Journal of Photochemistry and Photobiology A: Chemistry, volume 382, pages 111899

Novel fluorescent sensors based on zinc(II) bis(dipyrromethenate)s for furosemide detection in organic media

Stupikova Svetlana A 2, 3
Bocharov Pavel S 2, 3
Lukanov Mikhail M 2, 3
Khodov Ilya A. 4, 5
Publication typeJournal Article
Publication date2019-09-01
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor4.3
ISSN10106030, 18732666
General Chemistry
General Chemical Engineering
General Physics and Astronomy
Abstract
In this paper, the sensitivity of new fluorescent sensors based on zinc(II) bis(dipyrromethenate)s ([Zn2L2]s) to the furosemide presence in organic media is described. It has been shown that the instantaneous spectral response of [Zn2L2]s to the furosemide presence is based on the fluorescence quenching effect. Multi-approach analysis (UV–vis and fluorescent titrations, PXRD, FTIR, 1H NMR, DOSY, and DFT calculations) has shown that the [Zn2L2]s fluorescence quenching is associated with the formation of stable [Zn2L2Fur]s supramolecular systems, capable of photoinduced electron transfer. The furosemide detection limit with using [Zn2L2]s was 65–78 μg L−1. The proposed sensors can be used for the forensic, clinical and sports medicine needs.

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Ksenofontov A. A. et al. Novel fluorescent sensors based on zinc(II) bis(dipyrromethenate)s for furosemide detection in organic media // Journal of Photochemistry and Photobiology A: Chemistry. 2019. Vol. 382. p. 111899.
GOST all authors (up to 50) Copy
Ksenofontov A. A., Stupikova S. A., Bocharov P. S., Lukanov M. M., Ksenofontova K. V., Khodov I. A., Antina E. V. Novel fluorescent sensors based on zinc(II) bis(dipyrromethenate)s for furosemide detection in organic media // Journal of Photochemistry and Photobiology A: Chemistry. 2019. Vol. 382. p. 111899.
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RIS Copy
TY - JOUR
DO - 10.1016/j.jphotochem.2019.111899
UR - https://doi.org/10.1016%2Fj.jphotochem.2019.111899
TI - Novel fluorescent sensors based on zinc(II) bis(dipyrromethenate)s for furosemide detection in organic media
T2 - Journal of Photochemistry and Photobiology A: Chemistry
AU - Ksenofontov, Alexander A
AU - Stupikova, Svetlana A
AU - Bocharov, Pavel S
AU - Lukanov, Mikhail M
AU - Ksenofontova, Ksenia V
AU - Khodov, Ilya A.
AU - Antina, Elena V
PY - 2019
DA - 2019/09/01 00:00:00
PB - Elsevier
SP - 111899
VL - 382
SN - 1010-6030
SN - 1873-2666
ER -
BibTex
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BibTex Copy
@article{2019_Ksenofontov,
author = {Alexander A Ksenofontov and Svetlana A Stupikova and Pavel S Bocharov and Mikhail M Lukanov and Ksenia V Ksenofontova and Ilya A. Khodov and Elena V Antina},
title = {Novel fluorescent sensors based on zinc(II) bis(dipyrromethenate)s for furosemide detection in organic media},
journal = {Journal of Photochemistry and Photobiology A: Chemistry},
year = {2019},
volume = {382},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016%2Fj.jphotochem.2019.111899},
pages = {111899},
doi = {10.1016/j.jphotochem.2019.111899}
}
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