Journal of Luminescence, том 192, номера страниц: 1203-1210

Zinc(II) bis(dipyrromethenate)s-based «Оn–Off» fluorescent sensors for xylenes

Тип документаJournal Article
Дата публикации2017-12-22
Название журналаJournal of Luminescence
Квартиль по SCImagoQ2
Квартиль по Web of ScienceQ2
Импакт-фактор 20214.17
General Chemistry
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Краткое описание
This paper presents the results of spectral-luminescence research of binuclear zinc(II) helicates with deca-, octa-, and tetramethylsubstituted 3,3′-bis(dipyrromethene)s ([Zn 2 L 2 ]) in binary mixtures of cyclohexane with m -, o - and p -xylene. Structure effects of [Zn 2 L 2 ], and aromaticity criteria of analytes (HOMA, NICS, μ ) on the fluorescence quenching efficiency of [Zn 2 L 2 ] in the presence of xylenes was considered. It was found that decamethyl substituted 3,3′-bis(dipyrromethenate)s compared to octa-, and tetramethylsubstituted-analogs shows the highest fluorescence sensitivity to the presence of aromatic compounds. Quantum-chemical modeling showed that [Zn 2 L 2 ] fluorescence quenching in the xylenes presence is caused by the formation of [Zn 2 L 2 A n ] (n = 1 or 2) supramolecular structures. High specificity of spectral-luminescent characteristics changing in the presence of xylenes provides the possibility of using [Zn 2 L 2 ] helicates as new fluorescent sensors for trace amounts (6.5–99 ppm) detection of methylbenzenes in organic media.
Пристатейные ссылки: 33
Цитируется в публикациях: 8


1. Ksenofontov A. A. и др. Zinc(II) bis(dipyrromethenate)s-based «Оn–Off» fluorescent sensors for xylenes // Journal of Luminescence. 2017. Т. 192. С. 1203–1210.


DO - 10.1016/j.jlumin.2017.08.058

UR -

TI - Zinc(II) bis(dipyrromethenate)s-based «Оn–Off» fluorescent sensors for xylenes

T2 - Journal of Luminescence

AU - Ksenofontov, A.A.

AU - Guseva, G.B.

AU - Antina, E.V.

AU - Nuraneeva, E.N.

PY - 2017

DA - 2017/12

PB - Elsevier BV

SP - 1203-1210

VL - 192

SN - 0022-2313

ER -

BibTex |


doi = {10.1016/j.jlumin.2017.08.058},

url = {},

year = 2017,

month = {dec},

publisher = {Elsevier {BV}},

volume = {192},

pages = {1203--1210},

author = {A.A. Ksenofontov and G.B. Guseva and E.V. Antina and E.N. Nuraneeva},

title = {Zinc({II}) bis(dipyrromethenate)s-based {\guillemotleft}{\cyrchar\{CYRO}}n{\textendash}Off{\guillemotright} fluorescent sensors for xylenes},

journal = {Journal of Luminescence}


Ksenofontov, A. A., et al. “Zinc(II) Bis(Dipyrromethenate)s-Based «Оn–Off» Fluorescent Sensors for Xylenes.” Journal of Luminescence, vol. 192, Dec. 2017, pp. 1203–10. Crossref,