Journal of Power Sources, volume 265, pages 309-316

Spiro-(1,1′)-bipyrrolidinium tetrafluoroborate salt as high voltage electrolyte for electric double layer capacitors

Yu Xuewen ¹

Ruan Dianbo ²

Wu Changcheng ¹

Wang Jing ¹

Shi Zhiqiang ¹

Hide authors affiliations Show authors affiliations: 2 affiliations

Laboratory of Fiber Modification and Functional Fiber, College of Materials Science and Engineering, Tianjin Polytechnic University, Tianjin 300387, PR China |

Ningbo CRS New Energy Technology Co. Ltd, Ningbo 315000, PR China |

Publication type: Journal Article

Publication date: 2014-11-01

Elsevier

Journal: Journal of Power Sources

Quartile SCImago

Quartile WOS

Impact factor: 9.2

ISSN: 03787753

DOI: 10.1016/j.jpowsour.2014.04.144

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Physical and Theoretical Chemistry

Electrical and Electronic Engineering

Energy Engineering and Power Technology

Renewable Energy, Sustainability and the Environment

Abstract

A novel quaternary ammonium salt based on spiro-(1,1′)-bipyrolidinium tetrafluoroborate (SBP-BF4) has been synthesized and dissolved in propylene carbonate (PC) with 1.5 mol L−1 (M) concentration for electric double-layer capacitors (EDLCs). The physic-chemical properties and electrochemical performance of SBP-BF4/PC electrolyte are investigated. Compared with the standard electrolyte 1.5 M TEMA-BF4 in PC, the novel SBP-BF4/PC electrolyte exhibited much better electrochemical performance due to its smaller cation size, lower viscosity and higher conductivity. The specific discharge capacitance of activated carbon electrode based EDLCs using SBP-BF4/PC electrolyte is 120 F g−1, the energy density and power density can reach 31 kW kg−1 and 6938 W kg−1, respectively, when the working voltage is 2.7 V and current density is 50 mA g−1. The withstand voltage of activated carbon based EDLCs with SBP-BF4/PC electrolyte can reach to 3.2 V, where the stable discharge capacitance and energy density are 121 F g−1 and 43 Wh kg−1, respectively.

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Citations by journals

	1 2 3 4 5 6 7 8 9
Electrochimica Acta	Electrochimica Acta, 9, 11.54% Electrochimica Acta 9 publications, 11.54%
Journal of Power Sources	Journal of Power Sources, 7, 8.97% Journal of Power Sources 7 publications, 8.97%
Journal of Energy Storage	Journal of Energy Storage, 4, 5.13% Journal of Energy Storage 4 publications, 5.13%
Carbon	Carbon, 3, 3.85% Carbon 3 publications, 3.85%
ACS Applied Energy Materials	ACS Applied Energy Materials, 2, 2.56% ACS Applied Energy Materials 2 publications, 2.56%
Journal of the Electrochemical Society	Journal of the Electrochemical Society, 2, 2.56% Journal of the Electrochemical Society 2 publications, 2.56%
Journal of Energy Chemistry	Journal of Energy Chemistry, 2, 2.56% Journal of Energy Chemistry 2 publications, 2.56%
Springer Series in Materials Science	Springer Series in Materials Science, 2, 2.56% Springer Series in Materials Science 2 publications, 2.56%
Chemistry of Heterocyclic Compounds	Chemistry of Heterocyclic Compounds, 1, 1.28% Chemistry of Heterocyclic Compounds 1 publication, 1.28%
Chemistry Letters	Chemistry Letters, 1, 1.28% Chemistry Letters 1 publication, 1.28%
Electrochemistry	Electrochemistry, 1, 1.28% Electrochemistry 1 publication, 1.28%
Materials Research Letters	Materials Research Letters, 1, 1.28% Materials Research Letters 1 publication, 1.28%
Minerals	Minerals, 1, 1.28% Minerals 1 publication, 1.28%
Nanomaterials	Nanomaterials, 1, 1.28% Nanomaterials 1 publication, 1.28%
Science China Chemistry	Science China Chemistry, 1, 1.28% Science China Chemistry 1 publication, 1.28%
Journal of Materials Science: Materials in Electronics	Journal of Materials Science: Materials in Electronics, 1, 1.28% Journal of Materials Science: Materials in Electronics 1 publication, 1.28%
Science China Materials	Science China Materials, 1, 1.28% Science China Materials 1 publication, 1.28%
Journal of Materials Research	Journal of Materials Research, 1, 1.28% Journal of Materials Research 1 publication, 1.28%
Journal of Molecular Structure	Journal of Molecular Structure, 1, 1.28% Journal of Molecular Structure 1 publication, 1.28%
Chinese Physics B	Chinese Physics B, 1, 1.28% Chinese Physics B 1 publication, 1.28%
Nanotechnology	Nanotechnology, 1, 1.28% Nanotechnology 1 publication, 1.28%
Biomass and Bioenergy	Biomass and Bioenergy, 1, 1.28% Biomass and Bioenergy 1 publication, 1.28%
Chinese Chemical Letters	Chinese Chemical Letters, 1, 1.28% Chinese Chemical Letters 1 publication, 1.28%
Energy Storage Materials	Energy Storage Materials, 1, 1.28% Energy Storage Materials 1 publication, 1.28%
Chemical Engineering Journal	Chemical Engineering Journal, 1, 1.28% Chemical Engineering Journal 1 publication, 1.28%
Renewable and Sustainable Energy Reviews	Renewable and Sustainable Energy Reviews, 1, 1.28% Renewable and Sustainable Energy Reviews 1 publication, 1.28%
Journal of Environmental Chemical Engineering	Journal of Environmental Chemical Engineering, 1, 1.28% Journal of Environmental Chemical Engineering 1 publication, 1.28%
Journal of Industrial and Engineering Chemistry	Journal of Industrial and Engineering Chemistry, 1, 1.28% Journal of Industrial and Engineering Chemistry 1 publication, 1.28%
Transactions of Nonferrous Metals Society of China	Transactions of Nonferrous Metals Society of China, 1, 1.28% Transactions of Nonferrous Metals Society of China 1 publication, 1.28%
	1 2 3 4 5 6 7 8 9

Citations by publishers

	5 10 15 20 25 30 35
Elsevier	Elsevier, 35, 44.87% Elsevier 35 publications, 44.87%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 7, 8.97% Royal Society of Chemistry (RSC) 7 publications, 8.97%
Springer Nature	Springer Nature, 6, 7.69% Springer Nature 6 publications, 7.69%
American Chemical Society (ACS)	American Chemical Society (ACS), 4, 5.13% American Chemical Society (ACS) 4 publications, 5.13%
Wiley	Wiley, 4, 5.13% Wiley 4 publications, 5.13%
Taylor & Francis	Taylor & Francis, 3, 3.85% Taylor & Francis 3 publications, 3.85%
The Electrochemical Society	The Electrochemical Society, 2, 2.56% The Electrochemical Society 2 publications, 2.56%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 2, 2.56% Multidisciplinary Digital Publishing Institute (MDPI) 2 publications, 2.56%
IOP Publishing	IOP Publishing, 2, 2.56% IOP Publishing 2 publications, 2.56%
The Chemical Society of Japan	The Chemical Society of Japan, 1, 1.28% The Chemical Society of Japan 1 publication, 1.28%
The Electrochemical Society of Japan	The Electrochemical Society of Japan, 1, 1.28% The Electrochemical Society of Japan 1 publication, 1.28%
Cambridge University Press	Cambridge University Press, 1, 1.28% Cambridge University Press 1 publication, 1.28%
Korean Society of Industrial Engineering Chemistry	Korean Society of Industrial Engineering Chemistry, 1, 1.28% Korean Society of Industrial Engineering Chemistry 1 publication, 1.28%
Hindawi Limited	Hindawi Limited, 1, 1.28% Hindawi Limited 1 publication, 1.28%
Taiwan Institute of Chemical Engineers	Taiwan Institute of Chemical Engineers, 1, 1.28% Taiwan Institute of Chemical Engineers 1 publication, 1.28%
	5 10 15 20 25 30 35

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Yu X. et al. Spiro-(1,1′)-bipyrrolidinium tetrafluoroborate salt as high voltage electrolyte for electric double layer capacitors // Journal of Power Sources. 2014. Vol. 265. pp. 309-316.

GOST all authors (up to 50) Copy

Yu X., Ruan D., Wu C., Wang J., Shi Z. Spiro-(1,1′)-bipyrrolidinium tetrafluoroborate salt as high voltage electrolyte for electric double layer capacitors // Journal of Power Sources. 2014. Vol. 265. pp. 309-316.

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RIS Copy

TY - JOUR

DO - 10.1016/j.jpowsour.2014.04.144

UR - https://doi.org/10.1016%2Fj.jpowsour.2014.04.144

TI - Spiro-(1,1′)-bipyrrolidinium tetrafluoroborate salt as high voltage electrolyte for electric double layer capacitors

T2 - Journal of Power Sources

AU - Yu, Xuewen

AU - Ruan, Dianbo

AU - Wu, Changcheng

AU - Wang, Jing

AU - Shi, Zhiqiang

PY - 2014

DA - 2014/11/01 00:00:00

PB - Elsevier

SP - 309-316

VL - 265

SN - 0378-7753

ER -

BibTex

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BibTex Copy

@article{2014_Yu,

author = {Xuewen Yu and Dianbo Ruan and Changcheng Wu and Jing Wang and Zhiqiang Shi},

title = {Spiro-(1,1′)-bipyrrolidinium tetrafluoroborate salt as high voltage electrolyte for electric double layer capacitors},

journal = {Journal of Power Sources},

year = {2014},

volume = {265},

publisher = {Elsevier},

month = {nov},

url = {https://doi.org/10.1016%2Fj.jpowsour.2014.04.144},

pages = {309--316},

doi = {10.1016/j.jpowsour.2014.04.144}

}

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Publisher

Elsevier

Journal

Journal of Power Sources

Quartile SCImago

Quartile WOS

Impact factor

9.2

ISSN

03787753 (Print)