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volume 53 pages 101718

Cyclic carbonates synthesis from epoxides and CO2 over NIIC-10 metal-organic frameworks

Publication typeJournal Article
Publication date2021-11-01
scimago Q1
wos Q1
SJR1.618
CiteScore15.2
Impact factor8.4
ISSN22129820, 22129839
Process Chemistry and Technology
Waste Management and Disposal
Chemical Engineering (miscellaneous)
Abstract
• Zn-based MOFs in the presence tetrabutylammonium bromide (TBAB) selectively catalyse conversion of CO 2 to cyclic carbonates. • Good to quantitative yields are obtained on aromatic, aliphatic epoxides, including fluorinated, di-substituted epoxides and bicyclic. • The MOF catalyst has been reused in five cycles. A series of microporous metal-organic frameworks, NIIC-10, based on 2,5-thiophendicarboxylate (tdc 2– ), 1,4-diazabicyclo[2.2.2]octane (dabco), polyol ligands and Zn-ions were investigated in carboxylation of mono-, di and tri-substituted epoxides in the presence of tetrabuthylammonium bromide (TBAB). Reactions were carried out in solventless media under CO 2 atmosphere and 80°C. All resulting mono- and disubstituted cyclic carbonates were obtained in good to excellent yields. Furthermore, the catalyst also showed good selectivity and recyclability for five cycles without a significant loss of activity.
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Bondarenko G. N. et al. Cyclic carbonates synthesis from epoxides and CO2 over NIIC-10 metal-organic frameworks // Journal of CO2 Utilization. 2021. Vol. 53. p. 101718.
GOST all authors (up to 50) Copy
Bondarenko G. N., Fedin V. P., Ganina O. G., Lysova A. A., Beletskaya I. P. Cyclic carbonates synthesis from epoxides and CO2 over NIIC-10 metal-organic frameworks // Journal of CO2 Utilization. 2021. Vol. 53. p. 101718.
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RIS Copy
TY - JOUR
DO - 10.1016/j.jcou.2021.101718
UR - https://doi.org/10.1016/j.jcou.2021.101718
TI - Cyclic carbonates synthesis from epoxides and CO2 over NIIC-10 metal-organic frameworks
T2 - Journal of CO2 Utilization
AU - Bondarenko, Grigoriy N
AU - Fedin, Vladimir P.
AU - Ganina, Olga G
AU - Lysova, A. A.
AU - Beletskaya, Irina P.
PY - 2021
DA - 2021/11/01
PB - Elsevier
SP - 101718
VL - 53
SN - 2212-9820
SN - 2212-9839
ER -
BibTex
Cite this
BibTex (up to 50 authors) Copy
@article{2021_Bondarenko,
author = {Grigoriy N Bondarenko and Vladimir P. Fedin and Olga G Ganina and A. A. Lysova and Irina P. Beletskaya},
title = {Cyclic carbonates synthesis from epoxides and CO2 over NIIC-10 metal-organic frameworks},
journal = {Journal of CO2 Utilization},
year = {2021},
volume = {53},
publisher = {Elsevier},
month = {nov},
url = {https://doi.org/10.1016/j.jcou.2021.101718},
pages = {101718},
doi = {10.1016/j.jcou.2021.101718}
}