Journal of Luminescence, volume 201, pages 500-508

Terbium-europium fluorides surface modified with benzoate and terephthalate anions for temperature sensing: Does sensitivity depend on the ligand?

Tcelykh L 2
Kovalenko Aleksandr D. 1
Lepnev L 5
Publication typeJournal Article
Publication date2018-09-01
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor3.6
ISSN00222313
General Chemistry
Biochemistry
Biophysics
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Abstract
Abstract Synthesis, morphology investigation and the study of luminescent properties temperature dependence of surface modified bimetallic europium-terbium fluorides (L@TbxEu1-xF3, L = benzoate or terephthalate anion), as well as their use in bioimaging is described. It was shown that the synthetic route and the solvent affects the TbxEu1-xF3 nanoparticle morphology. Moreover, the oriented attachment of Tb0.999Eu0.001F3 crystallites was observed for the first time. Luminescence intensity of nanoparticle surface modified with aromatic carboxylate anions significantly increased, depending on the ligand used, while the temperature sensitivity of TbxEu1-xF3 was only slightly affected by the organic ligand. The examination of L@Tb0.999Eu0.001F3 temperature dependence revealed excellent linearity both in low temperature range (77–293 K) and in physiological range (305–330 K) with temperature sensitivity of 0.4% K−1 at 40 °C. According to in cellulo tests, tph@Tb0.999Eu0.001F3 demonstrated uniform distribution in cell cytoplasm and exhibited intense ionic luminescence of both terbium and europium.

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Khudoleeva V. Yu. et al. Terbium-europium fluorides surface modified with benzoate and terephthalate anions for temperature sensing: Does sensitivity depend on the ligand? // Journal of Luminescence. 2018. Vol. 201. pp. 500-508.
GOST all authors (up to 50) Copy
Khudoleeva V. Yu., Tcelykh L., Kovalenko A. D., Kalyakina A. S., Goloveshkin A. S., Lepnev L., Utochnikova V. Terbium-europium fluorides surface modified with benzoate and terephthalate anions for temperature sensing: Does sensitivity depend on the ligand? // Journal of Luminescence. 2018. Vol. 201. pp. 500-508.
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TY - JOUR
DO - 10.1016/j.jlumin.2018.05.002
UR - https://doi.org/10.1016%2Fj.jlumin.2018.05.002
TI - Terbium-europium fluorides surface modified with benzoate and terephthalate anions for temperature sensing: Does sensitivity depend on the ligand?
T2 - Journal of Luminescence
AU - Khudoleeva, Vladislava Yu
AU - Tcelykh, L
AU - Kovalenko, Aleksandr D.
AU - Kalyakina, Alena S
AU - Goloveshkin, Alexander S.
AU - Lepnev, L
AU - Utochnikova, Valentina
PY - 2018
DA - 2018/09/01 00:00:00
PB - Elsevier
SP - 500-508
VL - 201
SN - 0022-2313
ER -
BibTex
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BibTex Copy
@article{2018_Khudoleeva
author = {Vladislava Yu Khudoleeva and L Tcelykh and Aleksandr D. Kovalenko and Alena S Kalyakina and Alexander S. Goloveshkin and L Lepnev and Valentina Utochnikova},
title = {Terbium-europium fluorides surface modified with benzoate and terephthalate anions for temperature sensing: Does sensitivity depend on the ligand?},
journal = {Journal of Luminescence},
year = {2018},
volume = {201},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016%2Fj.jlumin.2018.05.002},
pages = {500--508},
doi = {10.1016/j.jlumin.2018.05.002}
}
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