Journal of Alloys and Compounds, volume 859, pages 157765

Microstructure evolution during AlSi10Mg molten alloy/BN microflake interactions in metal matrix composites obtained through 3D printing

Konopatsky Anton ¹

Kvashnin Dmitry ¹

Corthay Shakti ¹

Boyarintsev Ivan ²

Firestein Konstantin L ³

Orekhov Anton ^{4, 5}

Arkharova Natalya ⁶

Golberg Dmitry V ^{3, 7}

Shtansky Dmitry V. ¹

Hide authors affiliations Show authors affiliations: 7 affiliations

National University of Science and Technology MISIS, Leninsky Prospect 4, Moscow 119049, Russia |

“ABuniversal” LLC, Kashirsky Proezd 13, Moscow, Russian Federation |

Centre for Materials Science and School of Chemistry and Physics, Science and Engineering Faculty, Queensland University of Technology (QUT), 2nd George St., Brisbane, QLD, 4000, Australia |

⁴

Moscow Institute of Physics and Technology, Institutsky Lane 9, Dolgoprudny, Moscow Region, 141700, Russian Federation |

⁵

National Research Center “Kurchatov Institute”, 1 Pl. Akademika Kurchatova, Moscow, 123182, Russian Federation |

⁶

A.V. Shubnikov Institute of Crystallography FSRC “Crystallography and Photonics” RAS, Moscow, 119333, Russian Federation

FSRC "Crystallography and photonics" of NRC «Kurchatov Institute»

Shubnikov Institute of Crystallography

⁷

International Centre for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), Namiki 1-1, Tsukuba, Ibaraki, 3050044, Japan |

Publication type: Journal Article

Publication date: 2021-04-01

Elsevier

Journal: Journal of Alloys and Compounds

Quartile SCImago

Quartile WOS

Impact factor: 6.2

ISSN: 09258388

DOI: 10.1016/j.jallcom.2020.157765

Copy DOI

Materials Chemistry

Metals and Alloys

Mechanical Engineering

Mechanics of Materials

Abstract

Utilization of metal/ceramic powders opens new possibilities for 3D printing of metal matrix composites of complex shape with high strength, but it is still a great challenge. In this work, an AlSi10Mg matrix composite embedded with 1 wt% of hexagonal BN phase microflakes ( h -BN) was obtained by means of 3D printing. Then the present study elucidated microstructure evolutions occurring at the h -BN/melt interface during selective laser melting (SLM) of an h -BN-AlSi10Mg powder mixture. During short-term (0.15 ms) high-temperature (∼2900 K) processing the BN inclusions partly dissolved in the Al–Si melt. This process was accompanied by the formation of an AlN phase at the BN surfaces. The AlN crystallites, 100–200 nm in size, had spherical/semispherical shape and formed a continuous layer along the BN/metal grain boundaries. The peculiar growth of AlN grains along the metal/BN interfaces was governed by the specific features of localized N diffusion in the vicinity of interfaces. By contrast, B atoms, released from the dissolved BN phase, were randomly distributed over the melt. AlB 2 nanocrystallites (∼10 nm in size) precipitated from the supersaturated Al–Si melt during cooling stage. With the addition of h -BN microflakes, the composite hardness and tensile strength increased by 32% and 28%, respectivelly. The observed experimental results were supported by ab initio molecular dynamics simulations. Our study demonstrates the possibility and wide prospects of obtaining a dense BN/AlSi10Mg material reinforced with h -BN, AlN, and AlB 2 phases via SLM 3D printing and sheds a new light on fine morphological and microstructural features of thus obtained new composites. • During the BN/Al(Al–Si) melt interactions AlN crystallites are formed along the BN/Al(Al–Si) grain boundaries. • AlB 2 nanocrystallites precipitated from the supersaturated Al–Si melt on cooling. • N atoms are less mobile as compared to B atoms due to the vibration amplitude differences.

By date By citations

Citations by journals

	1 2 3
Journal of Alloys and Compounds	Journal of Alloys and Compounds, 3, 11.54% Journal of Alloys and Compounds 3 publications, 11.54%
Nanomaterials	Nanomaterials, 2, 7.69% Nanomaterials 2 publications, 7.69%
Materials	Materials, 2, 7.69% Materials 2 publications, 7.69%
Surface and Coatings Technology	Surface and Coatings Technology, 2, 7.69% Surface and Coatings Technology 2 publications, 7.69%
Coatings	Coatings, 1, 3.85% Coatings 1 publication, 3.85%
Nano Research	Nano Research, 1, 3.85% Nano Research 1 publication, 3.85%
Metals	Metals, 1, 3.85% Metals 1 publication, 3.85%
Silicon	Silicon, 1, 3.85% Silicon 1 publication, 3.85%
Ceramics International	Ceramics International, 1, 3.85% Ceramics International 1 publication, 3.85%
Materials Today: Proceedings	Materials Today: Proceedings, 1, 3.85% Materials Today: Proceedings 1 publication, 3.85%
Materials and Design	Materials and Design, 1, 3.85% Materials and Design 1 publication, 3.85%
Materials Characterization	Materials Characterization, 1, 3.85% Materials Characterization 1 publication, 3.85%
Journal of Materials Research and Technology	Journal of Materials Research and Technology, 1, 3.85% Journal of Materials Research and Technology 1 publication, 3.85%
Materials Science & Engineering A: Structural Materials: Properties, Microstructure and Processing	Materials Science & Engineering A: Structural Materials: Properties, Microstructure and Processing, 1, 3.85% Materials Science & Engineering A: Structural Materials: Properties, Microstructure and Processing 1 publication, 3.85%
Materials Research Bulletin	Materials Research Bulletin, 1, 3.85% Materials Research Bulletin 1 publication, 3.85%
Materials Chemistry and Physics	Materials Chemistry and Physics, 1, 3.85% Materials Chemistry and Physics 1 publication, 3.85%
Journal of Manufacturing Processes	Journal of Manufacturing Processes, 1, 3.85% Journal of Manufacturing Processes 1 publication, 3.85%
Virtual and Physical Prototyping	Virtual and Physical Prototyping, 1, 3.85% Virtual and Physical Prototyping 1 publication, 3.85%
Journal of Materials Processing Technology	Journal of Materials Processing Technology, 1, 3.85% Journal of Materials Processing Technology 1 publication, 3.85%
Journal of Materials Science	Journal of Materials Science, 1, 3.85% Journal of Materials Science 1 publication, 3.85%
Scientific Reports	Scientific Reports, 1, 3.85% Scientific Reports 1 publication, 3.85%
	1 2 3

Citations by publishers

	2 4 6 8 10 12 14 16
Elsevier	Elsevier, 15, 57.69% Elsevier 15 publications, 57.69%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 6, 23.08% Multidisciplinary Digital Publishing Institute (MDPI) 6 publications, 23.08%
Springer Nature	Springer Nature, 4, 15.38% Springer Nature 4 publications, 15.38%
Taylor & Francis	Taylor & Francis, 1, 3.85% Taylor & Francis 1 publication, 3.85%
	2 4 6 8 10 12 14 16

We do not take into account publications that without a DOI.
Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
Statistics recalculated weekly.

{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2021,2022,2023,2024],"ids":[0,0,0,0],"codes":[0,0,0,0],"imageUrls":["","","",""],"datasets":[{"label":"Citations number","data":[4,10,10,2],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["15.38","38.46","38.46","7.69"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Journal of Alloys and Compounds","Nanomaterials","Materials","Surface and Coatings Technology","Coatings","Nano Research","Metals","Silicon","Ceramics International","Materials Today: Proceedings","Materials and Design","Materials Characterization","Journal of Materials Research and Technology","Materials Science & Engineering A: Structural Materials: Properties, Microstructure and Processing","Materials Research Bulletin","Materials Chemistry and Physics","Journal of Manufacturing Processes","Virtual and Physical Prototyping","Journal of Materials Processing Technology","Journal of Materials Science","Scientific Reports"],"ids":[4015,10051,25198,12521,24427,12211,5369,7149,15103,24147,8941,11469,18488,24183,9849,12041,20107,10483,1150,11453,13767],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/5YZtvLvkPZuc2JHOaZsjCvGSHFCuC3drUwN3YAc5_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp"],"datasets":[{"label":"","data":[3,2,2,2,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[11.54,7.69,7.69,7.69,3.85,3.85,3.85,3.85,3.85,3.85,3.85,3.85,3.85,3.85,3.85,3.85,3.85,3.85,3.85,3.85,3.85],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Elsevier","Multidisciplinary Digital Publishing Institute (MDPI)","Springer Nature","Taylor & Francis"],"ids":[17,202,8,18],"codes":[0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/5YZtvLvkPZuc2JHOaZsjCvGSHFCuC3drUwN3YAc5_medium.webp"],"datasets":[{"label":"","data":[15,6,4,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[57.69,23.08,15.38,3.85],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}

Metrics

Cite this

GOST |

Cite this

GOST Copy

Konopatsky A. et al. Microstructure evolution during AlSi10Mg molten alloy/BN microflake interactions in metal matrix composites obtained through 3D printing // Journal of Alloys and Compounds. 2021. Vol. 859. p. 157765.

GOST all authors (up to 50) Copy

Konopatsky A., Kvashnin D., Corthay S., Boyarintsev I., Firestein K. L., Orekhov A., Arkharova N., Golberg D. V., Shtansky D. V. Microstructure evolution during AlSi10Mg molten alloy/BN microflake interactions in metal matrix composites obtained through 3D printing // Journal of Alloys and Compounds. 2021. Vol. 859. p. 157765.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1016/j.jallcom.2020.157765

UR - https://doi.org/10.1016%2Fj.jallcom.2020.157765

TI - Microstructure evolution during AlSi10Mg molten alloy/BN microflake interactions in metal matrix composites obtained through 3D printing

T2 - Journal of Alloys and Compounds

AU - Konopatsky, Anton

AU - Kvashnin, Dmitry

AU - Corthay, Shakti

AU - Boyarintsev, Ivan

AU - Firestein, Konstantin L

AU - Orekhov, Anton

AU - Arkharova, Natalya

AU - Golberg, Dmitry V

AU - Shtansky, Dmitry V.

PY - 2021

DA - 2021/04/01 00:00:00

PB - Elsevier

SP - 157765

VL - 859

SN - 0925-8388

ER -

BibTex

Cite this

BibTex Copy

@article{2021_Konopatsky,

author = {Anton Konopatsky and Dmitry Kvashnin and Shakti Corthay and Ivan Boyarintsev and Konstantin L Firestein and Anton Orekhov and Natalya Arkharova and Dmitry V Golberg and Dmitry V. Shtansky},

title = {Microstructure evolution during AlSi10Mg molten alloy/BN microflake interactions in metal matrix composites obtained through 3D printing},

journal = {Journal of Alloys and Compounds},

year = {2021},

volume = {859},

publisher = {Elsevier},

month = {apr},

url = {https://doi.org/10.1016%2Fj.jallcom.2020.157765},

pages = {157765},

doi = {10.1016/j.jallcom.2020.157765}

}

Found error?

Publisher

Elsevier

Journal

Journal of Alloys and Compounds

Quartile SCImago

Quartile WOS

Impact factor

6.2

ISSN

09258388 (Print)

Labs

Center for Computer Modeling of Inorganic and Composite Nanoscale Materials

Profiles