Doping strategies for increased performance in BiFeO3
V. A. Khomchenko
1
,
Dmitry Kiselev
1
,
M. Kopcewicz
2
,
M. Maglione
3
,
Pavel S. Borisov
4
,
W. Kleemann
4
,
A. LOPES
5
,
Y. G. Pogorelov
5
,
J. J. Araújo
5
,
Rero Marques Rubinger
6
,
N. V. Sobolev
6
,
J. D. Vieira
1
,
2
Institute of Electronic Materials Technology, Wolczynska Street 133, 01-919 Warsaw, Poland
|
5
Publication type: Journal Article
Publication date: 2009-06-01
scimago Q2
wos Q2
SJR: 0.521
CiteScore: 5.1
Impact factor: 3.0
ISSN: 03048853, 18734766
Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Abstract
Investigation of crystal structure, dielectric, magnetic and local ferroelectric properties of the diamagnetically substituted Bi 1− x A x FeO 3− x /2 (A=Ca, Sr, Pb, Ba; x =0.2, 0.3) polycrystalline samples has been carried out. It has been shown that the heterovalent A 2+ substitution result in the formation of oxygen vacancies in the host lattice. The solid solutions have been found to possess a rhombohedrally distorted perovskite structure described by the space group R 3 c . Piezoresponse force microscopy has revealed signs of existence of the ferroelectric polarization in the samples at room temperature. Magnetization measurements have shown that the magnetic state of these compounds is determined by the ionic radius of the substituting elements. A-site substitution with the biggest ionic radius ions has been found to suppress the spiral spin structure of BiFeO 3 giving rise to the appearance of room-temperature weak ferromagnetism.
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Khomchenko V. A. et al. Doping strategies for increased performance in BiFeO3 // Journal of Magnetism and Magnetic Materials. 2009. Vol. 321. No. 11. pp. 1692-1698.
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Khomchenko V. A., Kiselev D., Kopcewicz M., Maglione M., Shvartsman V., Borisov P. S., Kleemann W., LOPES A., Pogorelov Y. G., Araújo J. J., Rubinger R. M., Sobolev N. V., Vieira J. D., Kholkin A. L. Doping strategies for increased performance in BiFeO3 // Journal of Magnetism and Magnetic Materials. 2009. Vol. 321. No. 11. pp. 1692-1698.
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TY - JOUR
DO - 10.1016/j.jmmm.2009.02.008
UR - https://doi.org/10.1016/j.jmmm.2009.02.008
TI - Doping strategies for increased performance in BiFeO3
T2 - Journal of Magnetism and Magnetic Materials
AU - Khomchenko, V. A.
AU - Kiselev, Dmitry
AU - Kopcewicz, M.
AU - Maglione, M.
AU - Shvartsman, Vladimir
AU - Borisov, Pavel S.
AU - Kleemann, W.
AU - LOPES, A.
AU - Pogorelov, Y. G.
AU - Araújo, J. J.
AU - Rubinger, Rero Marques
AU - Sobolev, N. V.
AU - Vieira, J. D.
AU - Kholkin, Andrei L.
PY - 2009
DA - 2009/06/01
PB - Elsevier
SP - 1692-1698
IS - 11
VL - 321
SN - 0304-8853
SN - 1873-4766
ER -
Cite this
BibTex (up to 50 authors)
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@article{2009_Khomchenko,
author = {V. A. Khomchenko and Dmitry Kiselev and M. Kopcewicz and M. Maglione and Vladimir Shvartsman and Pavel S. Borisov and W. Kleemann and A. LOPES and Y. G. Pogorelov and J. J. Araújo and Rero Marques Rubinger and N. V. Sobolev and J. D. Vieira and Andrei L. Kholkin},
title = {Doping strategies for increased performance in BiFeO3},
journal = {Journal of Magnetism and Magnetic Materials},
year = {2009},
volume = {321},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/j.jmmm.2009.02.008},
number = {11},
pages = {1692--1698},
doi = {10.1016/j.jmmm.2009.02.008}
}
Cite this
MLA
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Khomchenko, V. A., et al. “Doping strategies for increased performance in BiFeO3.” Journal of Magnetism and Magnetic Materials, vol. 321, no. 11, Jun. 2009, pp. 1692-1698. https://doi.org/10.1016/j.jmmm.2009.02.008.