%
Polymer Journal
Polymer Journal, 1, 2.08%
Polymer Journal
1 publication, 2.08%
Polymer Composites
Polymer Composites, 1, 2.08%
Polymer Composites
1 publication, 2.08%
ACS Applied Polymer Materials
ACS Applied Polymer Materials, 1, 2.08%
ACS Applied Polymer Materials
1 publication, 2.08%
1
2
3
4
5

Citations by publishers

5
10
15
20
25
Elsevier
Elsevier, 24, 50%
Elsevier
24 publications, 50%
Wiley
Wiley, 8, 16.67%
Wiley
8 publications, 16.67%
SAGE
SAGE, 3, 6.25%
SAGE
3 publications, 6.25%
Springer Nature
Springer Nature, 3, 6.25%
Springer Nature
3 publications, 6.25%
Pleiades Publishing
Pleiades Publishing, 2, 4.17%
Pleiades Publishing
2 publications, 4.17%
American Chemical Society (ACS)
American Chemical Society (ACS), 2, 4.17%
American Chemical Society (ACS)
2 publications, 4.17%
IOP Publishing
IOP Publishing, 1, 2.08%
IOP Publishing
1 publication, 2.08%
Multidisciplinary Digital Publishing Institute (MDPI)
Multidisciplinary Digital Publishing Institute (MDPI), 1, 2.08%
Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 2.08%
RTU MIREA
RTU MIREA, 1, 2.08%
RTU MIREA
1 publication, 2.08%
American Institute of Physics (AIP)
American Institute of Physics (AIP), 1, 2.08%
American Institute of Physics (AIP)
1 publication, 2.08%
Royal Society of Chemistry (RSC)
Royal Society of Chemistry (RSC), 1, 2.08%
Royal Society of Chemistry (RSC)
1 publication, 2.08%
Walter de Gruyter
Walter de Gruyter, 1, 2.08%
Walter de Gruyter
1 publication, 2.08%
5
10
15
20
25
  • We do not take into account publications that without a DOI.
  • Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
  • Statistics recalculated weekly.
Metrics
Share
Cite this
GOST |
Cite this
GOST Copy
Bulgakov B. et al. Low-melting phthalonitrile thermosetting monomers with siloxane- and phosphate bridges // European Polymer Journal. 2016. Vol. 84. pp. 205-217.
GOST all authors (up to 50) Copy
Bulgakov B., Babkin A., Dzhevakov P. B., Bogolyubov A. A., Sulimov A. V., Kepman A., Kolyagin Y. G., Guseva D. V., Rudyak V., Chertovich A. V. Low-melting phthalonitrile thermosetting monomers with siloxane- and phosphate bridges // European Polymer Journal. 2016. Vol. 84. pp. 205-217.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.eurpolymj.2016.09.013
UR - https://doi.org/10.1016%2Fj.eurpolymj.2016.09.013
TI - Low-melting phthalonitrile thermosetting monomers with siloxane- and phosphate bridges
T2 - European Polymer Journal
AU - Sulimov, A V
AU - Kepman, A.V.
AU - Bulgakov, Boris
AU - Babkin, Alexander
AU - Dzhevakov, Pavel B
AU - Bogolyubov, A A
AU - Kolyagin, Yuri G
AU - Guseva, D. V.
AU - Rudyak, Vladimir
AU - Chertovich, Alexander V.
PY - 2016
DA - 2016/11/01 00:00:00
PB - Elsevier
SP - 205-217
VL - 84
SN - 0014-3057
ER -
BibTex
Cite this
BibTex Copy
@article{2016_Bulgakov
author = {A V Sulimov and A.V. Kepman and Boris Bulgakov and Alexander Babkin and Pavel B Dzhevakov and A A Bogolyubov and Yuri G Kolyagin and D. V. Guseva and Vladimir Rudyak and Alexander V. Chertovich},
title = {Low-melting phthalonitrile thermosetting monomers with siloxane- and phosphate bridges},
journal = {European Polymer Journal},
year = {2016},
volume = {84},
publisher = {Elsevier},
month = {nov},
url = {https://doi.org/10.1016%2Fj.eurpolymj.2016.09.013},
pages = {205--217},
doi = {10.1016/j.eurpolymj.2016.09.013}
}
Found error?