Control of the composition and crystal structure of exchange reaction products of rare-earth acetates with pivalic acid
I.G. Fomina
1
,
A Gavrikov
1
,
Grygory G. Aleksandrov
1
,
Elena V Fatyushina
1
,
Sergey Yu Gavrilkin
2
,
Publication type: Journal Article
Publication date: 2018-10-01
scimago Q3
wos Q2
SJR: 0.393
CiteScore: 5.5
Impact factor: 3.2
ISSN: 00201693, 18733255
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract The rare-earth metal(III) complexes [M2(piv)6(Hpiv)6] (monoclinic, P21/c, 1), [M2(piv)6(Hpiv)6]·Hpiv (monoclinic, C2/c, 2), [M(piv)3]n (trigonal, P63/m, 3), and [(Hpiv)2(iPrOH)2Sm2(piv)6]·2Hpiv (triclinic, P-1, 4), where piv is (CH3)3CCO2−, were synthesized, and their structures were determined by single-crystal X-ray diffraction (SC-XRD). The crystallization was shown to be controllable by varying the nature of the salting-out agent – the non-coordinating organic solvent in the M(OAc)3·4H2O–Hpiv system. The following bulky single-phase samples were obtained: dimers 1 or 2 with M = Pr, Nd, Sm, Eu, and Gd using hexane C6H14; dimer 1 or 1D polymer 3 with M = Y, Er, and Yb using EtOH; dimers 2 or 4 with M = Sm using iPrOH. A reversible phase transition to a commensurate modulated modification (P21/c) was observed for crystals of 1 (Pn). The magnetic properties of complexes 1a (Pr), 1b (Nd), 4 (Sm), 1d (Eu), 1f (Dy), 1 g (Ho), and 1 h (Er) were investigated.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
|
|
|
Pure and Applied Chemistry
1 publication, 11.11%
|
|
|
European Journal of Inorganic Chemistry
1 publication, 11.11%
|
|
|
Polyhedron
1 publication, 11.11%
|
|
|
Journal of Cluster Science
1 publication, 11.11%
|
|
|
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
1 publication, 11.11%
|
|
|
Координационная химия
1 publication, 11.11%
|
|
|
New Journal of Chemistry
1 publication, 11.11%
|
|
|
Optical Materials
1 publication, 11.11%
|
|
|
Journal of Luminescence
1 publication, 11.11%
|
|
|
1
|
Publishers
|
1
2
3
|
|
|
Elsevier
3 publications, 33.33%
|
|
|
Pleiades Publishing
2 publications, 22.22%
|
|
|
Walter de Gruyter
1 publication, 11.11%
|
|
|
Wiley
1 publication, 11.11%
|
|
|
Springer Nature
1 publication, 11.11%
|
|
|
Royal Society of Chemistry (RSC)
1 publication, 11.11%
|
|
|
1
2
3
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
9
Total citations:
9
Citations from 2024:
3
(33%)
Cite this
GOST |
RIS |
BibTex
Cite this
GOST
Copy
Fomina I. et al. Control of the composition and crystal structure of exchange reaction products of rare-earth acetates with pivalic acid // Inorganica Chimica Acta. 2018. Vol. 482. pp. 8-15.
GOST all authors (up to 50)
Copy
Fomina I., Ilyukhin A. B., Gavrikov A., Aleksandrov G. G., Fatyushina E. V., Gavrilkin S. Yu., Bogomyakov A. S., Eremenko I. L. Control of the composition and crystal structure of exchange reaction products of rare-earth acetates with pivalic acid // Inorganica Chimica Acta. 2018. Vol. 482. pp. 8-15.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.ica.2018.05.033
UR - https://linkinghub.elsevier.com/retrieve/pii/S0020169318305036
TI - Control of the composition and crystal structure of exchange reaction products of rare-earth acetates with pivalic acid
T2 - Inorganica Chimica Acta
AU - Fomina, I.G.
AU - Ilyukhin, Andrey B.
AU - Gavrikov, A
AU - Aleksandrov, Grygory G.
AU - Fatyushina, Elena V
AU - Gavrilkin, Sergey Yu
AU - Bogomyakov, Artem S
AU - Eremenko, Igor L.
PY - 2018
DA - 2018/10/01
PB - Elsevier
SP - 8-15
VL - 482
SN - 0020-1693
SN - 1873-3255
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2018_Fomina,
author = {I.G. Fomina and Andrey B. Ilyukhin and A Gavrikov and Grygory G. Aleksandrov and Elena V Fatyushina and Sergey Yu Gavrilkin and Artem S Bogomyakov and Igor L. Eremenko},
title = {Control of the composition and crystal structure of exchange reaction products of rare-earth acetates with pivalic acid},
journal = {Inorganica Chimica Acta},
year = {2018},
volume = {482},
publisher = {Elsevier},
month = {oct},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0020169318305036},
pages = {8--15},
doi = {10.1016/j.ica.2018.05.033}
}