Inorganic Chemistry Communication, volume 111, pages 107611
Effect of meso-phenyl substitution on spectral properties, photo- and thermal stability of boron (III) and zinc (II) dipyrrometenates
Publication type: Journal Article
Publication date: 2020-01-01
Journal:
Inorganic Chemistry Communication
Quartile SCImago
Q2
Quartile WOS
Q1
Impact factor: 3.8
ISSN: 13877003
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The results of investigation of the spectral characteristics, photostability and thermal degradation of B(III) and Zn(II) complexes with 3,3′,5,5′-tetramethyl-2,2′-dipyrromethene and meso-phenyl-3,3',5,5′-tetramethyl-2,2′-dipyrromethene were presented. It has been shown that meso-phenyl substitution in the 3,3′, 5,5′-tetramethyl-2,2′-dipyrromethene complexes with B(III) and Zn(II) leads to a hypsochromic displacement S0 → S1 bands in the EAS and a significant increase in its intensity, but a decrease in the fluorescence quantum yield. It has been established that the introduction of phenyl substituent in the meso-position causes an increase in thermal stability (up to 20 °C in Bodipy and up to 74 °C in Zn-complexes) and photostability (up to 3 times for Bodipy and up to 7 times for Zn(II) dipyrromethenates).
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Berezin M. B. et al. Effect of meso-phenyl substitution on spectral properties, photo- and thermal stability of boron (III) and zinc (II) dipyrrometenates // Inorganic Chemistry Communication. 2020. Vol. 111. p. 107611.
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Berezin M. B., Antina E. V., Guseva G. B., Kritskaya A. Yu., Semeikin A. S., Antina E. V., Guseva G. B. Effect of meso-phenyl substitution on spectral properties, photo- and thermal stability of boron (III) and zinc (II) dipyrrometenates // Inorganic Chemistry Communication. 2020. Vol. 111. p. 107611.
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TY - JOUR
DO - 10.1016/j.inoche.2019.107611
UR - https://doi.org/10.1016%2Fj.inoche.2019.107611
TI - Effect of meso-phenyl substitution on spectral properties, photo- and thermal stability of boron (III) and zinc (II) dipyrrometenates
T2 - Inorganic Chemistry Communication
AU - Berezin, M B
AU - Antina, E V
AU - Guseva, G B
AU - Kritskaya, A Yu
AU - Semeikin, A S
AU - Antina, Elena V
AU - Guseva, Galina B
PY - 2020
DA - 2020/01/01 00:00:00
PB - Elsevier
SP - 107611
VL - 111
SN - 1387-7003
ER -
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@article{2020_Berezin
author = {M B Berezin and E V Antina and G B Guseva and A Yu Kritskaya and A S Semeikin and Elena V Antina and Galina B Guseva},
title = {Effect of meso-phenyl substitution on spectral properties, photo- and thermal stability of boron (III) and zinc (II) dipyrrometenates},
journal = {Inorganic Chemistry Communication},
year = {2020},
volume = {111},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016%2Fj.inoche.2019.107611},
pages = {107611},
doi = {10.1016/j.inoche.2019.107611}
}