Transformations of acetone in reactions with carboxylate complexes of palladium: Crystal structure of Pd4 (μ-CF3 CO 2 )4 (μ,k2-CH2 C(O)CH 3 )2 (η3-CH2 C(OH)CH 2 )2 •2CH3 C(O)CH3
Inessa A Efimenko
1
,
Roman E Podobedov
1
,
O.N. Shishilov
1
,
Yaroslavna N Rezinkova
2
,
Irina A Garbuzova
3
,
Boris Lokshin
3
Publication type: Journal Article
Publication date: 2011-02-01
scimago Q1
wos Q1
SJR: 0.758
CiteScore: 6.7
Impact factor: 5.4
ISSN: 13877003, 18790259
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract Interaction of palladium carboxylates [Pd(RCO2)2]n with acetone was studied and two new types of palladium polynuclear compounds containing acetonyl and carboxylate groups were isolated. The compounds of the first type are resented by Pd4(μ-CF3CO2)4(μ,k2-CH2C(O)CH3)2(η3-CH2C(OH)CH2)2·2CH3C(O)CH3. This complex has been characterized by the X-ray diffraction analysis. The compound has been shown to contain bridging enolate-anions and η3-coordinated 2-hydroxoallyl ligands. Both ligands represent the result of acetone transformations. The compound is the first transition metal complex simultaneously containing coordinated acetonyl and η3-coordinated 2-hydroxoallyl. The compounds of the second type represent polymeric complexes of the common formula [Pd2(μ-RCO2)2(μ,k2-CH2C(O)CH3)2]n (R = CF3, CCl3) containing only bridging enolate-anions. The obtained result shows that, in the presence of strong carboxylic acids, acetone acts as a high-reactive moiety towards palladium carboxylates.
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Efimenko I. A. et al. Transformations of acetone in reactions with carboxylate complexes of palladium: Crystal structure of Pd4(μ-CF3CO 2)4(μ,k2-CH2C(O)CH 3)2(η3-CH2C(OH)CH 2)2•2CH3C(O)CH3 // Inorganic Chemistry Communication. 2011. Vol. 14. No. 2. pp. 426-428.
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Efimenko I. A., Podobedov R. E., Shishilov O., Rezinkova Y. N., Churakov A. V., Kuz'mina L. G., Garbuzova I. A., Lokshin B. Transformations of acetone in reactions with carboxylate complexes of palladium: Crystal structure of Pd4(μ-CF3CO 2)4(μ,k2-CH2C(O)CH 3)2(η3-CH2C(OH)CH 2)2•2CH3C(O)CH3 // Inorganic Chemistry Communication. 2011. Vol. 14. No. 2. pp. 426-428.
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TY - JOUR
DO - 10.1016/j.inoche.2010.12.018
UR - https://linkinghub.elsevier.com/retrieve/pii/S1387700310005472
TI - Transformations of acetone in reactions with carboxylate complexes of palladium: Crystal structure of Pd4(μ-CF3CO 2)4(μ,k2-CH2C(O)CH 3)2(η3-CH2C(OH)CH 2)2•2CH3C(O)CH3
T2 - Inorganic Chemistry Communication
AU - Efimenko, Inessa A
AU - Podobedov, Roman E
AU - Shishilov, O.N.
AU - Rezinkova, Yaroslavna N
AU - Churakov, Andrei V.
AU - Kuz'mina, Lyudmila G.
AU - Garbuzova, Irina A
AU - Lokshin, Boris
PY - 2011
DA - 2011/02/01
PB - Elsevier
SP - 426-428
IS - 2
VL - 14
SN - 1387-7003
SN - 1879-0259
ER -
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BibTex (up to 50 authors)
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@article{2011_Efimenko,
author = {Inessa A Efimenko and Roman E Podobedov and O.N. Shishilov and Yaroslavna N Rezinkova and Andrei V. Churakov and Lyudmila G. Kuz'mina and Irina A Garbuzova and Boris Lokshin},
title = {Transformations of acetone in reactions with carboxylate complexes of palladium: Crystal structure of Pd4(μ-CF3CO 2)4(μ,k2-CH2C(O)CH 3)2(η3-CH2C(OH)CH 2)2•2CH3C(O)CH3},
journal = {Inorganic Chemistry Communication},
year = {2011},
volume = {14},
publisher = {Elsevier},
month = {feb},
url = {https://linkinghub.elsevier.com/retrieve/pii/S1387700310005472},
number = {2},
pages = {426--428},
doi = {10.1016/j.inoche.2010.12.018}
}
Cite this
MLA
Copy
Efimenko, Inessa A., et al. “Transformations of acetone in reactions with carboxylate complexes of palladium: Crystal structure of Pd4(μ-CF3CO 2)4(μ,k2-CH2C(O)CH 3)2(η3-CH2C(OH)CH 2)2•2CH3C(O)CH3.” Inorganic Chemistry Communication, vol. 14, no. 2, Feb. 2011, pp. 426-428. https://linkinghub.elsevier.com/retrieve/pii/S1387700310005472.