Journal of Organometallic Chemistry, volume 943, pages 121841

4-lithiosydnone imines: Generation and stability. Plant growth regulating activity of 4-hydroxymethyl derivatives of sydnone imines

Cherepanov Ilya A. 1
Shevaldina Ekaterina V
Lapshin Dmitry A
Spiridonov Yury Ya 2
Abubikerov Vladimir A 2
Shevaldina Ekaterina V 1
Lapshin Dmitry N 3
Publication typeJournal Article
Publication date2021-06-01
Quartile SCImago
Q3
Quartile WOS
Q2
Impact factor2.3
ISSN0022328X
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract The C(4)-deprotonation of N6-substituted sydnone imines with lithium hexamethyldisilazide (LHDMS), lithium diisopropylamide (LDA), lithium diethylamide (LDEA), and n-BuLi was studied. A thermal stability of 4-lithiosydnone imines was investigated and an efficiency of subsequent reactions of the generated C(4)-lithio derivatives with electrophiles was shown to depend on the exploited deprotonating reagent. It was found that 4-(α-arylhydroxymethyl)sydnone imines, when used for pre-sowing treatment of corn seeds at very low doses (0.25-5 g t−1), promoted a plant growth up to 60%.

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GOST Copy
Cherepanov I. A. et al. 4-lithiosydnone imines: Generation and stability. Plant growth regulating activity of 4-hydroxymethyl derivatives of sydnone imines // Journal of Organometallic Chemistry. 2021. Vol. 943. p. 121841.
GOST all authors (up to 50) Copy
Cherepanov I. A., Shevaldina E. V., Lapshin D. A., Spiridonov Y. Ya., Abubikerov V. A., Moiseev S. K., Shevaldina E. V., Lapshin D. N. 4-lithiosydnone imines: Generation and stability. Plant growth regulating activity of 4-hydroxymethyl derivatives of sydnone imines // Journal of Organometallic Chemistry. 2021. Vol. 943. p. 121841.
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RIS Copy
TY - JOUR
DO - 10.1016/j.jorganchem.2021.121841
UR - https://doi.org/10.1016%2Fj.jorganchem.2021.121841
TI - 4-lithiosydnone imines: Generation and stability. Plant growth regulating activity of 4-hydroxymethyl derivatives of sydnone imines
T2 - Journal of Organometallic Chemistry
AU - Cherepanov, Ilya A.
AU - Shevaldina, Ekaterina V
AU - Lapshin, Dmitry A
AU - Spiridonov, Yury Ya
AU - Abubikerov, Vladimir A
AU - Moiseev, S. K.
AU - Shevaldina, Ekaterina V
AU - Lapshin, Dmitry N
PY - 2021
DA - 2021/06/01 00:00:00
PB - Elsevier
SP - 121841
VL - 943
SN - 0022-328X
ER -
BibTex
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BibTex Copy
@article{2021_Cherepanov,
author = {Ilya A. Cherepanov and Ekaterina V Shevaldina and Dmitry A Lapshin and Yury Ya Spiridonov and Vladimir A Abubikerov and S. K. Moiseev and Ekaterina V Shevaldina and Dmitry N Lapshin},
title = {4-lithiosydnone imines: Generation and stability. Plant growth regulating activity of 4-hydroxymethyl derivatives of sydnone imines},
journal = {Journal of Organometallic Chemistry},
year = {2021},
volume = {943},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016%2Fj.jorganchem.2021.121841},
pages = {121841},
doi = {10.1016/j.jorganchem.2021.121841}
}
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