Joule, volume 3, issue 1, pages 279-289
Efficient Electrocatalytic N2 Fixation with MXene under Ambient Conditions
Publication type: Journal Article
Publication date: 2019-01-01
General Energy
Abstract
Summary The current efficiency of NH3 electrosynthesis from N2 and H2O is ultralow as a result of poor selectivity in most catalysts. Here, we demonstrate that under ambient conditions, MXene (Ti3C2Tx) nanosheets attached to a vertically aligned metal host can achieve a high faradic efficiency (5.78%) at an ultralow potential for NH3 electrosynthesis. On the basis of experimental and theoretical evidence, the basal plane of MXene is relatively inert, and its higher activity is related to a greater number of exposed edge sites. This work elucidates that significantly improved selectivity of NH3 electrosynthesis can be achieved by tuning active sites and retarding hydrogen evolution activity. The proposed strategy provides a new opportunity to optimize the surface properties of 2D catalysts for efficient N2 fixation under ambient conditions.
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7 publications, 1.24%
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Elsevier
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162 publications, 28.67%
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Wiley
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128 publications, 22.65%
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7 publications, 1.24%
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3 publications, 0.53%
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American Institute of Physics (AIP)
1 publication, 0.18%
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Tianjin Daxue/Tianjin University, 1, 0.18%
Tianjin Daxue/Tianjin University
1 publication, 0.18%
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Walter de Gruyter
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Walter de Gruyter
1 publication, 0.18%
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Hindawi Limited
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Hindawi Limited
1 publication, 0.18%
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Proceedings of the National Academy of Sciences (PNAS)
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Proceedings of the National Academy of Sciences (PNAS)
1 publication, 0.18%
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Luo Y. et al. Efficient Electrocatalytic N2 Fixation with MXene under Ambient Conditions // Joule. 2019. Vol. 3. No. 1. pp. 279-289.
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Luo Y., Chen G., Ding L., Chen X., Ding L. X., Wang H. Efficient Electrocatalytic N2 Fixation with MXene under Ambient Conditions // Joule. 2019. Vol. 3. No. 1. pp. 279-289.
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TY - JOUR
DO - 10.1016/j.joule.2018.09.011
UR - https://doi.org/10.1016%2Fj.joule.2018.09.011
TI - Efficient Electrocatalytic N2 Fixation with MXene under Ambient Conditions
T2 - Joule
AU - Luo, Yaru
AU - Chen, Gaofeng
AU - Ding, Li
AU - Chen, Xinzhi
AU - Ding, Liang Xin
AU - Wang, Haihui
PY - 2019
DA - 2019/01/01 00:00:00
PB - Elsevier
SP - 279-289
IS - 1
VL - 3
SN - 2542-4351
ER -
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@article{2019_Luo
author = {Yaru Luo and Gaofeng Chen and Li Ding and Xinzhi Chen and Liang Xin Ding and Haihui Wang},
title = {Efficient Electrocatalytic N2 Fixation with MXene under Ambient Conditions},
journal = {Joule},
year = {2019},
volume = {3},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016%2Fj.joule.2018.09.011},
number = {1},
pages = {279--289},
doi = {10.1016/j.joule.2018.09.011}
}
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MLA
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Luo, Yaru, et al. “Efficient Electrocatalytic N2 Fixation with MXene under Ambient Conditions.” Joule, vol. 3, no. 1, Jan. 2019, pp. 279-289. https://doi.org/10.1016%2Fj.joule.2018.09.011.