Journal of Photochemistry and Photobiology A: Chemistry, volume 411, pages 113196

Polarization holographic gratings in PAZO polymer films doped with particles of biometals

Stoilova Ani 1
Mateev G 1
Nazarova Dimana 1
Nedelchev Lian 1
Stoykova E 1
Blagoeva Blaga 1
Berberova N 1
Georgieva Stela 2
Todorov Petar 2
1
 
Institute of Optical Materials and Technology – Bulgarian Academy of Sciences, Sofia, Bulgaria
2
 
University of Chemical Technology and Metallurgy, Department of Physics, 8 Kliment Ohridski, 1756 Sofia, Bulgaria
Publication typeJournal Article
Publication date2021-04-01
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor4.3
ISSN10106030, 18732666
General Chemistry
General Chemical Engineering
General Physics and Astronomy
Abstract
• Azopolymer thin films doped with particles of biometals were prepared. • Polarization holographic gratings are recorded with a He-Cd gas laser with wavelength 442 nm in the composite films. • The influence of the dopants’ composition and concentration on the polarization holographic gratings parameters is discussed. The paper presents a study of the diffraction efficiency of polarization holographic gratings recorded in thin films of the azopolymer PAZO (poly[1-[4-(3-carboxy-4-hydroxyphenylazo) benzenesulfonamido]-1,2-ethanediyl, sodium salt]) doped with Cu(II) 3-amino-5,5′-dimethylhydantoin (CLP) and Ni(II) 3-amino-5,5′-dimethylhydantoin (NLP) at three different concentrations, namely 1, 2 and 5 wt.%. The influence of the dopants composition and concentration on the parameters of the polarization holographic gratings recorded in the thin composite films has been discussed. The gratings are recorded with a He-Cd gas laser with wavelength 442 nm. The polarization of the recording beams was left and right circular and the recording angle was 20°. Along with the anisotropic grating in the volume of the media, surface relief is also formed. The diffraction efficiency kinetics is probed at 635 nm and the height of the relief gratings is determined by AFM. Diffraction efficiency (η) higher than 30 % was achieved for the hybrid samples, as well as 585 nm surface relief height.

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Stoilova A. et al. Polarization holographic gratings in PAZO polymer films doped with particles of biometals // Journal of Photochemistry and Photobiology A: Chemistry. 2021. Vol. 411. p. 113196.
GOST all authors (up to 50) Copy
Stoilova A., Mateev G., Nazarova D., Nedelchev L., Stoykova E., Blagoeva B., Berberova N., Georgieva S., Todorov P. Polarization holographic gratings in PAZO polymer films doped with particles of biometals // Journal of Photochemistry and Photobiology A: Chemistry. 2021. Vol. 411. p. 113196.
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RIS Copy
TY - JOUR
DO - 10.1016/j.jphotochem.2021.113196
UR - https://doi.org/10.1016%2Fj.jphotochem.2021.113196
TI - Polarization holographic gratings in PAZO polymer films doped with particles of biometals
T2 - Journal of Photochemistry and Photobiology A: Chemistry
AU - Stoilova, Ani
AU - Mateev, G
AU - Nazarova, Dimana
AU - Nedelchev, Lian
AU - Stoykova, E
AU - Blagoeva, Blaga
AU - Berberova, N
AU - Georgieva, Stela
AU - Todorov, Petar
PY - 2021
DA - 2021/04/01 00:00:00
PB - Elsevier
SP - 113196
VL - 411
SN - 1010-6030
SN - 1873-2666
ER -
BibTex
Cite this
BibTex Copy
@article{2021_Stoilova,
author = {Ani Stoilova and G Mateev and Dimana Nazarova and Lian Nedelchev and E Stoykova and Blaga Blagoeva and N Berberova and Stela Georgieva and Petar Todorov},
title = {Polarization holographic gratings in PAZO polymer films doped with particles of biometals},
journal = {Journal of Photochemistry and Photobiology A: Chemistry},
year = {2021},
volume = {411},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016%2Fj.jphotochem.2021.113196},
pages = {113196},
doi = {10.1016/j.jphotochem.2021.113196}
}
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