Journal of Photochemistry and Photobiology A: Chemistry, volume 402, pages 112801

Self-assembly involving hydrogen bonds. Spectral properties and structure of supramolecular complexes of bis-aza-18-crown-6-containing dienones with alkanediammonium salts

Fomina Marina V ¹

Kurchavov Nikolai A ¹

Freidzon Alexandra Ya. ¹

Nuriev Vyacheslav N ^{2, 3}

Vedernikov Artem I. ¹

Strelenko Yuri A. ⁴

Fomina Marina V. ^{2, 3}

Hide authors affiliations Show authors affiliations: 4 affiliations

Photochemistry Center of RAS, FSRC Crystallography and Photonics, Russian Academy of Sciences, Novatorov Str. 7A-1, Moscow, 119421, Russian Federation

Photochemistry Center

FSRC "Crystallography and photonics" of NRC «Kurchatov Institute»

Department of Chemistry, M.V. Lomonosov Moscow State University, Leninskie Gory 1-3, Moscow 119991, Russian Federation |

Photochemistry Center of RAS, FSRC “Crystallography and Photonics”, Russian Academy of Sciences, Novatorov str. 7A-1, Moscow, 119421, Russian Federation

Photochemistry Center

FSRC "Crystallography and photonics" of NRC «Kurchatov Institute»

⁴

N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninskiy prosp. 47, Moscow 119991, Russian Federation |

Publication type: Journal Article

Publication date: 2020-11-01

Elsevier

Journal: Journal of Photochemistry and Photobiology A: Chemistry

Quartile SCImago

Quartile WOS

Impact factor: 4.3

ISSN: 10106030, 18732666

DOI: 10.1016/j.jphotochem.2020.112801

Copy DOI

General Chemistry

General Chemical Engineering

General Physics and Astronomy

Abstract

Abstract Dienones (ketocyanine dyes) containing two aza-18-crown-6 ether residues were synthesized. The complex formation of these dyes with the EtNH3+ and +H3N(CH2)nNH3+ ions (n = 2–10, 12) in MeCN was studied by electronic and 1H NMR spectroscopy, including spectrophotometric and 1H NMR titration. It was found that homoditopic bis-azacrown dienones and alkanediammonium ions with a short polymethylene chain form 1:1, 2:2, and 1:2 complexes, whereas alkanediammonium ions with a long polymethylene chain form only pseudocyclic 1:1 complexes. The stability constants of the resulting complexes were determined (logK1:1 varies in the range from 2.74 to 5.62 [M–1], logK2:2 = 2.1 [M–1], and logK1:2 varies in the range from 2.03 to 2.96 [M–1]). The most stable complexes are formed by diammonium ions with a long polymethylene chain owing to simultaneous binding of both NH3+ groups to the azacrown ether residues of the dye. The structure of supramolecular complexes was confirmed by quantum chemical calculations.

By date By citations

Citations by journals

	1
ACS Omega	ACS Omega, 1, 16.67% ACS Omega 1 publication, 16.67%
Molecules	Molecules, 1, 16.67% Molecules 1 publication, 16.67%
Journal of Photochemistry and Photobiology A: Chemistry	Journal of Photochemistry and Photobiology A: Chemistry, 1, 16.67% Journal of Photochemistry and Photobiology A: Chemistry 1 publication, 16.67%
Mendeleev Communications	Mendeleev Communications, 1, 16.67% Mendeleev Communications 1 publication, 16.67%
International Journal of Molecular Sciences	International Journal of Molecular Sciences, 1, 16.67% International Journal of Molecular Sciences 1 publication, 16.67%
Frontiers in Chemistry	Frontiers in Chemistry, 1, 16.67% Frontiers in Chemistry 1 publication, 16.67%
	1

Citations by publishers

	1 2
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 2, 33.33% Multidisciplinary Digital Publishing Institute (MDPI) 2 publications, 33.33%
Elsevier	Elsevier, 2, 33.33% Elsevier 2 publications, 33.33%
American Chemical Society (ACS)	American Chemical Society (ACS), 1, 16.67% American Chemical Society (ACS) 1 publication, 16.67%
Frontiers Media S.A.	Frontiers Media S.A., 1, 16.67% Frontiers Media S.A. 1 publication, 16.67%
	1 2

We do not take into account publications that without a DOI.
Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
Statistics recalculated weekly.

{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2022,2023],"ids":[0,0],"codes":[0,0],"imageUrls":["",""],"datasets":[{"label":"Citations number","data":[3,3],"backgroundColor":["#3B82F6","#3B82F6"],"percentage":["50","50"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["ACS Omega","Molecules","Journal of Photochemistry and Photobiology A: Chemistry","Mendeleev Communications","International Journal of Molecular Sciences","Frontiers in Chemistry"],"ids":[18901,1770,18164,5294,14627,6407],"codes":[0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/4QWA67eqfcfyOiA8Wk7YnqroHFqQbTsmDJUYTCTg_medium.webp"],"datasets":[{"label":"","data":[1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[16.67,16.67,16.67,16.67,16.67,16.67],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Multidisciplinary Digital Publishing Institute (MDPI)","Elsevier","American Chemical Society (ACS)","Frontiers Media S.A."],"ids":[202,17,40,208],"codes":[0,0,0,0],"imageUrls":["\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/4QWA67eqfcfyOiA8Wk7YnqroHFqQbTsmDJUYTCTg_medium.webp"],"datasets":[{"label":"","data":[2,2,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[33.33,33.33,16.67,16.67],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}

Metrics

Cite this

GOST |

Cite this

GOST Copy

Fomina M. V. et al. Self-assembly involving hydrogen bonds. Spectral properties and structure of supramolecular complexes of bis-aza-18-crown-6-containing dienones with alkanediammonium salts // Journal of Photochemistry and Photobiology A: Chemistry. 2020. Vol. 402. p. 112801.

GOST all authors (up to 50) Copy

Fomina M. V., Kurchavov N. A., Freidzon A. Y., Nuriev V. N., Vedernikov A. I., Strelenko Y. A., Fomina M. V. Self-assembly involving hydrogen bonds. Spectral properties and structure of supramolecular complexes of bis-aza-18-crown-6-containing dienones with alkanediammonium salts // Journal of Photochemistry and Photobiology A: Chemistry. 2020. Vol. 402. p. 112801.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1016/j.jphotochem.2020.112801

UR - https://doi.org/10.1016%2Fj.jphotochem.2020.112801

TI - Self-assembly involving hydrogen bonds. Spectral properties and structure of supramolecular complexes of bis-aza-18-crown-6-containing dienones with alkanediammonium salts

T2 - Journal of Photochemistry and Photobiology A: Chemistry

AU - Fomina, Marina V

AU - Kurchavov, Nikolai A

AU - Freidzon, Alexandra Ya.

AU - Nuriev, Vyacheslav N

AU - Vedernikov, Artem I.

AU - Strelenko, Yuri A.

AU - Fomina, Marina V.

PY - 2020

DA - 2020/11/01 00:00:00

PB - Elsevier

SP - 112801

VL - 402

SN - 1010-6030

SN - 1873-2666

ER -

BibTex

Cite this

BibTex Copy

@article{2020_Fomina,

author = {Marina V Fomina and Nikolai A Kurchavov and Alexandra Ya. Freidzon and Vyacheslav N Nuriev and Artem I. Vedernikov and Yuri A. Strelenko and Marina V. Fomina},

title = {Self-assembly involving hydrogen bonds. Spectral properties and structure of supramolecular complexes of bis-aza-18-crown-6-containing dienones with alkanediammonium salts},

journal = {Journal of Photochemistry and Photobiology A: Chemistry},

year = {2020},

volume = {402},

publisher = {Elsevier},

month = {nov},

url = {https://doi.org/10.1016%2Fj.jphotochem.2020.112801},

pages = {112801},

doi = {10.1016/j.jphotochem.2020.112801}

}

Found error?

Publisher

Elsevier

Journal

Journal of Photochemistry and Photobiology A: Chemistry

Quartile SCImago

Quartile WOS

Impact factor

4.3

ISSN

10106030 (Print)
18732666 (Electronic)

Labs

Laboratory of Synthesis and Supramolecular Chemistry of Photoactive Compounds

Profiles