Halogen ligands exchange in palladium(II) acyclic diaminocarbene complexes and their stereochemistry
Publication type: Journal Article
Publication date: 2017-03-01
scimago Q3
wos Q2
SJR: 0.393
CiteScore: 5.5
Impact factor: 3.2
ISSN: 00201693, 18733255
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Palladium(II) diaminocarbene complexes trans-[PdI2(CNXyl){C(NHXyl) = NHNHC(O)R}] (4a–h) bearing iodide anionic ligands were synthesised via ligands exchange from the corresponding chloride species cis-[PdCl2(CNXyl){C(NHXyl) NHNHC(O)R}] (3a–h) and KI in an acetone solution. Complexes 4a–h were isolated and characterized by HRESI+-MS, IR, 1H and 13C{1H} NMR spectroscopies, and single-crystal X-ray diffraction (in the case of complexes 4a–e, 4g and 4h). The entire synthesised compounds exhibit slightly distorted square planar geometry around the metal centre. The carbene and isocyanide ligands in the synthesised iodide complexes are in trans-position each other in contrast to the starting cis-dichloride species.
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Boyarskaya D. V. et al. Halogen ligands exchange in palladium(II) acyclic diaminocarbene complexes and their stereochemistry // Inorganica Chimica Acta. 2017. Vol. 458. pp. 190-198.
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Boyarskaya D. V., Kinzhalov M. A., Suslonov V. V., Boyarskiy V. P. Halogen ligands exchange in palladium(II) acyclic diaminocarbene complexes and their stereochemistry // Inorganica Chimica Acta. 2017. Vol. 458. pp. 190-198.
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TY - JOUR
DO - 10.1016/j.ica.2017.01.008
UR - https://doi.org/10.1016/j.ica.2017.01.008
TI - Halogen ligands exchange in palladium(II) acyclic diaminocarbene complexes and their stereochemistry
T2 - Inorganica Chimica Acta
AU - Boyarskaya, Dina V
AU - Kinzhalov, M. A.
AU - Suslonov, Vitalii V
AU - Boyarskiy, Vadim P
PY - 2017
DA - 2017/03/01
PB - Elsevier
SP - 190-198
VL - 458
SN - 0020-1693
SN - 1873-3255
ER -
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@article{2017_Boyarskaya,
author = {Dina V Boyarskaya and M. A. Kinzhalov and Vitalii V Suslonov and Vadim P Boyarskiy},
title = {Halogen ligands exchange in palladium(II) acyclic diaminocarbene complexes and their stereochemistry},
journal = {Inorganica Chimica Acta},
year = {2017},
volume = {458},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016/j.ica.2017.01.008},
pages = {190--198},
doi = {10.1016/j.ica.2017.01.008}
}
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