High-temperature oxidation of europium (II) sulfide
Maxim S. Molokeev
2, 3
,
A. A. Krylov
4
,
V. V. Atuchin
7, 8
,
Pavel E Plyusnin
10
,
Elena I Salnikova
9
,
Oleg Andreev
9
1
3
Krasnoyarsk 660041 Russia
|
Publication type: Journal Article
Publication date: 2019-11-01
scimago Q1
wos Q1
SJR: 1.121
CiteScore: 11.6
Impact factor: 6.0
ISSN: 1226086X, 1876794X
General Chemical Engineering
Abstract
The process of high-temperature oxidation of EuS in the air was explored in the temperature range of 500–1000 °C. The oxidation reaction enthalpy was determined (ΔH0exp = −1718.5 kJ/mol). The study of oxidation products allowed to establish the mechanism of EuS oxidation with oxygen. At 500–600 °C, EuS is oxidized to a mixture of Eu3+-containing compounds (Eu3S4, Eu2O2S). In the range of 700–1000 °C, only europium oxysulfate Eu2O2SO4 is formed. The structure refinement for Eu2O2SO4 was performed by the Rietveld method. The luminescence intensity of europium oxysulfate Eu2O2SO4 with characteristic 4f-4f transitions from the 5D0 state was investigated as a function of oxidation temperature.
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Total citations:
18
Citations from 2024:
1
(5%)
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GOST
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Denisenko Y. G. et al. High-temperature oxidation of europium (II) sulfide // Journal of Industrial and Engineering Chemistry. 2019. Vol. 79. pp. 62-70.
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Denisenko Y. G., Molokeev M. S., Krylov A. A., Aleksandrovsky A., Oreshonkov A. S., Atuchin V. V., Azarapin N. O., Plyusnin P. E., Salnikova E. I., Andreev O. High-temperature oxidation of europium (II) sulfide // Journal of Industrial and Engineering Chemistry. 2019. Vol. 79. pp. 62-70.
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RIS
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TY - JOUR
DO - 10.1016/j.jiec.2019.05.006
UR - https://linkinghub.elsevier.com/retrieve/pii/S1226086X19302278
TI - High-temperature oxidation of europium (II) sulfide
T2 - Journal of Industrial and Engineering Chemistry
AU - Denisenko, Yuriy G
AU - Molokeev, Maxim S.
AU - Krylov, A. A.
AU - Aleksandrovsky, Aleksandr
AU - Oreshonkov, Aleksandr S.
AU - Atuchin, V. V.
AU - Azarapin, Nikita O
AU - Plyusnin, Pavel E
AU - Salnikova, Elena I
AU - Andreev, Oleg
PY - 2019
DA - 2019/11/01
PB - Korean Society of Industrial Engineering Chemistry
SP - 62-70
VL - 79
SN - 1226-086X
SN - 1876-794X
ER -
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BibTex (up to 50 authors)
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@article{2019_Denisenko,
author = {Yuriy G Denisenko and Maxim S. Molokeev and A. A. Krylov and Aleksandr Aleksandrovsky and Aleksandr S. Oreshonkov and V. V. Atuchin and Nikita O Azarapin and Pavel E Plyusnin and Elena I Salnikova and Oleg Andreev},
title = {High-temperature oxidation of europium (II) sulfide},
journal = {Journal of Industrial and Engineering Chemistry},
year = {2019},
volume = {79},
publisher = {Korean Society of Industrial Engineering Chemistry},
month = {nov},
url = {https://linkinghub.elsevier.com/retrieve/pii/S1226086X19302278},
pages = {62--70},
doi = {10.1016/j.jiec.2019.05.006}
}