Journal of Power Sources, volume 470, pages 228231

Electrochemical properties and evolution of the phase transformation behavior in the NASICON-type Na3+xMnxV2-x(PO4)3 (0≤x≤1) cathodes for Na-ion batteries

Publication typeJournal Article
Publication date2020-09-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor9.2
ISSN03787753
Physical and Theoretical Chemistry
Electrical and Electronic Engineering
Energy Engineering and Power Technology
Renewable Energy, Sustainability and the Environment
Abstract
Abstract NASICON-structured cathode materials are considered as possible candidates for high-performance Na-ion batteries. Further increase of energy density of the Na3V2(PO4)3 may be achieved by substitution of the V cations by other transition metals. Here, we show that a family of Na3+xMnxV2-x(PO4)3 (0≤x≤1, Δx=0.2) cathode materials demonstrates remarkable diversity of the electrochemical properties and phase transformations depending on degree of substitution and cut-off voltage. An intermediate “Na2M2(PO4)3” phase was found for all compounds studied by means of operando powder X-ray diffraction. When Mn content is low (x~0–0.4), it coexists with Na3+xMnxV2-x(PO4)3 or Na1+xMnxV2-x(PO4)3. Increase in Mn content extends the length of the solid solution region corresponding to sodiated, intermediate and desodiated phases. All Mn-substituted samples are characterized by additional high-voltage plateau (~3.9 V) at charge-discharge curves. Na3+xMnxV2-x(PO4)3 (x≥0.4) compositions exhibit 8–10% energy density gain in comparison to Na3V2(PO4)3 material, Na3.2Mn0.2V1.8(PO4)3 and Na3.4Mn0.4V1.6(PO4)3 are most preferable in terms of cycling stability.

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Zakharkin M. V. et al. Electrochemical properties and evolution of the phase transformation behavior in the NASICON-type Na3+xMnxV2-x(PO4)3 (0≤x≤1) cathodes for Na-ion batteries // Journal of Power Sources. 2020. Vol. 470. p. 228231.
GOST all authors (up to 50) Copy
Zakharkin M. V., Drozhzhin O. A., Ryazantsev S. V., Chernyshov D., Kirsanova M. A., Mikheev I., Pazhetnov E. M., Antipov E. V., Stevenson K. J., Drozhzhin O. A., Ryazantsev S., Chernyshov D. O., Kirsanova M. A., Antipov E. V., Stevenson K. J. Electrochemical properties and evolution of the phase transformation behavior in the NASICON-type Na3+xMnxV2-x(PO4)3 (0≤x≤1) cathodes for Na-ion batteries // Journal of Power Sources. 2020. Vol. 470. p. 228231.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.jpowsour.2020.228231
UR - https://doi.org/10.1016%2Fj.jpowsour.2020.228231
TI - Electrochemical properties and evolution of the phase transformation behavior in the NASICON-type Na3+xMnxV2-x(PO4)3 (0≤x≤1) cathodes for Na-ion batteries
T2 - Journal of Power Sources
AU - Zakharkin, Maxim V.
AU - Drozhzhin, Oleg A
AU - Ryazantsev, Sergey V
AU - Chernyshov, Dmitry
AU - Kirsanova, Maria A
AU - Mikheev, I.V.
AU - Pazhetnov, Egor M
AU - Antipov, Evgeny V.
AU - Stevenson, Keith J
AU - Drozhzhin, Oleg A.
AU - Ryazantsev, Sergey
AU - Chernyshov, D. O.
AU - Kirsanova, Maria A
AU - Antipov, Evgeny V.
AU - Stevenson, Keith J
PY - 2020
DA - 2020/09/01 00:00:00
PB - Elsevier
SP - 228231
VL - 470
SN - 0378-7753
ER -
BibTex
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BibTex Copy
@article{2020_Zakharkin
author = {Maxim V. Zakharkin and Oleg A Drozhzhin and Sergey V Ryazantsev and Dmitry Chernyshov and Maria A Kirsanova and I.V. Mikheev and Egor M Pazhetnov and Evgeny V. Antipov and Keith J Stevenson and Oleg A. Drozhzhin and Sergey Ryazantsev and D. O. Chernyshov and Maria A Kirsanova and Evgeny V. Antipov and Keith J Stevenson},
title = {Electrochemical properties and evolution of the phase transformation behavior in the NASICON-type Na3+xMnxV2-x(PO4)3 (0≤x≤1) cathodes for Na-ion batteries},
journal = {Journal of Power Sources},
year = {2020},
volume = {470},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016%2Fj.jpowsour.2020.228231},
pages = {228231},
doi = {10.1016/j.jpowsour.2020.228231}
}
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