Journal of Photochemistry and Photobiology A: Chemistry, volume 391, pages 112333
9-(p-Tolyl)-2,3,4,4a,9,9a-hexahydro-1H-carbazole—A new donor building-block in the design of sensitizers for dye-sensitized solar cells
Mikhailov Maxim S
1
,
Mikhalchenko Ludmila V.
2
,
Rakitin Oleg A
,
Knyazeva Ekaterina A
1, 3
,
Gudim Nikita S
2
,
Zhang Lu
,
Robertson Neil
,
Tanaka Ellie
,
Tanaka Ellie
4
,
Zhang Lu
4
,
Rakitin Oleg A.
1, 3
2
3
Publication type: Journal Article
Publication date: 2020-03-01
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor: 4.3
ISSN: 10106030, 18732666
General Chemistry
General Chemical Engineering
General Physics and Astronomy
Abstract
Abstract The novel donor building-block - 9-(p-tolyl)-2,3,4,4a,9,9a-hexahydro-1H-carbazole was designed and employed in the synthesis of dye-sensitized solar cell (DSSCs). An effective, high-yielding synthesis of 4,6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9-(p-tolyl)-1,2,3,4,4a,9a-hexahydrocarbazole from 1,2,3,4,4a,9a-hexahydrocarbazole was realized. Three new metal-free organic sensitizers, containing the new donor building block were prepared by a stepwise approach from 4,7-dibromobenzo[c][1,2,5]chacogenadiazoles. A 2,1,3-Benzothiadiazole dye containing hexahydrocarbazole donor, thiophene as π-spacer and cyanoacrylate as anchoring electron acceptor showed photovoltaic properties higher than the well-known WS-2 sensitizer with PCE = 5.86 %. Although benzoxa- and –selenadiazole dyes have a bathochromic shift (24−30 nm) in the UV–vis spectra, and smaller energy gap Eg (about 0.1 eV), they have lower photovoltaic parameters, including PCE of 1.5–2.3 %. Introducing a new donor 9-(p-tolyl)-2,3,4,4a,9,9a-hexahydro-1H-carbazole into the construction of the DSSCs has broadened possibilities for the optimization of their photovoltaic properties.
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1
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Mikhailov M. S. et al. 9-(p-Tolyl)-2,3,4,4a,9,9a-hexahydro-1H-carbazole—A new donor building-block in the design of sensitizers for dye-sensitized solar cells // Journal of Photochemistry and Photobiology A: Chemistry. 2020. Vol. 391. p. 112333.
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Mikhailov M. S., Gudim N. S., Knyazeva E. A., Tanaka E., Zhang L., Mikhalchenko L. V., Robertson N., Rakitin O. A., Tanaka E., Zhang L., Robertson N. J., Rakitin O. A. 9-(p-Tolyl)-2,3,4,4a,9,9a-hexahydro-1H-carbazole—A new donor building-block in the design of sensitizers for dye-sensitized solar cells // Journal of Photochemistry and Photobiology A: Chemistry. 2020. Vol. 391. p. 112333.
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TY - JOUR
DO - 10.1016/j.jphotochem.2019.112333
UR - https://doi.org/10.1016%2Fj.jphotochem.2019.112333
TI - 9-(p-Tolyl)-2,3,4,4a,9,9a-hexahydro-1H-carbazole—A new donor building-block in the design of sensitizers for dye-sensitized solar cells
T2 - Journal of Photochemistry and Photobiology A: Chemistry
AU - Mikhailov, Maxim S
AU - Gudim, Nikita S
AU - Knyazeva, Ekaterina A
AU - Tanaka, Ellie
AU - Zhang, Lu
AU - Mikhalchenko, Ludmila V.
AU - Robertson, Neil
AU - Rakitin, Oleg A
AU - Tanaka, Ellie
AU - Zhang, Lu
AU - Robertson, Neil J.
AU - Rakitin, Oleg A.
PY - 2020
DA - 2020/03/01 00:00:00
PB - Elsevier
SP - 112333
VL - 391
SN - 1010-6030
SN - 1873-2666
ER -
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@article{2020_Mikhailov
author = {Maxim S Mikhailov and Nikita S Gudim and Ekaterina A Knyazeva and Ellie Tanaka and Lu Zhang and Ludmila V. Mikhalchenko and Neil Robertson and Oleg A Rakitin and Ellie Tanaka and Lu Zhang and Neil J. Robertson and Oleg A. Rakitin},
title = {9-(p-Tolyl)-2,3,4,4a,9,9a-hexahydro-1H-carbazole—A new donor building-block in the design of sensitizers for dye-sensitized solar cells},
journal = {Journal of Photochemistry and Photobiology A: Chemistry},
year = {2020},
volume = {391},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016%2Fj.jphotochem.2019.112333},
pages = {112333},
doi = {10.1016/j.jphotochem.2019.112333}
}