Journal of Power Sources, volume 360, pages 41-47
High performance spiro ammonium electrolyte for Electric Double Layer Capacitors
Derosa Donald
1
,
Higashiya Seiichiro
1
,
Schulz Adam
1
,
Rane Fondacaro Manisha
1
,
Haldar Pradeep
1
1
SUNY Polytechnic Institute – Colleges of Nanoscale Science and Engineering, 257 Fuller Road, Albany, NY 12203, United States
|
Publication type: Journal Article
Publication date: 2017-08-01
Journal:
Journal of Power Sources
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 9.2
ISSN: 03787753
Physical and Theoretical Chemistry
Electrical and Electronic Engineering
Energy Engineering and Power Technology
Renewable Energy, Sustainability and the Environment
Abstract
Abstract The smallest spiro ammonium salt reported to date, 1 M 4-Axoniaspiro[3,4]octane tetrafluoroborate (APBF4), was successfully synthesized and investigated as the electrolyte with acetonitrile (AN) in an Electric Double Layer Capacitor (EDLC) for the first time. The electrochemical characteristics of EDLC devices containing 1 M APBF4/AN paired with commercial activated carbon electrodes were compared to devices containing popular EDLC electrolytes, 1 M 5-Azoniaspiro[4.4]nonane tetrafluoroborate (SBPBF4/AN) and 1 M tetraethyl ammonium tetrafluoroborate (TEABF4/AN), using cyclic voltammetry (CV), galvanostatic charge discharge (GCD), and electrochemical impedance spectroscopy (EIS). The average gravimetric capacitance of the 1 M APBF4 device (124.7 F g−1) was found to be greater than the values measured for both the 1 M SBPBF4 device (108.6 F g−1) and the 1 M TEABF4 device (99.2 F g−1). The direct current equivalent series resistance (ESR) of the 1 M APBF4 device (383.4 mΩ cm−2) was found to be substantially lower than the values measured for both the 1 M SBPBF4 device (501.0 mΩ cm−2) and the 1 M TEABF4 device (710.8 mΩ cm−2). These results demonstrate that APBF4, when compared to current commercial electrolytes, significantly enhances the energy storage properties of EDLC devices.
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Citations by publishers
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Wiley
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1 publication, 5.26%
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Derosa D. et al. High performance spiro ammonium electrolyte for Electric Double Layer Capacitors // Journal of Power Sources. 2017. Vol. 360. pp. 41-47.
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Derosa D., Higashiya S., Schulz A., Rane Fondacaro M., Haldar P. High performance spiro ammonium electrolyte for Electric Double Layer Capacitors // Journal of Power Sources. 2017. Vol. 360. pp. 41-47.
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TY - JOUR
DO - 10.1016/j.jpowsour.2017.05.096
UR - https://doi.org/10.1016%2Fj.jpowsour.2017.05.096
TI - High performance spiro ammonium electrolyte for Electric Double Layer Capacitors
T2 - Journal of Power Sources
AU - Derosa, Donald
AU - Higashiya, Seiichiro
AU - Schulz, Adam
AU - Rane Fondacaro, Manisha
AU - Haldar, Pradeep
PY - 2017
DA - 2017/08/01 00:00:00
PB - Elsevier
SP - 41-47
VL - 360
SN - 0378-7753
ER -
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@article{2017_Derosa,
author = {Donald Derosa and Seiichiro Higashiya and Adam Schulz and Manisha Rane Fondacaro and Pradeep Haldar},
title = {High performance spiro ammonium electrolyte for Electric Double Layer Capacitors},
journal = {Journal of Power Sources},
year = {2017},
volume = {360},
publisher = {Elsevier},
month = {aug},
url = {https://doi.org/10.1016%2Fj.jpowsour.2017.05.096},
pages = {41--47},
doi = {10.1016/j.jpowsour.2017.05.096}
}