Inorganic Chemistry Communication, volume 111, pages 107611

Effect of meso-phenyl substitution on spectral properties, photo- and thermal stability of boron (III) and zinc (II) dipyrrometenates

Publication typeJournal Article
Publication date2020-01-01
Quartile SCImago
Q2
Quartile WOS
Q1
Impact factor3.8
ISSN13877003
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The results of investigation of the spectral characteristics, photostability and thermal degradation of B(III) and Zn(II) complexes with 3,3′,5,5′-tetramethyl-2,2′-dipyrromethene and meso-phenyl-3,3',5,5′-tetramethyl-2,2′-dipyrromethene were presented. It has been shown that meso-phenyl substitution in the 3,3′, 5,5′-tetramethyl-2,2′-dipyrromethene complexes with B(III) and Zn(II) leads to a hypsochromic displacement S0 → S1 bands in the EAS and a significant increase in its intensity, but a decrease in the fluorescence quantum yield. It has been established that the introduction of phenyl substituent in the meso-position causes an increase in thermal stability (up to 20 °C in Bodipy and up to 74 °C in Zn-complexes) and photostability (up to 3 times for Bodipy and up to 7 times for Zn(II) dipyrromethenates).

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Berezin M. B. et al. Effect of meso-phenyl substitution on spectral properties, photo- and thermal stability of boron (III) and zinc (II) dipyrrometenates // Inorganic Chemistry Communication. 2020. Vol. 111. p. 107611.
GOST all authors (up to 50) Copy
Berezin M. B., Antina E. V., Guseva G. B., Kritskaya A. Yu., Semeikin A. S., Antina E. V., Guseva G. B. Effect of meso-phenyl substitution on spectral properties, photo- and thermal stability of boron (III) and zinc (II) dipyrrometenates // Inorganic Chemistry Communication. 2020. Vol. 111. p. 107611.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.inoche.2019.107611
UR - https://doi.org/10.1016%2Fj.inoche.2019.107611
TI - Effect of meso-phenyl substitution on spectral properties, photo- and thermal stability of boron (III) and zinc (II) dipyrrometenates
T2 - Inorganic Chemistry Communication
AU - Berezin, M B
AU - Antina, E V
AU - Guseva, G B
AU - Kritskaya, A Yu
AU - Semeikin, A S
AU - Antina, Elena V
AU - Guseva, Galina B
PY - 2020
DA - 2020/01/01 00:00:00
PB - Elsevier
SP - 107611
VL - 111
SN - 1387-7003
ER -
BibTex
Cite this
BibTex Copy
@article{2020_Berezin
author = {M B Berezin and E V Antina and G B Guseva and A Yu Kritskaya and A S Semeikin and Elena V Antina and Galina B Guseva},
title = {Effect of meso-phenyl substitution on spectral properties, photo- and thermal stability of boron (III) and zinc (II) dipyrrometenates},
journal = {Inorganic Chemistry Communication},
year = {2020},
volume = {111},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016%2Fj.inoche.2019.107611},
pages = {107611},
doi = {10.1016/j.inoche.2019.107611}
}
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